Scotland's groundwater monitoring network : its effectiveness for monitoring nitrate

Scotland has had a national groundwater quality monitoring network since the year 2000. One of the main functions of this network is to monitor nitrate concentrations. Nitrate can be elevated in the environment due to modern agricultural practice. Initially there were 150 monitoring sites, but these have been added to, and in 2005, the number of groundwater monitoring points for nitrate was 219, comprising 139 boreholes, 51 springs and 27 wells; 67% of these sites are in agricultural areas. In order to have confidence in the interpretation of data gathered from the network it is important to know the context of the sample points, and in particular whether any sites are compromised by surface contamination or nearby point sources. Prior to this study, many of the sites had not undergone a formal risk assessment and their condition was unclear. In order to improve confidence in the network, and to help act as a baseline before improving the network, the British Geological Survey and the Macaulay Institute were commissioned by the Scottish Executive to carry out a review during the period February-July 2005. The core of the project was to undertake field assessments for 151 sites where no formal assessment had been made previously. Using criteria developed in this project, a judgement was made as to whether the monitoring point was adequate, required improvement or further assessment, or should be considered for removal. For all 219 sites on the network, a zone of influence was estimated using a semi-quantitative method. These zones were used to help focus the field surveys and also to characterise each site using national datasets; for example the monitoring site would be assigned the land use that occupied more than 60% of the zone. These data were then used to conduct an analysis of the factors controlling nitrate concentrations across the network and to help evaluate how effective the network is at monitoring nitrate in Scottish groundwater. Below is a summary of the main results from the project: 1. The fieldwork and analysis of the 151 previously unassessed sites indicated that: • 61 of the 151 sites are adequate and can continue to be monitored with no improvements. • There are serious concerns about 29 of the 151 sites (19% of the sites assessed and 13% of the total nitrate network). These sites should be considered for removal from the network. The sources found to be least reliable were shallow large diameter wells. However, there is little evidence to suggest that the data from these sources collected from 2000 – 2005 has been seriously compromised by point source pollution. • 30 sites require further assessment before being judged suitable. Most of these sites are springs and require additional work to identify the precise source. • 31 sites require improvements to the monitoring points – the improvements range from better sampling protocols to improving the headworks through simple engineering. 2. There is a clear difference between nitrate concentrations measured in the areas designated as nitrate vulnerable zones (NVZs) and other areas. Within the NVZs, the mean concentration is 25 mg-NO3 l-1 and the median 17 mg-NO3 l-1; outside the NVZs, the mean concentration is 9 mg-NO3 l-1 and the median 4.4 mg-NO3 l-1. The data from the network indicate that land use has a large influence on the nitrate concentrations measured in the monitoring network: arable areas, mixed cultivation of both arable and grassland, and areas where dairy, pigs and poultry are reared contribute to the highest nitrate concentrations, with 18% of sites in these areas exceeding 50 mg-NO3 l-1. The most significant control on nitrate concentrations in the monitoring network is the presence of dairy, pigs or poultry within the zone of influence. 4. A considerable number of monitoring sites have lower nitrate concentrations than would be expected from the nitrate pressure. This can be attributed to dilution from rainfall, mixing with older low nitrate waters, denitrification, or the presence of low permeability soil and superficial deposits which slow the movement of high nitrate water into the aquifers. 5. A “gaps” analysis which compared the current network with an idealised network based on nitrate pressures across Scotland indicated that overall the distribution of the current network is generally good. However, there are significant gaps in the improved grassland areas of the Midland Valley and Ayrshire and in the arable areas of Aberdeenshire, while Mid and East Lothian and the Borders are currently overrepresented. The following recommendations are made for the nitrate groundwater quality network in Scotland: 1. Consideration should be given to removing or replacing 29 of the 219 sites, and undertaking further assessments on 30 sites. A further 31 sites would benefit from improvements to the headworks or sampling arrangements. 2. Further statistical analysis should be undertaken to help understand the factors that control the nitrate concentrations in groundwater – particularly the environmental factors that help to reduce the measured nitrate. 3. The network should continue to be concentrated on nitrate pressured areas in Scotland, with approximately 75% of the network in high nitrate areas, and 25% used to monitor background nitrate concentrations in less pressured areas. 4. Any future sites added to the network must undergo a risk assessment similar to the one developed for this study to ensure that the network remains of good quality. 5. The network must continue to reflect the diverse hydrogeological, soil and land use conditions in Scotland. Therefore, both bedrock and superficial aquifers should be monitored in a variety of soil conditions. The network should continue to include different types of sources, although less emphasis should be given to wells, which are generally poor monitoring points. 6. In the future, the data from the network will require to be actively interpreted: an inevitable outcome from having a diverse network is that the results of the monitoring must be interpreted not only in terms of agricultural practice, but in light of the other factors such as geological and environmental conditions. In practice this could mean a regular detailed review (maybe every 2-3 years) of the data from the network. 7. The network will also need to be actively managed to account for various changes in monitoring sites, for example the land use, the condition of the headworks and the pumping rate. This will involve SEPA hydrogeologists having an overview of the network; individual sources being periodically reviewed using a simple checklist; and additional new sources being sought, possibly through the ongoing BGS/SEPA study of baseline groundwater chemistry across Scotland. 8. Wellhead measurements should be taken periodically to help identify denitrification or mixing with older waters. The limited samples taken during this study proved invaluable for interpreting apparently anomalous nitrate concentrations. To undertake this successfully, dedicated sample taps may have to be introduced. 9. A separate programme of focussed monitoring should be developed in tandem with the national groundwater monitoring network to give information on the effects of the action programmes within the NVZs. These sites should be in a controlled environment that will respond rapidly to changes in agricultural practice. The results from these studies can then be upscaled to help interpret changes in the national network as well as be used on their own to help understand the success of the Action Programmes

