Geochemistry on sediments from Baja California

Pelagic sediment recovered at DOMES Site A in the equatorial North Pacific (151°W, 9° 15'N) consists of a surface homogeneous layer, approximately 10 cm thick, overlying a strongly mottled layer that is lighter in color. The radiolarian composition of both units is Quaternary. In areas where this sediment was only a few centimeters thick, the underlying sediment was early Tertiary. Clay mineralogy and major oxide composition of the two Quaternary sediments are uniform. Their similarity to continental shale suggests that the sediment has a terrigenous source. Clay mineralogy and major oxide composition of the Tertiary sediment also are uniform, although they differ markedly from the Quarternary sediment. In contrast to the major oxides, concentrations of Mn, Co, Cu, and Ni soluble in hydroxylamine hydrochloride-acetic acid are strongly different in the surface and subsurface Quaternary sediment. Mn and Ni exhibit pronounced depletions in the subsurface sediment, Ni slightly more than Mn. Cu is also depleted in the subsurface sediment, but less than Mn. It is also depleted in the subsurface Tertiary sediment, whereas the Mn concentration remains high. Concentration of Co relative to Mn increases into the subsurface Quaternary sediment to a constant Co/Mn ratio of 300. The trivalent REE (the REE exclusive of Ce) and Fe exhibit little down-core variation. Distribution of elements in these sediments is closely related to their concentration in associated surface ferromanganese nodules. The nodules are of two distinct types: those from the area where the Quaternary sediment is relatively thick have Delta-MnO2 as the dominant manganese mineral. The ratios of Ni/Mn, Cu/Mn, and Fe/Mn in these nodules approximate the corresponding ratios of the soluble fraction of surface sediment. Todorokite is the dominant mineral of nodules recovered from areas where the Quaternary sediment is thin. Relatively high Cu/Mn, Ni/Mn, and low Fe/Mn ratios of these nodules mirror differences between the soluble fraction of surface and subsurface Quaternary sediment. These compositional trends of sediment and nodules at DOMES Site A reflect a diagenetic origin for the todorokite nodules and a predominantly hydrogenous origin for the Delta-MnO2 nodules

Spatial variations in nutrient utilization, production and diagenesis in the sediments of a coastal upwelling regime (NW Africa): Implications for the paleoceanographic record

A biogeochemical study of recent (multicores) sediments of the northwest African slope was undertaken to understand how the sediment composition varies with respect to the location of core sites relative to the centers of coastal upwelling, and how this has affected the palaeoceanographic record. Sedimentary organic carbon contents are inversely correlated with the nitrogen isotopic composition (15N), high Corganic concentrations and low 15N occurring at proximal (shallow) sites and the opposite at distal (deep) ones. These spatial differences are interpreted to result from higher relative nutrient utilization and a decrease in production as waters are advected offshore from the zone of upwelling. Highest Corganic contents also correlate positively with highest concentrations of redox-sensitive elements (U, Mo and S) that are fixed diagenetically in the sediments. These results suggest that the sedimentary regime at a fixed position depends on the spatial location of the productive areas relatively to a given core site. Downcore records of Zr/Al, Ti/Al, mean grain size of the terrigenous fraction, 15N, Corganic , biogenic Ba, U, Mo and sulfur at a single site on the slope are interpreted to reflect glacial-interglacial changes in the core location relative to the coastline (sea-level effect), and hence changes in production as the area of coastal upwelling moved on- and offshore as sea-level changed, as well as undoubtedly changes in upwelling intensity through wind forcing. Further studies are needed to fully understand the interrelationships of all these processes, which are required for building more reliable paleoceanographic-paleoclimatic records

Alternating seismic uplift and subsidence in the late Holocene at Madang, Papaua New Guinea: Evidence from raised reefs

Well-preserved mid-late Holocene coral reefs are exposed in low coastal cliffs in the vicinity of the Madang lagoon on the north coast of Papua New Guinea. Results from U/Th and C dating of corals, surveying, and field mapping indicate several major changes in relative sea level over this period. Specifically, there is evidence for a relative sea level fall of 4.5 m about 3000 calendar years B.P., followed by relative sea level rises of 1.5 m about 2400 calendar years B.P. and 0.5 m about 1200 calendar years B.P. and a subsequent relative sea level fall of 3 m some time in the past 1000 years. Since regional eustatic sea levels are believed to have been dropping gradually over this time frame, these observed changes in relative sea level are interpreted as reflecting alternating tectonic uplift and subsidence. Furthermore, the detailed structure and age relationships of the coral deposits indicate that both uplift and subsidence occurred rapidly, most probably as coseismic events with vertical displacements of 0.5 to 4.5 m. These events may be related to rupture on NW-SE trending reverse faults which have been mapped in the nearby Adelbert Range and possibly on NE trending cross faults which have been inferred from seismicity. This interpretation implies a much greater degree of tectonic instability and potential seismic hazard in the region than previously recognized, although the inferred coseismic vertical displacements are shown to be consistent with present-day local seismicity. In a broader context, the study illustrates how detailed analysis of vertical changes in coral reef structure and assemblages may be used as a sensitive indicator of changing relative sea level, capable of resolving century timescale events and reversals