139 research outputs found
Experimentelle Bestimmung der elektronischen Eigenschaften anwendungsrelevanter Grenzflächen organischer Halbleiter mittels Photoelektronenspektroskopie
Diese Dissertation unter dem Titel Experimentelle Bestimmung der elektronischen Eigenschaften anwendungsrelevanter Grenzflächen organischer Halbleiter mittels Photoelektronenspektroskopie wurde am Leibniz Institut für Festkürper- und Werkstoffforschung (IFW) Dresden am Institut für Festkörperforschung (IFF) unter der Betreuung von Prof. Dr. B. Büchner angefertigt. Zur wissenschaftlichen Untersuchung kamen hierbei zwei Typen anwendungsrelevanter Grenzflächen. Zum einem wurde der Einfluss einer Elektrodenpräparation unter Normalbedingungen mittels ex-situ Reinigungsverfahren im Vergleich zu insitu präparierten Kontakten auf das elektronische Verhalten des organischen Halbleiters Sexithiophen an Grenzflächen zu metallischen Substraten studiert. Als Substratmaterialien kamen hierbei die Metalle Silber, Palladium, Gold und Platin zum Einsatz. In einer zweiten Studie wurden die Grenzflächen der organischen Halbleiter Sexithiophen und Kupfer(II)- Phthalocyanin in Kontakt zu dünnen Filmen des Übergangsmetalloxides La0.7Sr0.3MnO3 untersucht. Auch hier wurde eine vergleichende Untersuchung für ex-situ und in-situ gereinigte La0.7Sr0.3MnO3-Kontakte durchgeführt. Die hierzu verwendeten Filme wurden im IFW Dresden am Institut für Metallische Werkstoffe (IMW) hergestellt. Auch im Rahmen dieser Untersuchungen stand der Einfluss von Sauerstoff auf das elektronische und chemische Verhalten an den Grenzflächen im Vordergrund
Experimentelle Bestimmung der elektronischen Eigenschaften anwendungsrelevanter Grenzflächen organischer Halbleiter mittels Photoelektronenspektroskopie
Diese Dissertation unter dem Titel Experimentelle Bestimmung der elektronischen Eigenschaften anwendungsrelevanter Grenzflächen organischer Halbleiter mittels Photoelektronenspektroskopie wurde am Leibniz Institut für Festkürper- und Werkstoffforschung (IFW) Dresden am Institut für Festkörperforschung (IFF) unter der Betreuung von Prof. Dr. B. Büchner angefertigt. Zur wissenschaftlichen Untersuchung kamen hierbei zwei Typen anwendungsrelevanter Grenzflächen. Zum einem wurde der Einfluss einer Elektrodenpräparation unter Normalbedingungen mittels ex-situ Reinigungsverfahren im Vergleich zu insitu präparierten Kontakten auf das elektronische Verhalten des organischen Halbleiters Sexithiophen an Grenzflächen zu metallischen Substraten studiert. Als Substratmaterialien kamen hierbei die Metalle Silber, Palladium, Gold und Platin zum Einsatz. In einer zweiten Studie wurden die Grenzflächen der organischen Halbleiter Sexithiophen und Kupfer(II)- Phthalocyanin in Kontakt zu dünnen Filmen des Übergangsmetalloxides La0.7Sr0.3MnO3 untersucht. Auch hier wurde eine vergleichende Untersuchung für ex-situ und in-situ gereinigte La0.7Sr0.3MnO3-Kontakte durchgeführt. Die hierzu verwendeten Filme wurden im IFW Dresden am Institut für Metallische Werkstoffe (IMW) hergestellt. Auch im Rahmen dieser Untersuchungen stand der Einfluss von Sauerstoff auf das elektronische und chemische Verhalten an den Grenzflächen im Vordergrund
Electronic properties of molecular solids: the peculiar case of solid Picene
Recently, a new organic superconductor, K-intercalated Picene with high
transition temperatures (up to 18\,K) has been discovered. We have
investigated the electronic properties of the undoped relative, solid picene,
using a combination of experimental and theoretical methods. Our results
provide detailed insight into the occuopied and unoccupied electronic states
Fentanyl analytics in a case of fatal misuse of transdermal fentanyl
Abstract A 54-year old male (90 kg) was found in his bedroom with a fentanyl transdermal patch on his penis. With low vital reactions, the dormant man was immediately brought to hospital, where he died shortly. Systematic toxicological analysis confirmed a fatal poisoning with fentanyl. The fentanyl concentration in blood was 35.1 µg/L (LC-MS-MS). The presented case demonstrated the possibility of fentanyl misuse with a transdermal patch at a place of possibel high resorption and fatal outcome. Death due to the application of fentanyl transdermal system which was patched on the penis has not been previously reported
Optical Study of LaO_0.9F_0.1FeAs: Evidence for a Weakly Coupled Superconducting State
We have studied the reflectance of the recently discovered superconductor
LaO_0.9F0.FeAs in a wide energy range from the far infrared to the visible
regime. We report on the observation of infrared active phonons, the plasma
edge (PE) and possible interband transitions. On the basis of this data and the
reported in-plane penetration depth lambda_L(0) about 254 nm [H. Luetkens et
al., Phys. Rev. Lett. v. 101, 0970009 (2008)] a disorder sensitive relatively
small value of the total electron electron-boson coupling constant
lambda_tot=lambda_e-ph+lambda_e-sp ~ 0.6 +- 0.35 can be estimated adopting an
effective single-band picture.Comment: Changed title, updated references, final published versio
New insight into the physics of iron pnictides from optical and penetration depth data
