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    Peter Matthiessen\u27s Misfits

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    Characteristics of Fluvial Bed Material In and Adjacent to Instream Aggregate Extraction Pits Along the Bouie River in Hattiesburg, Mississippi

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    A characterization of channel-bed and bottom sediments adjacent to and along a 3.6 mi (5.8 km) reach of inundated aggregate extraction pits along the Bouie River in Hattiesburg, Mississippi, was made to infer compositional differences upstream and downstream of the disturbed reach. Sedimentary data reveal the following: (i) organic carbon content of fine-grained pit bottom sediments systematically increases with depth and, thus, exhibits an inverse relationship with particle size; (ii) maximum organic carbon content of pit bottom sediments approaches 6.0%; (iii) particle size distributions of gravel and sand channel-bed deposits upstream and downstream of the extraction pit reach are quite similar, with median values mostly ranging from 10 to 20 mm for gravelly sites and 0.38 to 0.40 mm for sandy sites; (iv) pit bottom sediments display a general downstream-fining sequence from medium to coarse sands near channel inflows to fine-grained muds near pit outflows; and (v) variability in particle-size trends of pit bottom sediments is attributed to a subaqueous delta slope and relatively narrow zones that exhibit greater flow velocities during infrequent floods. The results indicate that well-documented channel changes downstream of the extraction pit reach are not necessarily contingent on changes to bed material composition, but are attributed to the overall decrease in sediment load. Furthermore, downstream sediment loads will not be fully restored to pre-disturbance conditions until the extraction pits are completely infilled with basal muds, overlying delta slope sands, and sand and gravel channel bars

    Cyclohexylamine inexplicably induces antennae loss in Formosan subterranean termites (Coptotermes formosanus Shiraki): cyclohexylamine hydrogen phosphate salts are novel termiticides

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    © 2017 Society of Chemical Industry BACKGROUND: In experiments with Formosan subterranean termites (Coptotermes formosanus Shirakii), myo-inositol-2-monophosphate as the dicyclohexylammonium salt was tested among other sugar derivatives, and was found to be toxic to C. formosanus when added to a moistened filter paper food source in plastic Petri dishes. RESULTS: Curiously, over a nine-day period, the moniliform (beaded) antenna of C. formosanus deteriorated in a stepwise fashion with the most distal pseudosegment (bead) turning brown and falling off, followed by the penultimate pseudosegment, sequentially, until 7–9 days when only a stub of the antenna remained. Termites became increasingly moribund with the loss of antennae, and quit normal behavior including consuming cellulose food, and died. sn-Glycerol-3-phosphate as the dicyclohexylammonium salt also gave the same results. Dicyclohexylammonium hydrogen phosphate and monocyclohexylammonium dihydrogen phosphate were synthesized, to find a low-cost form for application to baits, both of which also showed similar toxicity. In a trial with Fibonacci series dilutions of neat cyclohexylamine, the antenna-affecting activity became apparent in the LD30 (14 days) to LD70 range of concentrations. At the higher concentrations, darkening of the most distal parts of leg extremities was noticed. CONCLUSION: Cyclohexylamine appears to be a novel termiticide with a previously unreported mechanism of toxicity. Its hydrogen phosphate salts retain the toxic effect and are inexpensive and easily synthesized. © 2017 Society of Chemical Industry
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