Hybridization effects and multipole orders in Pr skutterudites

Theoretical account is given of 4f-electron dynamics and multipole orders in Pr skutterudites with particular attention to (i) mechanism of the crystalline electric field (CEF) splitting leading to a pseudo-quartet ground state;(ii) Kondo effect due to exchange interactions involving the pseudo-quartet;(iii) multipole orders in the lattice of the pseudo-quartet in magnetic field.Competition between the point-charge interaction andhybridization between 4f and conduction electrons is identified as the key for controlling the CEF splitting. It is found that one of two pseudo-spins forming the pseudo-quartet has a ferromagnetic exchange, while the other has an antiferromagnetic exchange with conduction electrons. The Kondo effect is clearly seen in the resistivity calculated by the NCA, provided the low-lying triplet above the singlet is mainly composed of the $\Gamma_4$-type wave functions.If the weight of the $\Gamma_5$-type is large in the triplet, the Kondo effect does not appear.This difference caused by the nature of the triplet explains the presence of the Kondo effect inPrFe$_4$P$_{12}$, and its absence in PrOs$_4$Sb$_{12}$.By taking the minimal model with antiferro-quadrupole (AFQ) and ferro-type intersite interactions for dipoles and octupoles between nearest-neighbors,the mean-field theory reproduces the overall feature of the multiple ordered phases in PrFe$_4$P$_{12}$. The AFQ order with the $\Gamma_3$-type symmetry is found to be stable only as a mixture of $O_2^0$ and $O_2^2$ components.Comment: 21 pages, to be published in proc. YKIS200

Effects of constant electric fields on the buoyant stability of reaction fronts

The effects that applying constant electric fields have on the buoyant instability of reaction fronts propagating vertically in a Hele-Shaw cell are investigated for a range of electric field strengths and fluid parameters. The reaction produces a decrease in density across the front such that upwards propagating fronts are buoyantly unstable in the field-free situation. The reaction kinetics are modeled by cubic autocatalysis. A linear stability analysis reveals that a positive electric field increases the stability of a reaction front and can stabilize an otherwise unstable front. A negative field has the opposite effect, making the reaction front more unstable. Numerical simulations of the full nonlinear problem confirm these predictions and show the development of cellular fingers on unstable fronts. These simulations show that the electric field effects on the reaction within the front can alter the fluid density so as to give the possibility of destabilizing an otherwise stable downward propagating front

Which preferences associate with school performance? Lessons from an exploratory study with university students

<div><p>Success in life is determined to a large extent by school performance so it is important to understand the effect of the factors that influence it. In this exploratory study, in addition to cognitive abilities, we attempt to link measures of preferences with outcomes of school performance. We measured in an incentivized way risk, time, social and competitive preferences and cognitive abilities of university students to look for associations between these measures and two important academic outcome measures: exam results and GPA. We find consistently that cognitive abilities (proxied by the Cognitive Reflection Test) are very well correlated with school performance. Regarding non-cognitive skills, we report suggestive evidence for many of our measured preferences. We used two alternative measures of time preference: patience and present bias. Present bias explains exam grades better, while patience explains GPA relatively better. Both measures of time preferences have a non-linear relation to school performance. Competitiveness matters, as students, who opt for a more competitive payment scheme in our experimental task have a higher average GPA. We observe also that risk-averse students perform a little better than more risk-tolerant students. That makes sense in case of multiple choice exams, because more risk-tolerant students may want to try to pass the exam less prepared, as the possibility of passing an exam just by chance is not zero. Finally, we have also detected that cooperative preferences—the amount of money offered in a public good game—associates strongly with GPA in a non-linear way. Students who offered around half of their possible amounts had significantly higher GPAs than those, who offered none or all their money.</p></div

Homogenization induced by chaotic mixing and diffusion in an oscillatory chemical reaction

A model for an imperfectly mixed batch reactor with the chlorine dioxide-iodine-malonic acid (CDIMA) reaction, with the mixing being modelled by chaotic advection, is considered. The reactor is assumed to be operating in oscillatory mode and the way in which an initial spatial perturbation becomes homogenized is examined. When the kinetics are such that the only stable homogeneous state is oscillatory then the perturbation is always entrained into these oscillations. The rate at which this occurs is relatively insensitive to the chemical effects, measured by the Damkohler number, and is comparable to the rate of homogenization of a passive contaminant. When both steady and oscillatory states are stable, spatially homogeneous states, two possibilities can occur. For the smaller Damkohler numbers, a localized perturbation at the steady state is homogenized within the background oscillations. For larger Damkohler numbers, regions of both oscillatory and steady behavior can co-exist for relatively long times before the system collapses to having the steady state everywhere. An interpretation of this behavior is provided by the one-dimensional Lagrangian filament model, which is analyzed in detail

