1,131 research outputs found
Editorial: InSAR for volcanoes and tectonics
Abstract not availabl
Biomechanical interactions of endodontically treated tooth implant-supported prosthesis under fatigue test with acoustic emission monitoring
International audienc
Nouveaux copolymères de furo-et sélénophéno(3,4-c)pyrrole-4,6-dione pour l'électronique organique
Depuis maintenant quelques années, les polymères conjugués ont suscité l’intérêt de la communauté scientifique en vertu de leurs propriétés semi-conductrices intéressantes. Récemment, les copolymères de thiéno[3,4-c]pyrrole-4,6-dione (TPD) ont démontré des propriétés optiques et électroniques surprenantes. Ainsi, une partie de cette recherche traite de l’amélioration de ces copolymères par la substitution de l’atome de soufre du TPD par un atome d’oxygène ou de sélénium. Ce mémoire est divisé en cinq chapitres. Le premier offre une introduction générale du champ de recherche présentant les enjeux et mettant en contexte les objectifs principaux du projet. Les deuxième et troisième chapitres présentent quant à eux la synthèse des comonomères et copolymères modifiés relativement au TPD tandis que la caractérisation des copolymères est abordée au chapitre quatre. Finalement, un retour sur les travaux ainsi que les perspectives de ce projet se retrouvent au chapitre cinq
Torsion–rotation global analysis of the first three torsional states (νt = 0, 1, 2) and terahertz database for methanol
Stimulated by recent THz measurements of the methanol spectrum in one of our laboratories, undertaken in support of NASA programs related to the Herschel Space Observatory (HSO) and the Atacama Large Millimeter Array (ALMA), we have carried out a global analysis of available microwave and high-resolution infrared data for the first three torsional states (νt = 0, 1, 2), and for J values up to 30. This global fit of approximately 5600 frequency measurements and 19 000 Fourier transform far infrared (FTFIR) wavenumber measurements to 119 parameters reaches the estimated experimental measurement accuracy for the FTFIR transitions, and about twice the estimated experimental measurement accuracy for the microwave, submillimeter-wave, and terahertz transitions. The present fit is essentially a continuation of our earlier work, but we have greatly expanded our previous data set and have added a large number of new torsion–rotation interaction terms to the Hamiltonian in our previously used computer program. The results, together with a number of calculated (but unmeasured) transitions, including their line strength, estimated uncertainty, and lower state energy, are made available in the supplementary material as a database formatted to be useful for astronomical searches. Some discussion of several open spectroscopic problems, e.g., (i) an improved notation for the numerous parameters in the torsion–rotation Hamiltonian, (ii) possible causes of the failure to fit frequency measurements to the estimated measurement uncertainty, and (iii) pitfalls to be avoided when intercomparing apparently identical parameters from the internal axis method and the rho axis method are also given
UV laser controlled quantum well intermixing in InAlGaAs/GaAs heterostructures
Abstract : The influence of surface irradiation of GaAs with a KrF excimer laser on the magnitude of the quantum well intermixing (QWI) effect has been investigated on GaAs/AlGaAs and GaAs/AlGaAs/InAlGaAs QWs heterostructures. The selective area irradiation through a SiOx mask was carried out in an atmospheric environment. Following the 1000 pulses irradiation at 100 mJ/cm2, the samples were annealed in a rapid thermal annealing furnace at 900 °C. Photoluminescence mapping and cathodoluminescence measurements show that significant laser-induced suppression of the QWI process can be achieved with lateral resolution of the order of 1μm
Laboratory Characterization and Astrophysical Detection of Vibrationally Excited States of Vinyl Cyanide in Orion-KL
New laboratory data of CHCHCN (vinyl cyanide) in its ground and
vibrationally excited states at the microwave to THz domain allow searching for
these excited state transitions in the Orion-KL line survey.
