Tunable far-infrared laser spectroscopy of deuterated isotopomers of Ar–H2O

Several far-infrared vibration-rotation-tunneling transitions have been measured in deuterated isotopomers of Ar–H2O for the first time. These experimental results will enable the generation of improved intermolecular potential energy surfaces for the Ar–H2O system when combined with existing microwave, far-infrared, and infrared data

Rape and Posttraumatic Stress Disorder (PTSD): Examining the Mediating Role of Explicit Sex-Power Beliefs for Men Versus Women

Many rape survivors exhibit symptoms of post-traumatic stress disorder (PTSD), and recent literature suggests survivors\u27 beliefs about sex and control may affect PTSD symptoms. The present study examined beliefs about sex and power as potential mediators of the relationship between rape and PTSD symptoms for men versus women. Participants (N = 782) reported lifetime history of rape, current PTSD symptoms, and beliefs about sex and power. Women reported higher levels of lifetime history of rape than men (19.7% for women; 9.7% for men). While rape history predicted PTSD symptoms for both genders, beliefs about sex and power were shown to be a significant partial mediator of this relationship for men, but not for women. Results extend the literature on rape and PTSD by suggesting that survivors\u27 beliefs about sex and power are connected and can affect their PTSD symptoms. Additionally, results illustrate how sexual violence against men may reaffirm male gender roles that entail power and aggression, and ultimately affect trauma recovery

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Serious Bacterial Infections Acquired During Treatment of Patients Given a Diagnosis of Chronic Lyme Disease - United States.

The term "chronic Lyme disease" is used by some health care providers as a diagnosis for various constitutional, musculoskeletal, and neuropsychiatric symptoms (1,2). Patients with a diagnosis of chronic Lyme disease have been provided a wide range of medications as treatment, including long courses of intravenous (IV) antibiotics (3,4). Studies have not shown that such treatments lead to substantial long-term improvement for patients, and they can be harmful (1,5). This report describes cases of septic shock, osteomyelitis, Clostridium difficile colitis, and paraspinal abscess resulting from treatments for chronic Lyme disease. Patients, clinicians, and public health practitioners should be aware that treatments for chronic Lyme disease can carry serious risks

Is telomere length a biomarker for aging: cross-sectional evidence from the west of Scotland?

Background <p> The search for biomarkers of aging (BoAs) has been largely unsuccessful to-date and there is widespread skepticism about the prospects of finding any that satisfy the criteria developed by the American Federation of Aging Research. This may be because the criteria are too strict or because a composite measure might be more appropriate. Telomere length has attracted a great deal of attention as a candidate BoA. We investigate whether it meets the criteria to be considered as a single biomarker of aging, and whether it makes a useful contribution to a composite measure. </p> Methodology/Principal Findings <p> Using data from a large population based study, we show that telomere length is associated with age, with several measures of physical and cognitive functioning that are related to normal aging, and with three measures of overall health. In the majority of cases, telomere length adds predictive power to that of age, although it was not nearly as good a predictor overall. We used principal components analysis to form two composites from the measures of functioning, one including telomere length and the other not including it. These composite BoAs were better predictors of the health outcomes than chronological age. There was little difference between the two composites. </p> Conclusions <p> Telomere length does not satisfy the strict criteria for a BoA, but does add predictive power to that of chronological age. Equivocal results from previous studies might be due to lack of power or the choice of measures examined together with a focus on single biomarkers. Composite biomarkers of aging have the potential to outperform age and should be considered for future research in this area.</p&gt

Gold(I)-Catalysed Direct Thioetherifications Using Allylic Alcohols: an Experimental and Computational Study

A gold(I)-catalysed direct thioetherification reaction between allylic alcohols and thiols is presented. The reaction is generally highly regioselective (S(N)2′). This dehydrative allylation procedure is very mild and atom economical, producing only water as the by-product and avoiding any unnecessary waste/steps associated with installing a leaving or activating group on the substrate. Computational studies are presented to gain insight into the mechanism of the reaction. Calculations indicate that the regioselectivity is under equilibrium control and is ultimately dictated by the thermodynamic stability of the products

Classifying Single Stars and Spectroscopic Binaries Using Optical Stellar Templates

