Emission characteristics of nonmethane hydrocarbons from private cars and taxis at different driving speeds in Hong Kong

Vehicular emissions are the major sources of a number of air pollutants including nonmethane hydrocarbons (NMHCs) in urban area. The emission composition and emission factors of NMHCs from vehicles are currently lacking in Hong Kong. In this study, speciation and emission factors of NMHCs emitted from gasoline-fuelled private cars and liquefied petroleum gas (LPG)-fuelled taxis at different driving speeds were constructed using a chassis dynamometer. Large variations in the contributions of individual NMHC species to total emission were observed for different private cars at different driving speeds. The variations of individual NMHC emissions were relatively smaller for taxis due to their relatively homogeneous year of manufacture and mileages. Incomplete combustion products like ethane, ethene and propene were the major component of both types of vehicles, while unburned fuel component was also abundant in the exhausts of private cars and taxis (i.e. i-pentane and toluene for private car, and propane and butanes for taxi). Emission factors of major NMHCs emitted from private cars and taxis were estimated. High emission factors of ethane, n-butane, i/n-pentanes, methylpentanes, trimethylpentanes, ethene, propene, i-butene, benzene, toluene and xylenes were found for private cars, whereas propane and i/n-butanes had the highest values for taxis. By evaluating the effect of vehicular emissions on the ozone formation potential (OFP), it was found that the contributions of olefinic and aromatic hydrocarbons to OFP were higher than that from paraffinic hydrocarbons for private car, whereas the contributions of propane and i/n-butanes were the highest for taxis. The total OFP value was higher at lower speeds (≤50 km h-1) for private cars while a minimum value at driving speed of 100 km h-1 was found for taxis. At the steady driving speeds, the total contribution of NMHCs emitted from LPG-fuelled taxis to the OFP was much lower than that from gasoline-fuelled private cars. However, at idling state, the contribution of NMHCs from LPG-fuelled vehicles to OFP was comparable to that from gasoline-fuelled vehicles. The findings obtained in this study can be used to mitigate the air pollution caused by vehicles in highly dense urban areas. © 2011 Elsevier Ltd

A potential field approach to the modeling of route choice in pedestrian evacuation

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Collection, spillback, and dissipation in pedestrian evacuation: A network-based method

We present a method of predicting pedestrian route choice behavior and physical congestion during the evacuation of indoor areas with internal obstacles. Under the proposed method, a network is first constructed by discretizing the space into regular hexagonal cells and giving these cells potentials before a modified cell transmission model is employed to predict the evolution of pedestrian flow in the network over time and space. Several properties of this cell transmission model are explored. The method can be used to predict the evolution of pedestrian flow over time and space in indoor areas with internal obstacles and to investigate the collection, spillback, and dissipation behavior of pedestrians passing through a bottleneck. The cell transmission model is further extended to imitate the movements of multiple flows of pedestrians with different destinations. An algorithm based on generalized cell potential is also developed to assign the pedestrian flow. © 2010 Elsevier Ltd.postprin

Characteristics of nonmethane hydrocarbons (NMHCs) in industrial, industrial-urban, and industrial-suburban atmospheres of the Pearl River Delta (PRD) region of south China

In a study conducted in late summer 2000, a wide range of volatile organic compounds (VOCs) were measured throughout five target cities in the Pearl River Delta (PRD) region of south China. Twenty-eight nonmethane hydrocarbons (NMHCs; 13 saturated, 9 unsaturated, and 6 aromatic) are discussed. The effect of rapid industrialization was studied for three categories of landuse in the PRD: Industrial, industrial-urban, and industrial-suburban. The highest VOC mixing ratios were observed in industrial areas. Despite its relatively short atmospheric lifetime (2-3 days), toluene, which is largely emitted from industrial solvent use and vehicular emissions, was the most abundant NMHC quantified. Ethane, ethene, ethyne, propane, n-butane, i-pentane, benzene, and m-xylene were the next most abundant VOCs. Direct emissions from industrial activities were found to greatly impact the air quality in nearby neighborhoods. These emissions lead to large concentration variations for many VOCs in the five PRD study cities. Good correlations between isoprene and several short-lived combustion products were found in industrial areas, suggesting that in addition to biogenic sources, anthropogenic emissions may contribute to urban isoprene levels. This study provides a snapshot of industrial, industrial-urban, and industrial-suburban NMHCs in the five most industrially developed cities of the PRD. Increased impact of industrial activities on PRD air quality due to the rapid spread of industry from urban to suburban and rural areas, and the decrease of farmland, is expected to continue until effective emission standards are implemented. Copyright 2006 by the American Geophysical Union

Role of street patterns in zone-based traffic safety analysis

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Experimental study on mixed traffic flow of bicycles and pedestrians

