III-V Gate-all-around Nanowire MOSFET Process Technology: From 3D to 4D

In this paper, we have experimentally demonstrated, for the first time, III-V 4D transistors with vertically stacked InGaAs nanowire (NW) channels and gate-all-around (GAA) architecture. Novel process technology enabling the transition from 3D to 4D structure has been developed and summarized. The successful fabrication of InGaAs lateral and vertical NW arrays has led to 4x increase in MOSFET drive current. The top-down technology developed in this paper has opened a viable pathway towards future low-power logic and RF transistors with high-density III-V NWs

GaAs Enhancement-Mode NMOSFETs Enabled by Atomic Layer Epitaxial La1.8Y0.2O3La_{1.8}Y_{0.2}O_3 as Dielectric

We demonstrate high performance enhancement-mode (E-mode) GaAs NMOSFETs with an epitaxial gate dielectric layer of $La_{1.8}Y_{0.2}O_3$ grown by atomic layer epitaxy (ALE) on GaAs(111)A substrates. A $0.5-\mu m$-gate-length device has a record-high maximum drain current of 336 mA/mm for surface-channel E-mode GaAs NMOSFETs, a peak intrinsic transconductance of 210 mS/mm, a subthreshold swing of 97 mV/dec and an $I_{ON}/I_{OFF}$ ratio larger than $10^7$. Thermal stability of the single crystalline $La_{1.8}Y_{0.2}O_3$-single crystalline GaAs interface is investigated by capacitance-voltage (C-V) and conductance-voltage (G-V) analysis. High temperature annealing is found to be effective to reduce the $D_{it}$.Chemistry and Chemical Biolog

Variational upper bounds for low-lying states of lithium

We present improved calculations of variational energy eigenvalues for the 1s22s2S, 1s23s2S, and 1s22p2P states of lithium using basis sets with up to 30 224 terms in Hylleraas coordinates. The nonrelativistic energies for infinite nuclear mass are -7.4780603239101437(45) a.u. for 1s22s2S, -7. 3540984214443164(32) a.u. for 1s23s2S, and -7.4101565326516(5) a.u. for 1s22p2P, which represent the most accurate variational upper bounds to date. An important advantage of the basis sets with multiple distance scales is their exceptional numerical stability. © 2011 American Physical Society

Dynamic Covalent Synthesis of Crystalline Porous Graphitic Frameworks

Porous graphitic framework (PGF) is a two-dimensional (2D) material that has emerging energy applications. An archetype contains stacked 2D layers, the structure of which features a fully annulated aromatic skeleton with embedded heteroatoms and periodic pores. Due to the lack of a rational approach in establishing in-plane order under mild synthetic conditions, the structural integrity of PGF has remained elusive and ultimately limited its material performance. Here, we report the discovery of the unusual dynamic character of the C=N bonds in the aromatic pyrazine ring system under basic aqueous conditions, which enables the successful synthesis of a crystalline porous nitrogenous graphitic framework with remarkable in-plane order, as evidenced by powder X-ray diffraction studies and direct visualization using high-resolution transmission electron microscopy. The crystalline framework displays superior performance as a cathode material for lithium-ion batteries, outperforming the amorphous counterparts in terms of capacity and cycle stability. Insertion of well-defined, evenly spaced nanoscale pores into the two-dimensional (2D) layers of graphene invokes exciting properties due to the modulation of its electronic band gaps and surface functionalities. A bottom-up synthesis approach to such porous graphitic frameworks (PGFs) is appealing but also remains a great challenge. The current methods of building covalent organic frameworks rely on a small collection of thermodynamically reversible reactions. Such reactions are, however, inadequate in generating a fully annulated aromatic skeleton in PGFs. With the discovery of dynamic pyrazine formation, we succeeded in applying this linking chemistry to obtain a crystalline PGF material, which has displayed high electrical conductivity and remarkable performance as a cathode material for lithium-ion batteries. We envision that the demonstrated success will open the door to a wide array of fully annulated 2D porous frameworks, which hold immense potential for clean energy applications. We report the unusual dynamic characteristics of the C=N bonds in the pyrazine ring promoted under basic aqueous conditions, which enables the successful synthesis of two-dimensional porous graphitic frameworks (PGFs) featuring fully annulated aromatic skeletons and periodic pores. The PGF displayed high electrical conductivity and remarkable performance as a cathode material for lithium-ion batteries, far outperforming the amorphous counterparts in terms of capacity and cycle stability