Frequency-modulated spectrometers combined into a single broadband 50-1900 GHz
spectrum provided measurements of CHCHCN covering a spectral range of
18-1893 GHz, whose assignments was confirmed by Stark modulation spectra in the
18-40 GHz region and by ab-initio anharmonic force field calculations. For
analyzing the emission lines of CHCHCN species detected in Orion-KL we used
the excitation and radiative transfer code (MADEX) at LTE conditions. The
rotational transitions of the ground state of this molecule emerge from four
cloud components of hot core nature which trace the physical and chemical
conditions of high mass star forming regions in the Orion-KL Nebula. The total
column density of CHCHCN in the ground state is (3.00.9)x10
cm. We report on the first interstellar detection of transitions in the
v10=1/(v11=1,v15=1) dyad in space, and in the v11=2 and v11=3 states in
Orion-KL. The lowest energy vibrationally excited states of vinyl cyanide such
as v11=1 (at 328.5 K), v15=1 (at 478.6 K), v11=2 (at 657.8 K), the
v10=1/(v11=1,v15=1) dyad (at 806.4/809.9 K), and v11=3 (at 987.9 K) are
populated under warm and dense conditions, so they probe the hottest parts of
the Orion-KL source. Column density and rotational and vibrational temperatures
for CHCHCN in their ground and excited states, as well as for the
isotopologues, have been constrained by means of a sample of more than 1000
lines in this survey. Moreover, we present the detection of methyl isocyanide
(CHNC) for the first time in Orion-KL and a tentative detection of vinyl
isocyanide (CHCHNC) and give column density ratios between the cyanide and
isocyanide isomers.Comment: 46 pages, 22 figures, 14 tables, 9 online table
Post-eruptive volcano inflation following major magma drainage: Interplay between models of viscoelastic response influence and models of magma inflow at Bárðarbunga caldera, Iceland, 2015-2018
<p>Unrest at Bárðarbunga after a caldera collapse in 2014-2015 includes elevated seismicity beginning about six months after the eruption ended, including nine Mw>4.5 earthquakes. The earthquakes occurred mostly on the northern and southern parts of a caldera ring fault. Global Navigation Satellite System (GNSS, in particular, Global Positioning System; GPS) and Interferometric Synthetic Aperture Radar (InSAR) geodesy are applied to evaluate the spatial and temporal pattern of ground deformation around Bárðarbunga caldera outside the icecap, in 2015-2018, when deformation rates were relatively steady. The aim is to study the role of viscoelastic relaxation following major magma drainage versus renewed magma inflow as an explanation for the ongoing unrest.</p><p>The largest horizontal velocity is measured at GPS station KISA (3 km from caldera rim), 141 mm/yr in direction N47<sup>o</sup>E relative to the Eurasian plate in 2015-2018. GPS and InSAR observations show that the velocities decay rapidly outward from the caldera. We correct our observations for Glacial Isostatic Adjustment and plate spreading to extract the deformation related to volcanic activity. After this correction, some GPS sites show subsidence.</p><p>We use a reference Earth model to initially evaluate the contribution of viscoelastic processes to the observed deformation field. We model the deformation within a half-space composed of a 7-km thick elastic layer on top of a viscoelastic layer with a viscosity of 5 x 10<sup>18</sup> Pa s, considering two co-eruptive contributors to the viscoelastic relaxation: “non-piston” magma withdrawal at 10 km depth (modelled as pressure drop in a spherical source) and caldera collapse (modelled as surface unloading). The other model we test is the magma inflow in an elastic half-space. Both the viscoelastic relaxation and magma inflow create horizontal outward movements around the caldera, and uplift at the surface projection of the source center in 2015-2018. Viscoelastic response due to magma withdrawal results in subsidence in the area outside the icecap. Magma inflow creates rapid surface velocity decay as observed.