The mixed flow of bicycles and pedestrians is frequently observed on bicycle-pedestrian-shared roads. Unfortunately, studies on dynamics of this kind of mixed flow are very limited. This paper reports an experimental study of this kind of mixed traffic flow with equal numbers of pedestrians and cyclists asked to walk/ride in a ring-shaped track. In the uni-/bi-directional flow scenarios, pedestrians and bicycles moved in the same/opposite direction. Under both scenarios, bicycles and pedestrians formed their own lanes. Pedestrians walked in the inner lane and cyclists rode in the outer lane. Widths of both the pedestrian lane and the bicycle lane were more uniform in bidirectional flow. The pedestrian flow rate is larger in the unidirectional flow scenario than in the bidirectional flow scenario. In contrast, at low densities, the bicycle flow rate is essentially the same under the two scenarios. When the density is large, the bicycle flow rate becomes larger in the unidirectional flow scenario. Comparing the two modes, pedestrian flow rate is smaller/larger than bicycle flow rate at small/large densities under both scenarios

Impaired flush response to niacin skin patch among schizophrenia patients and their nonpsychotic relatives: The effect of genetic loading

We previously reported familial aggregation in flush response to niacin skin patch among schizophrenia patients and their nonpsychotic relatives. However, little is known about whether this abnormal skin response is associated with genetic loading for schizophrenia. This study compared the niacin flush response in subjects from families with only one member affected with schizophrenia (simplex families) with those from families having a sib-pair with schizophrenia (multiplex families). Subjects were patients with schizophrenia and their nonpsychotic first-degree relatives from simplex families (176 probands, 260 parents, and 80 siblings) and multiplex families (311 probands, 180 parents, and 52 siblings) as well as 94 healthy controls. Niacin patches of 3 concentrations (0.001M, 0.01M, and 0.1M) were applied to forearm skin, and the flush response was rated at 5, 10, and 15 minutes, respectively, with a 4-point scale. More attenuated flush response to topical niacin was shown in schizophrenia probands and their relatives from multiplex families than in their counterparts from simplex families, and the differentiation was better revealed using 0.1M concentration of niacin than 0.01M or 0.001M. For the highest concentration of 0.1M and the longest time lag of 15 minutes, a subgroup of probands (23%), parents (27%), and siblings (19%) still exhibited nonflush response. Flush response to niacin skin patch is more impaired in schizophrenia patients and their relatives from families with higher genetic loading for schizophrenia, and this finding has implications for future genetic dissection of schizophrenia. © 2008 The Authors.published_or_final_versio

Adiponectin is protective against oxidative stress induced cytotoxicity in amyloid-beta neurotoxicity

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Neurocognitive Changes among Elderly Exposed to PCBs/PCDFs in Taiwan

BACKGROUND: In 1979 approximately 2,000 people were exposed to polychlorinated biphenyls (PCBs) and polychlorinated dibenzofurans (PCDFs) due to ingestion of contaminated cooking oil in Taiwan. Although a previous study has shown delayed developmental milestones and poorer neurocognitive functioning in children born to exposed mothers, it is unclear whether neurocognitive functioning was impaired in people who were directly exposed to the PCBs and PDCFs. OBJECTIVE: The objective of this study was to compare neurocognitive functioning in people exposed to PCBs and PCDFs with that of unexposed sex- and age-matched neighbors. METHODS: We conducted a retrospective cohort study among exposed and unexposed subjects >= 60 years of age using prospective outcome measurements. We evaluated neurocognitive tests including cognition, memory modalities, learning, motor and sensory function, mood, and daily activity. RESULTS: In total, 162 (59%) exposed and 151 (55%) reference subjects completed this study. In exposed men, all test results were similar to the reference group; however, exposed women had reduced functioning in attention and digit span (ADS), visual memory span (VMS), and verbal memory recalls (VMR ), especially learning ability. We also found a borderline reduction in the Mini-Mental State Examination. The digit symbol, motor, sensory, depression ( determined by the Geriatric Depression Scale-Short Form), and activity of daily life were not different between the exposed and reference groups. A significant dose-response relationship was found for VMR, ADS, and VMS. CONCLUSION: Our study showed dose-dependent neurocognitive deficits in certain aspects of attention, visual memory, and learning ability in women previously exposed to PCBs and PCDFs, but not in exposed men

Integration Concept of Injection, Forming and Foaming: A Practical Approach to Manufacture Hybrid Structures

Motivated by the concept of the integrative production systems, the hybrid process of polymer injection molding and sheet metal forming, known as polymer injection forming (PIF), has been introduced to manufacture sheet metal-polymer components in a single operation. Despite the wide potential application of this technology, its implementation in actual industrial production has been hindered due to several challenges; a thick layer of polymer where there is deep deformation, non-uniform deformation due to pressure loss and the opposite phenomena of shrinkage and springback. To mitigate these practical issues, the novel idea of integrating supercritical fluid (Sc.F.) technology with the PIF process is introduced in this work. As the proposed technology is a manufacturing innovation, with no available information in the literature correlating to this concept, two sets of experiments are designed to investigate the feasibility of this integration. In the first set, the effect of blank material and shot volume as design variables were investigated over a range of Sc.F. weight percentage. To improve the cell morphology in experiments with the low-strength sheet material, several other processing scenarios are explored in the second set of experiments. The results of this study clearly demonstrate the capabilities of this concept manufacturing process in terms of initiating the foaming process within the simultaneous injection/forming process, ensuring weight reduction (of up to 16%) and complete elimination of issues related to shrinkage