WNB 0313+683: Analysis of a Newly Discovered Giant Radio Galaxy

We present the results of a detailed analysis of the newly discovered 15 arcmin large FRII-type radio galaxy WNB 0313+683. It has a redshift of 0.0901 +/- 0.0002 and a projected linear size of 2.0 Mpc. Using multi-frequency radio data from the WENSS and NVSS surveys, the VLA, the WSRT and the 100m Effelsberg telescope, we have derived the age of the source (1.4 +/- 0.1 x 10^8 yrs) and the particle densities around the two radio lobes (>1.6 x 10^(-6) per cubic cm for the southern lobe and >5.8 x 10^(-7) per cubic cm for the northern). From optical spectroscopy we find that the H$\alpha$ emission line has a broad component, and that the extinction is large (with colour index E(B-V) = 0.98 +/- 0.10 mag), but is probably mostly galactic in origin (b= +9.8 degrees). Further, the radio core has an inverted spectrum with a spectral index of +0.42 +/- 0.03, suggesting a very compact structure. At 10.5 GHz, it contributes 25% of the total flux density of the source, which is extremely high for radio galaxies. WNB 0313+683 has a very large optical emission line flux with respect to its estimated jet power, when compared with the correlation between these two properties found by Rawlings & Saunders (1991). We argue that this, together with the relatively high radio power and the inverted radio spectrum of the radio core, is suggestive of a new phase of radio activity in this source.Comment: 26 pages, LaTeX (l-aa30 style, including 5 Tables and 30 figures), Accepted for publication in A&A Main Journa

Identification of high performance solvents for the sustainable processing of graphene

Nanomaterials have many advanced applications, from bio-medicine to flexible electronics to energy storage, and the broad interest in graphene-based materials and devices means that high annual tonnages will be required to meet this demand. However, manufacturing at the required scale remains unfeasible until economic and environmental obstacles are resolved. Liquid exfoliation of graphite is the preferred scalable method to prepare large quantities of good quality graphene, but only low concentrations are achieved and the solvents habitually employed are toxic. Furthermore, good dispersions of nanomaterials in organic solvents are crucial for the synthesis of many types of nanocomposites. To address the performance and safety issues of solvent use, a bespoke approach to solvent selection was developed and the renewable solvent Cyrene was identified as having excellent properties. Graphene dispersions in Cyrene were found to be an order of magnitude more concentrated than those achieved in N-methylpyrrolidinone (NMP). Key attributes to this success are optimum solvent polarity, and importantly a high viscosity. We report the role of viscosity as crucial for the creation of larger and less defective graphene flakes. These findings can equally be applied to the dispersion of other layered bi-dimensional materials, where alternative solvent options could be used as drop-in replacements for established processes without disruption or the need to use specialized equipment. Thus, the discovery of a benign yet high performance graphene processing solvent enhances the efficiency, sustainability and commercial potential of this ever-growing field, particularly in the area of bulk material processing for large volume applications

The spin temperature of high-redshift damped Lyman-α\alpha systems

We report results from a programme aimed at investigating the temperature of neutral gas in high-redshift damped Lyman-$\alpha$ absorbers (DLAs). This involved (1) HI 21cm absorption studies of a large DLA sample, (2) VLBI studies to measure the low-frequency quasar core fractions, and (3) optical/ultraviolet spectroscopy to determine DLA metallicities and velocity widths. Including literature data, our sample consists of 37 DLAs with estimates of the spin temperature $T_s$ and the covering factor. We find a strong $4\sigma$) difference between the $T_s$ distributions in high-z (z>2.4) and low-z (z<2.4) DLA samples. The high-z sample contains more systems with high $T_s$ values, $\gtrsim 1000$ K. The $T_s$ distributions in DLAs and the Galaxy are also clearly (~$6\sigma$) different, with more high-$T_s$ sightlines in DLAs than in the Milky Way. The high $T_s$ values in the high-z DLAs of our sample arise due to low fractions of the cold neutral medium. For 29 DLAs with metallicity [Z/H] estimates, we confirm the presence of an anti-correlation between $T_s$ and [Z/H], at $3.5\sigma$ significance via a non-parametric Kendall-tau test. This result was obtained with the assumption that the DLA covering factor is equal to the core fraction. Monte Carlo simulations show that the significance of the result is only marginally decreased if the covering factor and the core fraction are uncorrelated, or if there is a random error in the inferred covering factor. We also find evidence for redshift evolution in DLA $T_s$ values even for the z>1 sub-sample. Since z>1 DLAs have angular diameter distances comparable to or larger than those of the background quasars, they have similar efficiency in covering the quasars. Low covering factors in high-z DLAs thus cannot account for the observed redshift evolution in spin temperatures. (Abstract abridged.)Comment: 37 pages, 22 figures. Accepted for publication in Monthly Notices of the Royal Astronomical Societ

