Investigation of lunar crustal structure and isostasy

The lunar mascon basins have strongly free air gravity anomalies, generally exceeding 100 milligals at an elevation of 100 km. The source of the anomalies is a combination of mantle uplift beneath the impact basins and subsequent infilling by high-density mare basalts. The relative contribution of these two components is still somewhat uncertain, although it is generally accepted that the amount of mantle uplift greatly exceeds the thickness of the basalts. Extensive studies have been carried out of the crustal structure of mare basins, based on gravity data, and their tectonic evolution, based on compressive and extensional tectonic features. The present study endeavored to develop a unified, self-consistent model of the lunar crust and lithosphere incorporating both gravity and tectonic constraints

A three-dimensional crustal seismic velocity model for southern California from a composite event method

We present a new crustal seismic velocity model for southern California derived from P and S arrival times from local earthquakes and explosions. To reduce the volume of data and ensure a more uniform source distribution, we compute "composite event" picks for 2597 distributed master events that include pick information for other events within spheres of 2 km radius. The approach reduces random picking error and maximizes the number of S wave picks. To constrain absolute event locations and shallow velocity structure, we also use times from controlled sources, including both refraction shots and quarries. We implement the SIMULPS tomography algorithm to obtain three-dimensional (3-D) V_p and V_p/V_s structure and hypocenter locations of the composite events. Our new velocity model in general agrees with previous studies, resolving low-velocity features at shallow depths in the basins and some high-velocity features in the midcrust. Using our velocity model and 3-D ray tracing, we relocate about 450,000 earthquakes from 1981 to 2005. We observe a weak correlation between seismic velocities and earthquake occurrence, with shallow earthquakes mostly occurring in high P velocity regions and midcrustal earthquakes occurring in low P velocity regions. In addition, most seismicity occurs in regions with relatively low V_p/V_s ratios, although aftershock sequences following large earthquakes are often an exception to this pattern

A California Statewide Three-Dimensional Seismic Velocity Model from Both Absolute and Differential Times

We obtain a seismic velocity model of the California crust and uppermost mantle using a regional-scale double-difference tomography algorithm. We begin by using absolute arrival-time picks to solve for a coarse three-dimensional (3D) P velocity (V_P) model with a uniform 30 km horizontal node spacing, which we then use as the starting model for a finer-scale inversion using double-difference tomography applied to absolute and differential pick times. For computational reasons, we split the state into 5 subregions with a grid spacing of 10 to 20 km and assemble our final statewide V_P model by stitching together these local models. We also solve for a statewide S-wave model using S picks from both the Southern California Seismic Network and USArray, assuming a starting model based on the VP results and a V_P/V_S ratio of 1.732. Our new model has improved areal coverage compared with previous models, extending 570 km in the SW–NE direction and 1320 km in the NW–SE direction. It also extends to greater depth due to the inclusion of substantial data at large epicentral distances. Our V_P model generally agrees with previous separate regional models for northern and southern California, but we also observe some new features, such as high-velocity anomalies at shallow depths in the Klamath Mountains and Mount Shasta area, somewhat slow velocities in the northern Coast Ranges, and slow anomalies beneath the Sierra Nevada at midcrustal and greater depths. This model can be applied to a variety of regional-scale studies in California, such as developing a unified statewide earthquake location catalog and performing regional waveform modeling

Development of high-temperature ferromagnetism in SnO2 and paramagnetism in SnO by Fe doping

We report the development of room-temperature ferromagnetism in chemically synthesized powder samples of Sn1−xFexO2 (0.005≤ x ≤0.05) and paramagnetic behavior in an identically synthesized set of Sn1−xFexO. The ferromagnetic Sn0.99Fe0.01O2 showed a Curie temperature TC=850 K, which is among the highest reported for transition-metal-doped semiconductor oxides. With increasing Fe doping, the lattice parameters of SnO2 decreased and the saturation magnetization increased, suggesting a strong structure-magnetic property relationship. When the Sn0.95Fe0.05O2 was prepared at different temperatures between 200 and 900 °C, systematic changes in the magnetic properties were observed. Combined Mössbauer spectroscopy and magnetometry measurements showed a ferromagnetic behavior in Sn0.95Fe0.05O2 samples prepared at and above 350°C, but the ferromagnetic component decreased gradually as preparation temperature approached 600 °C. All Sn0.95Fe0.05O2 samples prepared above 600 °C were paramagnetic. X-ray photoelectron spectroscopy, magnetometry, and particle induced x-ray emission studies showed that the Fe dopants diffuse towards the surface of the particles in samples prepared at higher temperatures, gradually destroying the ferromagnetism. Mössbauer studies showed that the magnetically ordered Fe3+ spins observed in the Sn0.95Fe0.05O2 sample prepared at 350 °C is only ~24% of the uniformly incorporated Fe3+. No evidence of any iron oxide impurity phases were detected in Sn1−xFexO2 or Sn1−xFexO, suggesting that the emerging magnetic interactions in these systems are most likely related to the properties of the host systems SnO2 and SnO, and their oxygen stoichiometry

