Two phosphonium cation-based ionic liquids as lubricant additive to a polyalphaolefin base oil

This paper studies the tribological performance of two phosphonium cation-based ionic liquids: trihexyltetradecylphosphonium bis(2,4,4-trimethylpentyl) phosphinate ([P6,6,6,14][(iC8)2PO2]) and trihexyltetradecylphosphonium bis(2-ethylhexyl) phosphate ([P6,6,6,14][BEHP]), as lubricant additive at 1 wt% to a polyalphaolefin. A comparison of their tribological behavior was made to that of one type of zinc dialkyldithiophosphate (ZDDP). Stribeck curve tests were made in a Mini Traction Machine (MTM) tribometer at entrainment speeds ranging from 2000 to 10 mm/s, 30 N-load, slide-to-roll ratio (SRR) of 50%, and temperatures of 40, 60, 80 and 100 °C. Tribofilm formation tests were also conducted in the MTM at 100 °C, load of 50 N, entrainment speed of 150 mm/s, SRR of 50%, and duration of 60 min. Additionally, reciprocating 60-min wear tests at 60 N-load, frequency of 15 Hz, stroke length of 4 mm and at room temperature were performed with IL-containing mixtures at 0.5 and 1 wt%. Coefficient of friction was recorded during the tests, and wear on the discs surface was measured using confocal microscopy. SEM-EDS and XPS were also used for studying the lubricant-surface interactions after these tests. Lubricants including [P6,6,6,14][(iC8)2PO2] exhibited better tribological performance than [P6,6,6,14][BEHP] ones and close to the ZDDP results. SEM images of worn surfaces exhibited evidence of plastic deformation and adhesive wear and EDS analysis showed that only active elements (P, S, Zn) were detected for mixtures containing ZDDP. XPS analysis indicated a different lubrication mechanism of the blends with ionic liquids compared with the ZDDP ones

A study of squeeze and starvation in elastohydrodynamic lubrication

SIGLEAvailable from British Library Document Supply Centre-DSC:DX198259 / BLDSC - British Library Document Supply CentreGBUnited Kingdo

A Joint Angle and Frequency Spectrum Estimation Algorithm Using Difference Coarray

The spectrum sensing that jointly estimates direction-of-arrival (DOA) and frequency spectrum is an important issue for cognitive radio. Existing off-grid DOA estimation algorithms using difference coarray require a large number of snapshots to guarantee the estimation accuracy. Meanwhile, inaccurate DOA estimation renders inaccurate frequency spectrum estimation due to coupled estimation process. In order to overcome these disadvantages, we propose a joint angle and frequency spectrum estimation algorithm using difference coarray in this work. The proposed algorithm first transforms the received signal into the coarray domain and then adopts an “estimate and subtract” method to separate multiple signals. Subsequently, the DOA estimate of each source is corrected iteratively based on the proposed simple interpolation method. Finally, the frequency spectra are obtained by estimating the frequency response matrix based on the previous estimated DOAs. The shortage of requiring a large number of snapshots are overcome by utilizing the deterministically orthogonal signal model in which the signals are completely uncorrelated. Simulation results demonstrate the effectiveness of the proposed algorithm for off-grid DOA and frequency spectrum estimation using difference coarray with few snapshots

Crystallization and preliminary crystallographic study of a recombinant predicted acetamidase/formamidase from the thermophile Thermoanaerobacter tengcongensis

A predicated acetamidase/formanidase from the archaeon T. tengcongensis and its SeMet substitute have been crystallized and undergone preliminarily crystallographic studies including MAD data collection