Opposite Variability of Indonesian Throughflow and South China Sea Throughflow in the Sulawesi Sea

Based on a high-resolution (0.1° × 0.1°) regional ocean model covering the entire northern Pacific, this study investigated the seasonal and interannual variability of the Indonesian Throughflow (ITF) and the South China Sea Throughflow (SCSTF) as well as their interactions in the Sulawesi Sea. The model efficiency in simulating the general circulations of the western Pacific boundary currents and the ITF/SCSTF through the major Indonesian seas/straits was first validated against the International Nusantara Stratification and Transport (INSTANT) data, the OFES reanalysis, and results from previous studies. The model simulations of 2004–12 were then analyzed, corresponding to the period of the INSTANT program. The results showed that, derived from the North Equatorial Current (NEC)–Mindanao Current (MC)–Kuroshio variability, the Luzon–Mindoro–Sibutu flow and the Mindanao–Sulawesi flow demonstrate opposite variability before flowing into the Sulawesi Sea. Although the total transport of the Mindanao–Sulawesi flow is much larger than that of the Luzon–Mindoro–Sibutu flow, their variability amplitudes are comparable but out of phase and therefore counteract each other in the Sulawesi Sea. Budget analysis of the two major inflows revealed that the Luzon–Mindoro–Sibutu flow is enhanced southward during winter months and El Niño years, when more Kuroshio water intrudes into the SCS. This flow brings more buoyant SCS water into the western Sulawesi Sea through the Sibutu Strait, building up a west-to-east pressure head anomaly against the Mindanao–Sulawesi inflow and therefore resulting in a reduced outflow into the Makassar Strait. The situation is reversed in the summer months and La Niña years, and this process is shown to be more crucially important to modulate the Makassar ITF’s interannual variability than the Luzon–Karimata flow that is primarily driven by seasonal monsoons

Zero-field Edge Magnetoplasmons in a Magnetic Topological Insulator

Incorporating ferromagnetic dopants, such as chromium or vanadium, into thin films of the three-dimensional (3D) topological insulator (TI) (Bi,Sb)2Te3 has recently led to the realisation of the quantum anomalous Hall effect (QAHE), a unique phase of quantum matter. These materials are of great interest, since they may support electrical currents that flow without resistance via edge channels, even at zero magnetic field. To date, the QAHE has been investigated using low-frequency transport measurements. However, transport requires contacting the sample and results can be difficult to interpret due to the presence of parallel conductive paths, via either the bulk or surface, or because additional non-chiral edge channels may exist. Here, we move beyond transport measurements by probing the microwave response of a magnetised disk of Cr-(Bi,Sb)2Te3. We identify features associated with chiral edge magnetoplasmons (EMPs), a signature that robust edge-channels are indeed intrinsic to this material system. Our results provide a measure of the velocity of edge excitations without contacting the sample, and pave the way for a new, on-chip circuit element of practical importance: the TI, zero-field microwave circulator

Stable mode-locked pulses from mid-infrared semiconductor lasers

We report the unequivocal demonstration of mid-infrared mode-locked pulses from a semiconductor laser. The train of short pulses was generated by actively modulating the current and hence the optical gain in a small section of an edge-emitting quantum cascade laser (QCL). Pulses with pulse duration at full-width-at-half-maximum of about 3 ps and energy of 0.5 pJ were characterized using a second-order interferometric autocorrelation technique based on a nonlinear quantum well infrared photodetector. The mode-locking dynamics in the QCLs was modelled and simulated based on Maxwell-Bloch equations in an open two-level system. We anticipate our results to be a significant step toward a compact, electrically-pumped source generating ultrashort light pulses in the mid-infrared and terahertz spectral ranges.Comment: 26 pages, 4 figure

Coherent instabilities in a semiconductor laser with fast gain recovery

We report the observation of a coherent multimode instability in quantum cascade lasers (QCLs), which is driven by the same fundamental mechanism of Rabi oscillations as the elusive Risken-Nummedal-Graham-Haken (RNGH) instability predicted 40 years ago for ring lasers. The threshold of the observed instability is significantly lower than in the original RNGH instability, which we attribute to saturable-absorption nonlinearity in the laser. Coherent effects, which cannot be reproduced by standard laser rate equations, can play therefore a key role in the multimode dynamics of QCLs, and in lasers with fast gain recovery in general.Comment: 5 pages, 4 figure