Stellar spectral classification is a fundamental tool of modern astronomy, providing insight into physical characteristics such as effective temperature, surface gravity, and metallicity. Accurate and fast spectral typing is an integral need for large all-sky spectroscopic surveys like the SDSS and LAMOST. Here, we present the next version of PyHammer, stellar spectral classification software that uses optical spectral templates and spectral line index measurements. PyHammer v2.0 extends the classification power to include carbon (C) stars, DA white dwarf (WD) stars, and also double-lined spectroscopic binaries (SB2). This release also includes a new empirical library of luminosity-normalized spectra that can be used to flux calibrate observed spectra, or to create synthetic SB2 spectra. We have generated physically reasonable SB2 combinations as templates, adding to PyHammer the ability to spectrally type SB2s. We test classification success rates on SB2 spectra, generated from the SDSS, across a wide range of spectral types and signal-to-noise ratios. Within the defined range of pairings described, more than $95\%$ of SB2s are correctly classified.Comment: 16 pages, 7 figures, 4 tables; accepted to ApJ

Quasar Evolution and the Baldwin Effect in the Large Bright Quasar Survey

From a large homogeneous sample of optical/UV emission line measurements for 993 quasars from the Large Bright Quasar Survey (LBQS), we study correlations between emission line equivalent width and both restframe ultraviolet luminosity (i.e., the Baldwin Effect) and redshift. Our semi-automated spectral fitting accounts for absorption lines, fits blended iron emission, and provides upper limits to weak emission lines. Use of a single large, well-defined sample and consistent emission line measurements allows us to sensitively detect many correlations, most of which have been previously noted. A new finding is a significant Baldwin Effect in UV iron emission. Further analysis reveals that the primary correlation of iron emission strength is probably with redshift, implying an evolutionary rather than a luminosity effect. We show that for most emission lines with a significant Baldwin Effect, and for some without, evolution dominates over luminosity effects. This may reflect evolution in abundances, in cloud covering factors, or overall cloud conditions such as density and ionization. We find that in our sample, a putative correlation between Baldwin Effect slope and the ionization potential is not significant. Uniform measurements of other large quasar samples will extend the luminosity and redshift range of such spectral studies and provide even stronger tests of spectral evolution.Comment: 16 pages, Latex, emulateapj style, including 3 tables and 6 figures. Accepted April 02, 2001 for publication in ApJ Main Journal. See also http://hea-www.harvard.edu/~pgreen/Papers.htm

A Persistent High-Energy Flux from the Heart of the Milky Way : Integral's view of the Galactic Center

The Ibis/Isgri imager on Integral detected for the first time a hard X-ray source, IGR J17456-2901, located within 1' of Sgr A* over the energy range 20-100 keV. Here we present the results of a detailed analysis of ~7 Ms of Integral observations of the GC. With an effective exposure of 4.7 Ms we have obtained more stringent positional constraints on this HE source and constructed its spectrum in the range 20-400 keV. Furthermore, by combining the Isgri spectrum with the total X-ray spectrum corresponding to the same physical region around SgrA* from XMM data, and collected during part of the Integral observations, we constructed and present the first accurate wide band HE spectrum for the central arcmins of the Galaxy. Our complete analysis of the emission properties of IGR shows that it is faint but persistent with no variability above 3 sigma contrary to what was alluded to in our first paper. This result, in conjunction with the spectral characteristics of the X-ray emission from this region, suggests that the source is most likely not point-like but, rather, that it is a compact, yet diffuse, non-thermal emission region. The centroid of IGR is estimated to be R.A.=17h45m42.5, decl.=-28deg59'28'', offset by 1' from the radio position of Sgr A* and with a positional uncertainty of 1'. Its 20-400 keV luminosity at 8 kpc is L=5.4x10^35 erg/sec. Very recently, Hess detected of a source of ~TeV g-rays also located within 1' of Sgr A*. We present arguments in favor of an interpretation according to which the photons detected by Integral and Hess arise from the same compact region of diffuse emission near the central BH and that the supernova remnant Sgr A East could play an important role as a contributor of very HE g-rays to the overall spectrum from this region.Comment: 14 pages, 11 figures, Accepted for publication in Ap