Berry-phase blockade in single-molecule magnets

We formulate the problem of electron transport through a single-molecule magnet (SMM) in the Coulomb blockade regime taking into account topological interference effects for the tunneling of the large spin of a SMM. The interference originates from spin Berry phases associated with different tunneling paths. We show that in the case of incoherent spin states it is essential to place the SMM between oppositely spin-polarized source and drain leads in order to detect the spin tunneling in the stationary current, which exhibits topological zeros as a function of the transverse magnetic field.Comment: 4 pages, Revtex 4, 4 EPS figure

Cats with thermal burn injuries from California wildfires show echocardiographic evidence of myocardial thickening and intracardiac thrombi.

Recent increases in the prevalence and severity of wildfires in some regions have resulted in an increased frequency of veterinary burn patients. Few studies exist regarding diagnostics and management of burn wounds in veterinary patients and current knowledge is extrapolated from human literature and research models. Post-burn cardiac injury is a common finding and predictor of mortality in human patients and echocardiography is an important tool in monitoring response to therapy and predicting outcome. We describe the notable findings from cats naturally exposed to California wildfires in 2017 and 2018. Domestic cats (n = 51) sustaining burn injuries from the Tubbs (2017) and Camp (2018) wildfires were prospectively enrolled and serial echocardiograms and cardiac troponin I evaluations were performed. Echocardiograms of affected cats revealed a high prevalence of myocardial thickening (18/51) and spontaneous echocardiographic contrast and thrombi formation (16/51). Forty-two cats survived to discharge and 6 died or were euthanized due to a possible cardiac cause. For the first time, we describe cardiovascular and coagulation effects of thermal burn and smoke inhalation in cats. Further studies in veterinary burn victims are warranted and serve as a translational research opportunity for uncovering novel disease mechanisms and therapies

Circular Dichroism of Optically Active 1,2-Disubstituted 1,2-Diphenyl Ethanes Part II: Compounds without COOR-group at Benzylic C

(R,R)-Hydrobenzoin and homochirally analogous thTeo-compounds of formula Ph-CHX-CHY-Ph (X = Y; X rO Y; Y = H) show anegative O-O - CD-line below 37200 crn? and/er a positive one just above it, which can be explained by conformational equilibria around the Ph-C - bonds. The Cotton effect at 220-210 nm is negative for this same configuration, if X rO Y (also Y = H), in these other cases there no such simple correlation. Cotton effects within the Elg- or the E2g-transitions might be the reason for this, although otherwise no indication of them could be found. The same rules hold if a ring is closed between X and Y, the Cotton effect at 220-210 nm has thus the same sign as the torsional angle (Ph-)C-C(-Ph), and the same is also true of the next Cotton effect at 198-191 nm. The temperature dependence of the CD can be explained only by assuming conformational as well as solvational equilibria. Introduction of asingle p-chloro substituent shifts the borderline between the two O-O - CD-lines of opposite signs to 36200 cm-lo It causes a sign inversion of the CD within the «-band of a »half\u27-molecule« of type CI-C6H4-C(H, Bn)-OZ, not however in the case of CI-C6H4(H, Bn)-CH20Z. Such p-chloro substitution does not influence the Cotton effects below 220 nm. p,p\u27-Disubstitution by the CH3CO- -group shifts the p-band strongly batbochromically, the corresponding intense CD-couplet prooves the preponderance of that conformation deduced already from NMR-spectra, and prooves as well the absolute configuration

Synthesis, physicochemical and photophysical characterization of 4-(1-Pyrenyl)-Butyl-α-d-mannopyranoside

Indexación: Web of Science; Scopus; Scielo.Glycolipids are biomolecules composed of a lipid chain (lipophilic) and a monosaccharide or oligosaccharide as hydrophilic group. Their chemical structure and biological role make them undoubtedly good candidates for a large and continuously growing number of biotechnological applications. Mannose is a carbohydrate present on membrane glycolipids of a wide number of pathogenic microorganisms (bacteria, fungi, protozoa, and viruses) and specifically recognized by several lectins. We synthesized a mannose derivative linked through a short methylene chain to a pyrene moiety which behaves as a surfactant, able to aggregate, and retains the photophysical properties of pyrene: showing comparable absorption and emission spectra, having lower fluorescence quantum yield and the ability to form excimer, and finally the ability to produce O-2((1)Delta(g)) with high quantum yields. Thus, this novel molecule would open future applications for detection (fluorescence) or inactivation (singlet oxygen) of bacterial pathogens, viruses, tumor cells, or particular cells.http://ref.scielo.org/pcn4d

Dissipative dynamics of an extended magnetic nanostructure: Spin necklace in a metallic environment

We study theoretically the dynamics of an ``xxz'' spin necklace coupled to a conduction electron sea, a model system for a nanostructure in a dissipative environment. We extract the long-time behavior via a mapping to a multichannel Coulomb gas problem followed by a scaling analysis. The strong quantum fluctuations of the necklace cause a nontrivial dependence of couplings on system size which we extract via an analysis involving the ``boundary condition changing operator'', and confirm via a detailed numerical evaluation of one case.Comment: 4 pages, 4 figure

Constraining the Variability and Binary Fraction of Galactic Center Young Stars

We present constraints on the variability and binarity of young stars in the central 10 arcseconds (~0.4 pc) of the Milky Way Galactic Center (GC) using Keck Adaptive Optics data over a 12 year baseline. Given our experiment's photometric uncertainties, at least 36% of our sample's known early-type stars are variable. We identified eclipsing binary systems by searching for periodic variability. In our sample of spectroscopically confirmed and likely early-type stars, we detected the two previously discovered GC eclipsing binary systems. We derived the likely binary fraction of main sequence, early-type stars at the GC via Monte Carlo simulations of eclipsing binary systems, and find that it is at least 32% with 90% confidence.Comment: Accepted for publication in Proceedings of IAU Symposium 322: The Multi-Messenger Astrophysics of the Galactic Centre, 2 pages, 1 figur

The effect of copper doping on martensite shear stress in porous TiNi (Mo, Fe, Cu) alloys

The properties of alloys based on porous nickel-titanium (TiNi) with copper additives have bee

Classical Stabilization of Homogeneous Extra Dimensions

If spacetime possesses extra dimensions of size and curvature radii much larger than the Planck or string scales, the dynamics of these extra dimensions should be governed by classical general relativity. We argue that in general relativity, it is highly nontrivial to obtain solutions where the extra dimensions are static and are dynamically stable to small perturbations. We also illustrate that intuition on equilibrium and stability built up from non-gravitational physics can be highly misleading. For all static, homogeneous solutions satisfying the null energy condition, we show that the Ricci curvature of space must be nonnegative in all directions. Much of our analysis focuses on a class of spacetime models where space consists of a product of homogeneous and isotropic geometries. A dimensional reduction of these models is performed, and their stability to perturbations that preserve the spatial symmetries is analyzed. We conclude that the only physically realistic examples of classically stabilized large extra dimensions are those in which the extra-dimensional manifold is positively curved.Comment: 25 pages; minor changes, improved reference