A simplified hydrokinetic model for a steady‐state microwave discharge sustained by traveling waves at atmospheric pressure conditions

The properties of a microwave‐induced argon plasma produced by traveling surface wave at atmospheric pressure are investigated theoretically. A hydrokinetic model is elaborated to obtain the nonequilibrium one‐dimensional profiles of electron temperature Te (average electron energy), electron density ne, and the first excited state population density n4s, along the axis of a steady‐state discharge. A three‐level atomic structure is assumed for the argon atom. A particle balance is included through the continuity equations for ne and n4s. These equations are coupled with an energy balance equation for the electrons. The effects of different parameters on the properties of the argon discharge are investigated: discharge tube radius, gas flow rate, resonant radiation‐escape factor, and neutral gas temperature.Ministerio de Educación y Ciencia. Gobierno de España-PB91- 0847 y PB94-145

Distinct nonequilibrium plasma chemistry of C2 affecting the synthesis of nanodiamond thin films from C2H2 (1%)/H2/Ar-rich plasmas

6 pages, 5 figures, 6 tables.We show that the concentrations of the species C2 (X 1Σg+), C2 (a 3Πu), and C2H exhibit a significant increase when the argon content grows up to 95% in medium pressure (0.75 Torr) radio frequency (rf) (13.56 MHz) produced C2H2 (1%)/H2/Ar plasmas of interest for the synthesis of nanodiamond thin films within plasma enhanced chemical vapor deposition devices. In contrast, the concentrations of CH3 and C2H2 remain practically constant. The latter results have been obtained with an improved quasianalytic space–time-averaged kinetic model that, in addition, has allowed us to identify and quantify the relative importance of the different underlying mechanisms driving the nonequilibrium plasma chemistry of C2. The results presented here are in agreement with recent experimental results from rf CH4/H2/Ar-rich plasmas and suggest that the growth of nanodiamond thin films from hydrocarbon/Ar-rich plasmas is very sensitive to the contribution of C2 and C2H species from the plasma.This work was partially funded by CICYT (Spain) under a Ramón y Cajal project and under Project No. TIC2002- 03235. One of the authors (F.J.G.V.) acknowledges a Ramón y Cajal contract from the Spanish Ministry of Science and Technology (MCYT). One of the authors (J.M.A.) acknowledges partial support from CICYT (Spain) under Project No. MAT 2002-04085-C02-02.Peer reviewe

Upper D region chemical kinetic modeling of LORE relaxation times

The recovery times of upper D region electron density elevations, caused by lightning-induced electromagnetic pulses (EMP), are modeled. The work was motivated from the need to understand a recently identified narrowband VLF perturbation named LOREs, an acronym for LOng Recovery Early VLF events. LOREs associate with long-living electron density perturbations in the upper D region ionosphere; they are generated by strong EMP radiated from large peak current intensities of +/- CG (cloud to ground) lightning discharges, known also to be capable of producing elves. Relaxation model scenarios are considered first for a weak enhancement in electron density and then for a much stronger one caused by an intense lightning EMP acting as an impulsive ionization source. The full nonequilibrium kinetic modeling of the perturbed mesosphere in the 76 to 92 km range during LORE-occurring conditions predicts that the electron density relaxation time is controlled by electron attachment at lower altitudes, whereas above 79 km attachment is balanced totally by associative electron detachment so that electron loss at these higher altitudes is controlled mainly by electron recombination with hydrated positive clusters H+(H2O)(n) and secondarily by dissociative recombination with NO+ ions, a process which gradually dominates at altitudes > 88 km. The calculated recovery times agree fairly well with LORE observations. In addition, a simplified (quasi-analytic) model build for the key charged species and chemical reactions is applied, which arrives at similar results with those of the full kinetic model. Finally, the modeled recovery estimates for lower altitudes, that is < 79 km, are in good agreement with the observed short recovery times of typical early VLF events, which are known to be associated with sprites.This work was supported by the Spanish Ministry of Science and Innovation, MINECO under projects ESP2013-48032-C5-5-R, FIS2014-61774-EXP, and ESP2015-69909-C5-2-R, and by the EU through the FEDER program. A.L. acknowledges support by a Ramon y Cajal contract, code RYC-2011-07801.Peer reviewe