</p><p>We explore further two parameters in the viscoelastic reference model: the viscosity and the "non-piston" magma withdrawal volume. Our comparison between the corrected InSAR velocities and viscoelastic models suggests a viscosity of 2.6×10<sup>18</sup> Pa s and 0.36 km<sup>3</sup> of “non-piston” magma withdrawal volume, given by the optimal reduced Chi-squared statistic. When the deformation is explained using only magma inflow into a single spherical source (and no viscoelastic response), the optimal model suggests an inflow rate at 1×10<sup>7</sup> m<sup>3</sup>/yr at 700 m depth. A magma inflow model with more model parameters is also a possible explanation, including sill inflation at 10 km together with slip on caldera ring faults. Our reference Earth model and the two end-member models suggest that there is a trade-off between the viscoelastic relaxation and the magma inflow, since they produce similar deformation signals outside the icecap. However, to reproduce details of the observed deformation, both processes are required. A viscoelastic-only model cannot fully explain the fast velocity decay away from the caldera, whereas a magma inflow-only model cannot explain the subsidence observed at several locations.</p>
</jats:p
Highly transparent low capacitance plasma enhanced atomic layer deposition Al2O3-HfO2 tunnel junction engineering
Abstract : The development of metallic single electron transistor (SET) depends on the downscaling and the electrical properties of its tunnel junctions. These tunnel junctions should insure high tunnel current levels, low thermionic current, and low capacitance. The authors use atomic layer deposition to fabricate Al2O3 and HfO2 thin layers. Tunnel barrier engineering allows the achievement of low capacitance Al2O3 and HfO2 tunnel junctions using optimized annealing and plasma exposure conditions. Different stacks were designed and fabricated to increase the transparency of the tunnel junction while minimizing thermionic current. This tunnel junction is meant to be integrated in SET to enhance its electrical properties (e.g., operating temperature, ION/IOFF ratio)
Influence of the substrate-induced strain and irradiation disorder on the Peierls transition in TTF-TCNQ microdomains
The influence of the combined effects of substrate-induced strain, finite
size and electron irradiation-induced defects have been studied on individual
micron-sized domains of the organic charge transfer compound
tetrathiafulvalene-tetracyanoquinodimethane (TTF-TCNQ) by temperature-dependent
conductivity and current-voltage measurements. The individual domains have been
isolated by focused ion beam etching and electrically contacted by focused ion
and electron beam induced deposition of metallic contacts. The
temperature-dependent conductivity follows a variable range hopping behavior
which shows a crossover of the exponent as the Peierls transition is
approached. The low temperature behavior is analyzed within the segmented rod
model of Fogler, Teber and Shklowskii, as originally developed for a
charge-ordered quasi one-dimensional electron crystal. The results are compared
with data obtained on as-grown and electron irradiated epitaxial TTF-TCNQ thin
films of the two-domain type
Rotational spectra of isotopic species of methyl cyanide, CHCN, in their ground vibrational states up to terahertz frequencies
Methyl cyanide is an important trace molecule in star-forming regions. It is
one of the more common molecules used to derive kinetic temperatures in such
sources. As preparatory work for Herschel, SOFIA, and in particular ALMA we
want to improve the rest frequencies of the main as well as minor isotopologs
of methyl cyanide. The laboratory rotational spectrum of methyl cyanide in
natural isotopic composition has been recorded up to 1.63 THz. Transitions with
good signal-to-noise ratio could be identified for CHCN, CHCN,
CHCN, CHCN, CHDCN, and CHCN in their
ground vibrational states up to about 1.2 THz. The main isotopic species could
be identified even in the highest frequency spectral recordings around 1.6 THz.
The highest quantum numbers included in the fit are 64 for
CHCN and 89 for the main isotopic species. Greatly improved
spectroscopic parameters have been obtained by fitting the present data
together with previously reported transition frequencies. The present data will
be helpful to identify isotopologs of methyl cyanide in the higher frequency
bands of instruments such as the recently launched Herschel satellite, the
upcoming airplane mission SOFIA or the radio telescope array ALMA.Comment: 13 pages, 2 figures, article appeared; CDMS links update
- …