Decoherence of Histories and Hydrodynamic Equations for a Linear Oscillator Chain

We investigate the decoherence of histories of local densities for linear oscillators models. It is shown that histories of local number, momentum and energy density are approximately decoherent, when coarse-grained over sufficiently large volumes. Decoherence arises directly from the proximity of these variables to exactly conserved quantities (which are exactly decoherent), and not from environmentally-induced decoherence. We discuss the approach to local equilibrium and the subsequent emergence of hydrodynamic equations for the local densities.Comment: 37 pages, RevTe

Survival of, and competition between, oligodendrocytes expressing different alleles of the Plp gene

Mutations in the X-linked Plp gene lead to dysmyelinating phenotypes and oligodendrocyte cell death. Here, we exploit the X inactivation phenomenon to show that a hierarchy exists in the influence of different mutant Plp alleles on oligodendrocyte survival. We used compound heterozygote mice to study the long-term fate of oligodendrocytes expressing either the jimpy or rumpshaker allele against a background of cells expressing a Plp-null allele. Although mutant and null oligodendrocytes were generated in equal numbers, the proportion expressing the mutant allele subsequently declined, but whereas those expressing the rumpshaker allele formed a reduced but stable population, the number of jimpy cells fell progressively. The age of decline in the jimpy cells in different regions of the CNS correlated with the temporal sequence of myelination. In compound heterozygotes expressing rumpshaker and jimpy alleles, oligodendrocytes expressing the former predominated and were more abundant than when the rumpshaker and null alleles were in competition. Thus, oligodendrocyte survival is not determined solely by cell intrinsic factors, such as the conformation of the misfolded PLP, but is influenced by neighboring cells, possibly competing for cell survival factors

Feasibility of direct discharge from the coronary/intermediate care unit after acute myocardial infarction

AbstractOBJECTIVESThis investigation was designed to determine the feasibility and cost-effectiveness of direct discharge from the coronary/intermediate care unit (CICU) in 497 consecutive patients with an acute myocardial infarction (AMI).BACKGROUNDAlthough patients with an AMI are traditionally treated in the CICU followed by a period on the medical ward, the latter phase can likely be incorporated within the CICU.METHODSAll patients were considered for direct discharge from the CICU with appropriate patient education. The 6-week postdischarge course was evaluated using a structured questionnaire by a telephone interview.RESULTSThere were 497 patients (men = 353; women = 144; age 63.5 ± 0.6 years) in the study, with 29 in-hospital deaths and a further 11 deaths occurring within 6 weeks of discharge. The mode length of CICU stay was 4.0 days (mean 5.1 ± 0.2 days): 1 to 2 (12%), 3 (19%), 4 (21%), 5 (14%), 6 to 7 (19%) and ≥7 (15%) days, respectively with 87.2% discharged home directly. Of the 425 patients surveyed, 119 (28.0%) indicated that they had made unscheduled return visits (URV) to a hospital or physician’s office: 10.6% to an emergency room, 9.4% to a physician’s office and 8.0% readmitted to a hospital. Of these URV, only 14.3% occurred within 48 h of discharge. Compared to historical controls, the present management strategy resulted in a cost savings of Cdn. $4,044.01 per patient.CONCLUSIONSDirect discharge from CICU is a feasible and safe strategy for the majority of patients that results in considerable savings

