Discrete-Ordinates Modelling of the Radiative Heat Transfer in a Pilot-Scale Rotary Kiln

This paper presents work focused on the development, evaluation and use of a 3D model for investigation of the radiative heat transfer in rotary kilns. The model applies a discrete-ordinates method to solve the radiative transfer equation considering emission, absorption and scattering of radiation by gas species and particles for cylindrical and semi-cylindrical enclosures. Modelling input data on temperature, particle distribution and gas composition in the radial, axial and angular directions are experimentally gathered in a down-scaled version of a rotary kiln. The model is tested in its capability to predict the radiative intensity and heat flux to the inner wall of the furnace and good agreement was found when compared to measurements. Including the conductive heat transfer through the furnace wall, the model also satisfactorily predicts the intermediate wall temperature. The work also includes a first study on the effect of the incident radiative heat flux to the different surfaces while adding a cold bed material. With further development of the model, it can be used to study the heat transfer in full-scale rotary kilns

Heat Transfer Conditions in Hydrogen-Fired Rotary Kilns for Iron Ore Processing

This work analyzes the heat transfer conditions in a rotary kiln used for the heat treatment of iron ore pellets in the grate-kiln process. The analysis concerns conditions relevant to fuel switching from coal to hydrogen gas. A modeling assessment of the radiative heat transfer in the kiln is conducted including the pellet bed and inner kiln wall temperature conditions. The results show that the heat transfer rate to the iron ore pellets under conditions of a pure hydrogen flame is comparable to the conditions relevant to coal firing. However, it is higher at the kiln wall surfaces near the burner region and lower in the remaining parts of the kiln. Increasing the particle concentration in the hydrogen flame represents a practical implication of co-firing coal with hydrogen. By adding particles, the emittance of radiation from the flame is significantly influenced, leading to further increased kiln surface temperatures closer to the burner position. Increased flame length also showed enhanced heat transfer rates to the kiln wall, although further away from the burner region

Recirculation of NOx and SOx Scrubber Effluent to an Industrial Grate Fired MSW Boiler - Influence on Combustion Performance, Deposition Behavior, and Flue Gas Composition

The concept of scrubber effluent recirculation has recently received attention in connection to NOx emission control. Here, we present data from an industrial-scale MSW-fired plant, where effluent from a combined NOx and SOx scrubber was recirculated and injected into a grate-fired boiler. The combustion characteristics were carefully studied during the injections to observe the potential effects on burnout and flue gas composition. In addition, deposition measurements were performed to observe effects on growth rate and chemical composition of deposits, which are critical factors for any solid fuel-fired heat and power plant. The recirculation of the nitrogen-rich waste streams was performed via pre-existing liquid injection equipment, and the results show that the N-containing compounds in the scrubber effluent were efficaciously reduced to inert nitrogen gas. Furthermore, the recirculation of the scrubber effluent may reduce ammonia demand for selective non-catalytic reduction systems by inhibiting the formation of ammonium chloride. Sulfur and alkali components in the effluent increased the deposition growth rate and also changed the chemical composition of the deposits. Understanding how the local conditions at the injection point influence the distribution and speciation of the injected compounds is essential for a successful recirculation strategy

Interface characterization of Co2MnGe/Rh2CuSn Heusler multilayers

All-Heusler multilayer structures have been investigated by means of high kinetic x-ray photoelectron spectroscopy and x-ray magnetic circular dichroism, aiming to address the amount of disorder and interface diffusion induced by annealing of the multilayer structure. The studied multilayers consist of ferromagnetic Co$_2$MnGe and non-magnetic Rh$_2$CuSn layers with varying thicknesses. We find that diffusion begins already at comparably low temperatures between 200 $^{\circ}$C and 250 $^{\circ}$C, where Mn appears to be most prone to diffusion. We also find evidence for a 4 {\AA} thick magnetically dead layer that, together with the identified interlayer diffusion, are likely reasons for the small magnetoresistance found for current-perpendicular-to-plane giant magneto-resistance devices based on this all-Heusler system

2D to 3D crossover of the magnetic properties in ordered arrays of iron oxide nanocrystals

The magnetic 2D to 3D crossover behavior of well-ordered arrays of monodomain gamma-Fe2O3 spherical nanoparticles with different thicknesses has been investigated by magnetometry and Monte Carlo (MC) simulations. Using the structural information of the arrays obtained from grazing incidence small-angle X-ray scattering and scanning electron microscopy together with the experimentally determined values for the saturation magnetization and magnetic anisotropy of the nanoparticles, we show that MC simulations can reproduce the thickness-dependent magnetic behavior. The magnetic dipolar particle interactions induce a ferromagnetic coupling that increases in strength with decreasing thickness of the array. The 2D to 3D transition in the magnetic properties is mainly driven by a change in the orientation of the magnetic vortex states with increasing thickness, becoming more isotropic as the thickness of the array increases. Magnetic anisotropy prevents long-range ferromagnetic order from being established at low temperature and the nanoparticle magnetic moments instead freeze along directions defined by the distribution of easy magnetization directions

pHEMT and mHEMT Ultra Wideband Millimeterwave Balanced Resistive Mixers

Two ultra wideband millimeterwave single balanced resistive mixers utilizing a Marchand balun for the LO-hybrid are simulated, fabricated and characterized for 30-60 GHz in both up and down conversion. Two different versions of the mixer were manufactured in a commercial pHEMT-MMIC and a mHEMT-MMIC process respectively. A measured down conversion loss of approximately 6 to 12 dB over the whole band is obtained for both versions of the mixer with external IF power combining. In spite of the balanced design, the required LO power is quite low, 2 dBm is sufficient for low conversion loss. The LO-RF isolation is excellent, often more than 30 dB for both type of mixers. Low noise figure and high IIP3 figures are obtained. It is also shown that by applying selective drain bias, up to 5 dB improvement of IIP3 can be obtained for the mHEMT mixer with small LO powers

pHEMT and mHEMT ultra wideband millimetre wave balanced resistive mixers

Abstract Two ultra wideband millimeterwave single balanced resistive mixers utilizing a Marchand balun for the LO–hybrid are simulated, fabricated and characterized for 30-60 GHz in both up and down conversion. Two different versions of the mixer were manufactured in a commercial pHEMT-MMIC and a mHEMT-MMIC process respectively. A measured down conversion loss of approximately 6 to 12 dB over the whole band is obtained for both versions of the mixer with external IF power combining. In spite of the balanced design, the required LO power is quite low, 2 dBm is sufficient for low conversion loss. The LO-RF isolation is excellent, often more than 30 dB for both type of mixers. Low noise figure and high IIP3 figures are obtained. It is also shown that by applying selective drain bias, up to 5 dB improvement of IIP3 can be obtained for the mHEMT mixer with small LO powers. 1