An Imaging and Spectroscopic Study of the z=3.38639 Damped Lyman Alpha System in Q0201+1120: Clues to Star Formation Rate at High Redshift

We present the results of a series of imaging and spectroscopic observations aimed at identifying and studying the galaxy responsible for the z = 3.38639 damped lya system in the z = 3.61 QSO Q0201+1120. We find that the DLA is part of a concentration of matter which includes at least four galaxies (probably many more) over linear comoving dimensions, greater than 5h^-1Mpc. The absorber may be a 0.7 L* galaxy at an impact parameter of 15 h^-1 kpc, but follow-up spectroscopy is still required for positive identification. The gas is turbulent, with many absorption components distributed over approximately 270 km/s and a large spin temperature, T_s greater than 4000K. The metallicity is relatively high for this redshift, Z(DLA) approximately 1/20 Z(solar). From consideration of the relative ratios of elements which have different nucleosynthetic timescales, it would appear that the last major episode of star formation in this DLA occurred at z greater than 4.3, more than approximately 500 Myr prior to the time when we observe it.Comment: Accepted for publication in Ap

Prospects for detecting the 21cm forest from the diffuse intergalactic medium with LOFAR

We discuss the feasibility of the detection of the 21cm forest in the diffuse IGM with the radio telescope LOFAR. The optical depth to the 21cm line has been derived using simulations of reionization which include detailed radiative transfer of ionizing photons. We find that the spectra from reionization models with similar total comoving hydrogen ionizing emissivity but different frequency distribution look remarkably similar. Thus, unless the reionization histories are very different from each other (e.g. a predominance of UV vs. x-ray heating) we do not expect to distinguish them by means of observations of the 21cm forest. Because the presence of a strong x-ray background would make the detection of 21cm line absorption impossible, the lack of absorption could be used as a probe of the presence/intensity of the x-ray background and the thermal history of the universe. Along a random line of sight LOFAR could detect a global suppression of the spectrum from z>12, when the IGM is still mostly neutral and cold, in contrast with the more well-defined, albeit broad, absorption features visible at lower redshift. Sharp, strong absorption features associated with rare, high density pockets of gas could be detected also at z~7 along preferential lines of sight.Comment: 12 pages, 13 figures. MNRAS, in pres

Dynamics and Selection of Giant Spirals in Rayleigh-Benard Convection

For Rayleigh-Benard convection of a fluid with Prandtl number \sigma \approx 1, we report experimental and theoretical results on a pattern selection mechanism for cell-filling, giant, rotating spirals. We show that the pattern selection in a certain limit can be explained quantitatively by a phase-diffusion mechanism. This mechanism for pattern selection is very different from that for spirals in excitable media