Dispersion curves in the diffusional instability of reaction fronts

A (linear) stability analysis of planar reaction fronts to transverse perturbations is considered for systems based on cubic autocatalysis and a model for the chlorite-tetrathionate reaction. Dispersion curves (plots of the growth rate sigma against a transverse wave-number k) are obtained. In both cases it is seen that there is a nonzero value D-0 of D (the ratio of the diffusion coefficients of autocatalyst and substrate) at which sigma(max), the maximum value of sigma for a given value of D, achieves its largest value, with sigma(max) being less for other values of D and becoming small as D decreases to zero. The existence of the optimum value D-0 for initiating a diffusional instability is confirmed, in the cubic autocatalysis case, by an asymptotic analysis for small wave numbers

Nova Cygni 2001/2 = V2275 Cyg

We present an analysis of low- and medium resolution spectra of the very fast nova, Nova Cygni 2001/2 (V2275 Cyg) obtained at nine epochs in August, September and October, 2001. The expansion velocity from hydrogen Balmer lines is found to be 2100 km/s, although early H-alpha profile showed a weak feature at -3500 km/s, too. The overall appearance of the optical spectrum is dominated by broad lines of H, He and N, therefore, the star belongs to the ``He/N'' subclass of novae defined by Williams (1992). Interstellar lines and bands, as well as BV photometry taken from the literature yielded to a fairly high reddening of E(B-V)=1.0+/-0.1 mag. The visual light curve was used to deduce M_V by the maximum magnitude versus rate of decline relationship. The resulting parameters are: t_0=2452141.4(+0.1)(-0.5), t_2=2.9+/-0.5 days, t_3=7+/-1 days, M_V=-9.7+/-0.7 mag. Adopting these parameters, the star lies between 3 kpc and 8 kpc from the Sun.Comment: 5 pages, 5 figures, accepted for publication in A&

Self-Consistent Perturbation Theory for Thermodynamics of Magnetic Impurity Systems

Integral equations for thermodynamic quantities are derived in the framework of the non-crossing approximation (NCA). Entropy and specific heat of 4f contribution are calculated without numerical differentiations of thermodynamic potential. The formulation is applied to systems such as PrFe4P12 with singlet-triplet crystalline electric field (CEF) levels.Comment: 3 pages, 2 figures, proc. ASR-WYP-2005 (JAERI

N=4 Supergravity with Antisymmetric Tensor in Central Charge Superspace

A concise geometrical formulation of N=4 supergravity containing an antisymmetric tensor gauge field is given in central charge superspace: graviphotons are identified in the super-vielbein on the same footing as the vierbein and the Rarita-Schwinger fields. As a consequence of superspace soldering, Chern-Simons terms in the fieldstrength of the antisymmetric tensor arise as an intrinsic property of superspace with central charge coordinates.Comment: Latex, 13 pages, minor clarification about a referenc

Describing and Processing Topology and Quality of Service Parameters of Applications in the Cloud

Typical cloud applications require high-level policy driven orchestration to achieve efficient resource utilisation and robust security to support different types of users and user scenarios. However, the efficient and secure utilisation of cloud resources to run applications is not trivial. Although there have been several efforts to support the coordinated deployment, and to a smaller extent the run-time orchestration of applications in the Cloud, no comprehensive solution has emerged until now that successfully leverages applications in an efficient, secure and seamless way. One of the major challenges is how to specify and manage Quality of Service (QoS) properties governing cloud applications. The solution to address these challenges could be a generic and pluggable framework that supports the optimal and secure deployment and run-time orchestration of applications in the Cloud. A specific aspect of such a cloud orchestration framework is the need to describe complex applications incorporating several services. These application descriptions must specify both the structure of the application and its QoS parameters, such as desired performance, economic viability and security. This paper proposes a cloud technology agnostic approach to application descriptions based on existing standards and describes how these application descriptions can be processed to manage applications in the Cloud