An evaluation of the Wii Nunchuk as an alternative assistive device for people with intellectual and physical disabilities using switch controlled software

Many people with intellectual disabilities also have physical difficulties which prevent them from using standard computer control devices. Custom made alternative devices for those with special needs can be expensive and the low unit turnover makes the prospect unattractive to potential manufacturers. One solution is to explore the potential of devices used in contemporary gaming technology, such as the Nintendo Wii. The Wii Nunchuk has the potential to replace joystick functions with the advantages of not being surface bound and easier for some individuals to grasp. This study evaluated the feasibility of using the Nunchuk by comparing its performance as a switch with the participant's usual switch. Twenty three volunteers aged between 17 and 21 with intellectual and physical disabilities completed a Single Switch Performance Test using the new device and their familiar device. For most functions of the switch, there was no significant difference between the participants' performance using the Nunchuck and their familiar device. Additional analysis found that some participants' performance did improve whilst using the Nunchuck, but this was not significantly related to physical or cognitive ability. Those whose performance was better with the Nunchuk were more likely to hold it in the conventional way than were those who had better performance with their familiar device. This merits it being offered as a possible alternative to currently available switches for those with physical difficulties affecting their grip

Multibeam Maser Survey of methanol and excited OH in the Magellanic clouds: new detections and maser abundance estimates

‘The definitive version is available at www.blackwell-synergy.com.’ Copyright Blackwell Publishing DOI: 10.1111/j.1365-2966.2008.12888.xPeer reviewe

Wind turbine blade design review

A detailed review of the current state-of-art for wind turbine blade design is presented, including theoretical maximum efficiency, propulsion, practical efficiency, HAWT blade design, and blade loads. The review provides a complete picture of wind turbine blade design and shows the dominance of modern turbines almost exclusive use of horizontal axis rotors. The aerodynamic design principles for a modern wind turbine blade are detailed, including blade plan shape/quantity, aerofoil selection and optimal attack angles. A detailed review of design loads on wind turbine blades is offered, describing aerodynamic, gravitational, centrifugal, gyroscopic and operational conditions

Lagrangian Curves in a 4-dimensional affine symplectic space

Lagrangian curves in R4 entertain intriguing relationships with second order deformation of plane curves under the special affine group and null curves in a 3-dimensional Lorentzian space form. We provide a natural affine symplectic frame for Lagrangian curves. It allows us to classify La- grangrian curves with constant symplectic curvatures, to construct a class of Lagrangian tori in R4 and determine Lagrangian geodesic

A model of the Universe including Dark Energy accounted for by both a Quintessence Field and a (negative) Cosmological Constant

In this work we present a model of the universe in which dark energy is modelled explicitely with both a dynamical quintessence field and a cosmological constant. Our results confirm the possibility of a future collapsing universe (for a given region of the parameter space), which is necessary for a consistent formulation of string theory and quantum field theory. We have also reproduced the measurements of modulus distance from supernovae with good accuracy.Comment: 11 pages, 4 figures, only the results for the single exponential potential are preserved. One author added. Some changes in the reference section. Submitted to Physical Review

Entropy Crisis, Ideal Glass Transition and Polymer Melting: Exact Solution on a Husimi Cactus

We introduce an extension of the lattice model of melting of semiflexible polymers originally proposed by Flory. Along with a bending penalty, present in the original model and involving three sites of the lattice, we introduce an interaction energy that corresponds to the presence of a pair of parallel bonds and a second interaction energy associated with the presence of a hairpin turn. Both these new terms represent four-site interactions. The model is solved exactly on a Husimi cactus, which approximates a square lattice. We study the phase diagram of the system as a function of the energies. For a proper choice of the interaction energies, the model exhibits a first-order melting transition between a liquid and a crystalline phase. The continuation of the liquid phase below this temperature gives rise to a supercooled liquid, which turns continuously into a new low-temperature phase, called metastable liquid. This liquid-liquid transition seems to have some features that are characteristic of the critical transition predicted by the mode-coupling theory.Comment: To be published in Physical Review E, 68 (2) (2003