Physical Conditions in the Narrow-Line Region of M51

We have investigated the physical conditions in the narrow-line region (NLR) of M51 using long-slit spectra obtained with the Space Telescope Imaging Spectrograph (STIS) aboard the Hubble Space Telescope (HST) and 3.6 cm radio continuum observations obtained with the Very Large Array (VLA). Emission-line diagnostics were employed for nine NLR clouds, which extend 2.5" (102 pc) from the nucleus, to examine the electron density, temperature, and ionization state of the NLR gas. The emission-line ratios are consistent with those typically found in Seyfert nuclei and indicate that within the inner near-nuclear region (r ~< 1") the ionization decreases with increasing radius. Upper-limits to the [O III] electron temperature (T ~< 11,000 K) for the inner NLR clouds indicate that photoionization is the dominant ionization mechanism close to the nucleus. The emission-line fluxes for most of the NLR clouds can be reproduced reasonably well by simple photoionization models using a central power-law continuum source and supersolar nitrogen abundances. Shock+precursor models, however, provide a better fit to the observed fluxes of an NLR cloud ~2.5" south of the nucleus that is identified with the extra-nuclear cloud (XNC). The large [O III] electron temperature of this cloud (T = 24,000 K) further suggests the presence of shocks. This cloud is straddled by two radio knots and lies near the location where a weak radio jet, ~2.5" (102pc) in extent, connects the near-nuclear radio emission with a diffuse lobe structure spanning \~4" (163 pc). It is plausible that this cloud represents the location where the radio jet impinges on the disk ISM.Comment: 25 pages, 26 figures (9 color), 7 tables. Accepted for publication in the Astrophysical Journa

Polysaccharide-derived mesoporous materials (Starbon®) for sustainable separation of complex mixtures

The recovery and separation of high value and low volume extractives are a considerable challenge for the commercial realisation of zero-waste biorefineries. Using solid-phase extractions (SPE) based on sustainable sorbents is a promising method to enable efficient, green and selective separation of these complex extractive mixtures. Mesoporous carbonaceous solids derived from renewable polysaccharides are ideal stationary phases due to their tuneable functionality and surface structure. In this study, the structure-separation relationships of thirteen polysaccharide-derived mesoporous materials and two modified types as sorbents for ten naturally-occurring bioactive phenolic compounds were investigated. For the first time, a comprehensive statistical analysis of the key molecular and surface properties influencing the recovery of these species was carried out. The obtained results show the possibility of developing tailored materials for purification, separation or extraction, depending on the molecular composition of the analyte. The wide versatility and application span of these polysaccharide-derived mesoporous materials offer new sustainable and inexpensive alternatives to traditional silica-based stationary phases

Early stages of ramified growth in quasi-two-dimensional electrochemical deposition

I have measured the early stages of the growth of branched metal aggregates formed by electrochemical deposition in very thin layers. The growth rate of spatial Fourier modes is described qualitatively by the results of a linear stability analysis [D.P. Barkey, R.H. Muller, and C.W. Tobias, J. Electrochem. Soc. {\bf 136}, 2207 (1989)]. The maximum growth rate is proportional to $(I/c)^\delta$ where $I$ is the current through the electrochemical cell, $c$ the electrolyte concentration, and $\delta = 1.37 \pm 0.08$. Differences between my results and the theoretical predictions suggest that electroconvection in the electrolyte has a large influence on the instability leading to ramified growth.Comment: REVTeX, four ps figure

CLASS B0827+525: `Dark lens' or binary radio-loud quasar?

We present radio, optical, near-infrared and spectroscopic observations of the source B0827+525. We consider this source as the best candidate from the Cosmic Lens All-Sky Survey (CLASS) for a `dark lens' system or binary radio-loud quasar. The system consists of two radio components with somewhat different spectral indices, separated by 2.815 arcsec. VLBA observations show that each component has substructure on a scale of a few mas. A deep K-band exposure with the W.M.Keck-II Telescope reveals emission near both radio components. The K-band emission of the weaker radio component appears extended, whereas the emission from the brighter radio component is consistent with a point source. Hubble Space Telescope F160W-band observations with the NICMOS instrument confirms this. A redshift of 2.064 is found for the brighter component, using the LRIS instrument on the W.M.Keck-II Telescope. The probability that B0827+525 consists of two unrelated compact flat-spectrum radio sources is ~3%, although the presence of similar substructure in both component might reduce this. We discuss two scenarios to explain this system: (i) CLASS B0827+525 is a `dark lens' system or (ii) B0827+525 is a binary radio-loud quasar. B0827+525 has met all criteria that thus far have in 100% of the cases confirmed a source as an indisputable gravitational lens system. Despite this, no lens galaxy has been detected with m_F160W<=23 mag. Hence, we might have found the first binary radio-loud quasar. At this moment, however, we feel that the `dark lens' hypothesis cannot yet be fully excluded.Comment: 9 pages, 6 figures; Accepted for publication in Astronomy & Astrophysics; Full-res. images 1 and 3 can be obtained from L.V.E.