We report theoretical values for the unscreened plasma frequencies Omega_p of
several Fe pnictides obtained from DFT based calculations within the LDA and
compare them with experimental plasma frequencies obtained from reflectivity
data. The sizable renormalization observed for all considered compounds points
to the presence of many-body effects beyond the LDA. From the large empirical
background dielectric constant of about 12-15, we estimate a large arsenic
polarizability of about 9.5 +- 1.2 Angstroem^3 where the details depend on the
polarizabilities of the remaining ions taken from the literature. This large
polarizability can significantly reduce the value of the Coulomb repulsion U_d
about 4 eV on iron known from iron oxides to a level of 2 eV or below. In
general, this result points to rather strong polaronic effects as suggested by
G.A. Sawatzky et al., in Refs. arXiv:0808.1390 and arXiv:0811.0214 (Berciu et
al.). Possible consequences for the conditions of a formation of bipolarons are
discussed, too. From the extrapolated muon spin rotation penetration depth data
at T= 0 and the experimental Omega_p we estimate the total coupling constant
lambda_tot for the el-boson interaction within the Eliashberg-theory adopting a
single band approximation. For LaFeAsO_0.9F_0.1 a weak to intermediately strong
coupling regime and a quasi-clean limit behaviour are found. For a pronounced
multiband case we obtain a constraint for various intraband coupling constants
which in principle allows for a sizable strong coupling in bands with either
slow electrons or holes.Comment: 34 pages, 10 figures, submitted to New Journal of Physics
(30.01.2009
A photoemission study of interfaces between organic semiconductors and Co as well as Al<sub>2</sub>O<sub>3</sub>/Co contacts
We have studied the energy-level alignment of ex situ, acetone cleaned Co and Al2O3/Co contacts to the organic semiconductors pentacene and rubrene by combined X-ray and ultraviolet photoemission spectroscopy. Our results demonstrate that the work function under these conditions is smaller than in the in situ cleaned, atomically clean case. Moreover, the studied interfaces are characterized by very small, short range interfaces dipoles and substantial injection barriers for holes. This represents essential information in view of their use in organic spintronic devices. Our core-level photoemission spectroscopy measurements rule out chemical reactions
High-Field Pauli-Limiting Behavior and Strongly Enhanced Upper Critical Magnetic Fields near the Transition Temperature of an Arsenic-Deficient LaO_0.9F_0.1FeAs_(1-\delta) Superconductor
We report upper critical field B_c2(T) data for disordered
(arsenic-deficient) LaO_0.9F_0.1FeAs_(1-delta) in a wide temperature and
magnetic field range up to 47 T. Because of the large linear slope of Bc2 about
-5.4 T/K to -6.6 T/K near Tc = 28.5 K the T-dependence of the in-plane Bc2(T)
shows a flattening near 23 K above 30 T which points to Pauli-limited behavior
with Bc2(0) about 63-68 T. Our results are discussed in terms of disorder
effects within conventional and unconventional superconducting pairings.Comment: Change of the title as suggested by the Editors, one author added,
typos corrected, references updated, final published versio
Phase II trial of temsirolimus for relapsed/refractory primary CNS lymphoma
Purpose: In this phase II study (NCT00942747), temsirolimus was tested in patients with relapsed or refractory primary CNS lymphoma (PCNSL). Patients and Methods: Immunocompetent adults with histologically confirmed PCNSL after experiencing high-dose methotrexate-based chemotherapy failure who were not eligible for or had experienced high-dose chemotherapy with autologous stem-cell transplant failure were included. The first cohort (n = 6) received 25 mg temsirolimus intravenously once per week. All consecutive patients received 75 mg intravenously once per week. Results: Thirty-seven eligible patients (median age, 70 years) were included whose median time since their last treatment was 3.9 months (range, 0.1 to 14.6 months). Complete response was seen in five patients (13.5%), complete response unconfirmed in three (8%), and partial response in 12 (32.4%) for an overall response rate of 54%. Median progression-free survival was 2.1 months (95% CI, 1.1 to 3.0 months). The most frequent Common Toxicity Criteria ≥ 3° adverse event was hyperglycemia in 11 (29.7%) patients, thrombocytopenia in eight (21.6%), infection in seven (19%), anemia in four (10.8%), and rash in three (8.1%). Fourteen blood/CSF pairs were collected in nine patients (10 pairs in five patients in the 25-mg cohort and four pairs in four patients in the 75-mg cohort). The mean maximum blood concentration was 292 ng/mL for temsirolimus and 37.2 ng/mL for its metabolite sirolimus in the 25-mg cohort and 484 ng/mL and 91.1 ng/mL, respectively, in the 75-mg cohort. Temsirolimus CSF concentration was 2 ng/mL in one patient in the 75-mg cohort; in all others, no drug was found in their CSF. Conclusion: Single-agent temsirolimus at a weekly dose of 75 mg was found to be active in relapsed/refractory patients with PCNSL; however, responses were usually short lived
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