Transition Metal Dopants Essential for Producing Ferromagnetism in Metal Oxide Nanoparticles

Recent claims that ferromagnetism can be produced in nanoparticles of metal oxides without the presence of transition metal dopants have been challenged in this work by investigating 62 high quality well-characterized nanoparticle samples of both undoped and Fe doped (0-10% Fe) ZnO. The undoped ZnO nanoparticles showed zero or negligible magnetization, without any dependence on the nanoparticle size. However, chemically synthesized Zn1-xFexO nanoparticles showed clear ferromagnetism, varying systematically with Fe concentration. Furthermore, the magnetic properties of Zn1-xFexO nanoparticles showed strong dependence on the reaction media used to prepare the samples. The zeta potentials of the Zn1-xFexO nanoparticles prepared using different reaction media were significantly different, indicating strong differences in the surface structure. Electron paramagnetic resonance studies indicate that the difference in the ferromagnetic properties of Zn1-xFexO nanoparticles with different surface structures originates from differences in the fraction of the doped Fe ions that participate in ferromagnetic resonance

63Cu NQR evidence of dimensional crossover to anisotropic 2d regime in S= 1/2 three-leg ladder Sr2Cu3O5

We probed spin-spin correlations up to 725 K with 63Cu NQR in the S= 1/2 three-leg ladder Sr2Cu3O5. We present experimental evidence that below 300 K, weak inter-ladder coupling causes dimensional crossover of the spin-spin correlation length \xi from quasi-1d (\xi ~ 1/T) to anisotropic 2d regime (\xi \~ exp[2\pi\rho_{s}/T], where 2\pi\rho_{s} = 290 +/- 30 K is the effective spin stiffness). This is the first experimental verification of the renormalized classical behavior of the anisotropic non-linear sigma model in 2d, which has been recently proposed for the striped phase in high T_{c} cuprates.Comment: 4 pages, 3 figure

Direct inversion of S-P differential arrival-times for Vp/Vs ratio in SE Asia

Open Access via Jisc Wiley agreementPeer reviewedPublisher PD

Diffusive energy transport in the S=1 Haldane chain compound AgVP2S6

We present the results of measurements of the thermal conductivity $\kappa$ of the spin S=1 chain compound AgVP_2S_6 in the temperature range between 2 and 300 K and with the heat flow directed either along or perpendicular to the chain direction. The analysis of the anisotropy of the heat transport allowed for the identification of a small but non-negligible magnon contribution $\kappa_m$ along the chains, superimposed on the dominant phonon contribution $\kappa_ph$. At temperatures above about 100 K the energy diffusion constant D_E(T), calculated from the $\kappa_m(T)$ data, exhibits similar features as the spin diffusion constant D_S(T), previously measured by NMR. In this regime, the behaviour of both transport parameters is consistent with a diffusion process that is caused by interactions inherent to one-dimensional S=1 spin systems.Comment: 6 pages, 4 figure

Evidence for Ballistic Thermal Conduction in the One-Dimensional S=1/2 Heisenberg Antiferromagnetic Spin System Sr2CuO3

We have measured the thermal conductivity of the one-dimensional (1D) S=1/2 Heisenberg antiferromagnetic spin system of Sr2Cu1-xPdxO3 single crystals including nonmagnetic impurities of Pd2+. It has been found that the mean free path of spinons along the 1D spin chain at low temperatures is very close to the average length of finite spin chains between spin defects estimated from the magnetic susceptibility measurements. This proves that the thermal conduction due to spinons at low temperatures in Sr2CuO3 is ballistic as theoretically expected [Zotos et al.: Phys. Rev. Lett. 55 (1997) 11029]