Interaction of ionic liquids with noble metal surfaces: Structure formation and stability of [OMIM][TFSA] and [EMIM][TFSA] on Au(111) and Ag(111)

Principles of structure formation and adsorbate–adsorbate interactions in ionic liquid adlayers on metal surfaces were investigated in a comparative STM study on Ag(111) and Au(111) surfaces.</p

Nanoscale Electronic Order in Iron Pnictides

The charge distribution in RFeAs (R=La, Sm) iron pnictides is probed using As NQR. Whereas undoped and optimally-doped/overdoped compounds feature a single charge environment, two charge environments are detected in the underdoped region. Spin- lattice relaxation measurements show their coexistence at the nanoscale. Together with the quantitative variations of the spectra with doping, they point at a local electronic order in the iron layers, where low- and high-doping-like regions would coexist. Implications for the interplay of static magnetism and superconductivity are discussed

Saddles in the energy landscape probed by supercooled liquids

We numerically investigate the supercooled dynamics of two simple model liquids exploiting the partition of the multi-dimension configuration space in basins of attraction of the stationary points (inherent saddles) of the potential energy surface. We find that the inherent saddles order and potential energy are well defined functions of the temperature T. Moreover, decreasing T, the saddle order vanishes at the same temperature (T_MCT) where the inverse diffusivity appears to diverge as a power law. This allows a topological interpretation of T_MCT: it marks the transition from a dynamics between basins of saddles (T>T_MCT) to a dynamics between basins of minima (T<T_MCT).Comment: 4 pages, 3 figures, to be published on PR

Nutritional and tissue-specific regulation of cytochrome P450 CYP711A MAX1 homologues and strigolactone biosynthesis in wheat

Strigolactones (SLs) are a class of phytohormones regulating branching/tillering, and their biosynthesis has been associated with nutritional signals and plant adaptation to nutrient-limiting conditions. The enzymes in the SL biosynthetic pathway downstream of carlactone are of interest as they are responsible for structural diversity in SLs, particularly cytochrome P450 CYP711A subfamily members, such as MORE AXILLARY GROWTH1 (MAX1) in Arabidopsis. We identified 13 MAX1 homologues in wheat, clustering in four clades and five homoeologous subgroups. The utilization of RNA-sequencing data revealed a distinct expression pattern of MAX1 homologues in above- and below-ground tissues, providing insights into the distinct roles of MAX1 homologues in wheat. In addition, a transcriptional analysis showed that SL biosynthetic genes were systematically regulated by nitrogen supply. Nitrogen limitation led to larger transcriptional changes in the basal nodes than phosphorus limitation, which was consistent with the observed tillering suppression, as wheat showed higher sensitivity to nitrogen. The opposite was observed in roots, with phosphorus limitation leading to stronger induction of most SL biosynthetic genes compared with nitrogen limitation. The observed tissue-specific regulation of SL biosynthetic genes in response to nutritional signals is likely to reflect the dual role of SLs as rhizosphere signals and branching inhibitors

Two-Dimensional Electronic Spectroscopy of Chlorophyll a: Solvent Dependent Spectral Evolution

The interaction of the monomeric chlorophyll Q-band electronic transition with solvents of differing physical-chemical properties is investigated through two-dimensional electronic spectroscopy (2DES). Chlorophyll constitutes the key chromophore molecule in light harvesting complexes. It is well-known that the surrounding protein in the light harvesting complex fine-tunes chlorophyll electronic transitions to optimize energy transfer. Therefore, an understanding of the influence of the environment on the monomeric chlorophyll electronic transitions is important. The Q-band 2DES is inhomogeneous at early times, particularly in hydrogen bonding polar solvents, but also in nonpolar solvents like cyclohexane. Interestingly this inhomogeneity persists for long times, even up to the nanosecond time scale in some solvents. The reshaping of the 2DES occurs over multiple time scales and was assigned mainly to spectral diffusion. At early times the reshaping is Gaussian-like, hinting at a strong solvent reorganization effect. The temporal evolution of the 2DES response was analyzed in terms of a Brownian oscillator model. The spectral densities underpinning the Brownian oscillator fitting were recovered for the different solvents. The absorption spectra and Stokes shift were also properly described by this model. The extent and nature of inhomogeneous broadening was a strong function of solvent, being larger in H-bonding and viscous media and smaller in nonpolar solvents. The fastest spectral reshaping components were assigned to solvent dynamics, modified by interactions with the solute

Geometric approach to the dynamic glass transition

We numerically study the potential energy landscape of a fragile glassy system and find that the dynamic crossover corresponding to the glass transition is actually the effect of an underlying geometric transition caused by a qualitative change in the topological properties of the landscape. Furthermore, we show that the potential energy barriers connecting local glassy minima increase with decreasing energy of the minima, and we relate this behaviour to the fragility of the system. Finally, we analyze the real space structure of activated processes by studying the distribution of particle displacements for local minima connected by simple saddles

Организация самостоятельных физкультурно-оздоровительных занятий "Программа 100 минут"

Подготовлено в помощь студентам, осваивающим теоретический курс дисциплины «Физическое воспитание», в том числе и студентам, освобожденным от практических занятий по «Физическому воспитанию». Назначение учебного пособия заключается в том, чтобы представить сведения, необходимые для разработки студентами индивидуальных физкультурно- оздоровительных программ.Содержит знания об использовании различных средств рекреационной физической культуры, самомассажа, а также психологических средств восстановления и самоконтроля за своим функциональным состоянием. Усвоив их, студенты могут под контролем преподавателя разрабатывать такие оздоровительные программы занятий, которые будут учитывать исходное состояние здоровья и способствовать достижению стойкой ремиссии в ходе преодоления имеющихся заболеваний

MeerTime - the MeerKAT Key Science Program on Pulsar Timing

The MeerKAT telescope represents an outstanding opportunity for radio pulsar timing science with its unique combination of a large collecting area and aperture efficiency (effective area $\sim$7500 m$^2$), system temperature ($T<20$K), high slew speeds (1-2 deg/s), large bandwidths (770 MHz at 20cm wavelengths), southern hemisphere location (latitude $\sim -30^\circ$) and ability to form up to four sub-arrays. The MeerTime project is a five-year program on the MeerKAT array by an international consortium that will regularly time over 1000 radio pulsars to perform tests of relativistic gravity, search for the gravitational wave signature induced by supermassive black hole binaries in the timing residuals of millisecond pulsars, explore the interiors of neutron stars through a pulsar glitch monitoring programme, explore the origin and evolution of binary pulsars, monitor the swarms of pulsars that inhabit globular clusters and monitor radio magnetars. In addition to these primary programmes, over 1000 pulsars will have their arrival times monitored and the data made immediately public. The MeerTime pulsar backend comprises two server-class machines each of which possess four Graphics Processing Units. Up to four pulsars can be coherently dedispersed simultaneously up to dispersion measures of over 1000 pc cm$^{-3}$. All data will be provided in psrfits format. The MeerTime backend will be capable of producing coherently dedispersed filterbank data for timing multiple pulsars in the cores of globular clusters that is useful for pulsar searches of tied array beams. All MeerTime data will ultimately be made available for public use, and any published results will include the arrival times and profiles used in the results.Comment: 15 pages, MeerKAT Science: On the Pathway to the SKA, 25-27 May, 2016, Stellenbosch, South Africa, available at: https://pos.sissa.it/277/011/pd