From carbon nanostructures to new photoluminescence sources: an overview of new perspectives and emerging applications of low pressure PECVD

13 pages, 9 figures.Low-pressure, plasma-enhanced (PE)CVD is a powerful and versatile technique that has been used for thin-film deposition and surface treatment since the early 1960s. However, it is only recently that it has been used in applications other than the different stages of microelectronic circuit fabrication. Now, PECVD is being used in emerging applications due to new materials and process requirements in a wide variety of areas, such as biomedical applications, solar cells, fuel cell development, fusion research, or the synthesis of silicon nanocrystals showing efficient photoluminescence, useful for future solid-state light sources. These new scenarios have stimulated further development of novel PECVD diagnostic techniques, together with fundamental experimental and theoretical studies aimed at a better understanding of some of the basic processes underlying the plasma/surface interaction. This paper gives an overview of some new research areas where PECVD is finding promising applications.FJGV acknowledges partial financial support from CSIC-CAM (Project No. 200550M016 and 200650M016) and MEC (Projects No. MAT2006-13006-C02-01 and ENE2006-14577-C04-03), VJH and IT acknowledge funding from MEC (Projects No. FTN-2003-08228-C03-03, FIS2004-00456 and ENE2006-14577-C04-03).Peer reviewe

Chemical and thermal impacts of sprite streamers in the Earth's mesosphere

A one-dimensional self-consistent model has been developed to study the chemical and thermal effects of a single sprite streamer in the Earth's mesosphere. We have used sprite streamer profiles with three different driving current durations (5 ms, 50 ms, and 100 ms) between 50 and 80 km of altitude and considering a kinetic scheme of air with more than 90 chemical species. Our model predicts strong increases in practically all the concentrations of the species studied at the moment of the streamer head passage. Moreover, their densities remain high during the streamer afterglow phase. The concentration of electrons can reach values of up to 10 cm in the three cases analyzed. The model also predicts an important enhancement, of several orders of magnitude above ambient values, of nitrogen oxides and several metastables species. On the other hand, we found that the 4.26 μm IR emission brightness of CO can reach 10 GR at low altitudes (< 65 km) for the cases of intermediate (50 ms) and long (100 ms) driving currents. These results suggest the possibility of detecting sprite IR emissions from space with the appropriate instrumentation. Finally, we found that the thermal impact of sprites in the Earth's mesosphere is proportional to the driving current duration. This produces variations of more than 40 K (in the extreme case of a 100 ms driving current) at low altitudes (< 55 km) and at about 10 s after the streamer head. Key Points Chemical and thermal impacts of sprites in the mesosphere are calculated The calculated concentration of electrons exhibits a significant enhancement The model predicts an increase in the gas temperature at low altitudes.©2016. American Geophysical Union. All Rights Reserved.This work was supported by the Spanish Ministry of Economy and Competitiveness, MINECO, under projects AYA2011-29936-C05-02 and ESP2013-48032-C5-5-R and by the Junta de Andalucia, Proyecto de Excelencia, FQM-5965. F.C.P.R. acknowledges MINECO for the FPI grant BES-2010-042367. A.L. was supported by a Ramon y Cajal contract, code RYC-2011-07801Peer Reviewe

Modeling the chemical impact and the optical emissions produced by lightning-induced electromagnetic fields in the upper atmosphere: the case of halos and elves triggered by different lightning discharges

Halos and elves are Transient Luminous Events (TLEs) produced in the lower ionosphere as a consequence of lightning-driven electromagnetic fields. These events can influence the upper-atmospheric chemistry and produce optical emissions. We have developed different two-dimensional self-consistent models that couple electrodynamical equations with a chemical scheme to simulate halos and elves produced by vertical cloud-to-ground (CG) lightning discharges, Compact Intra-cloud Discharges (CIDs) and Energetic In-cloud Pulses (EIPs). The optical emissions from radiative relaxation of excited states of molecular and atomic nitrogen and oxygen have been calculated. We have upgraded previous local models of halos and elves to calculate for the first time the vibrationally detailed optical spectra of elves triggered by CIDs and EIPs. According to our results, the optical spectra of elves do not depend on the type of parent lightning discharge. Finally, we have quantified the local chemical impact in the upper atmosphere of single halos and elves. In the case of the halo, we follow the cascade of chemical reactions triggered by the lightning-produced electric field during a long-time simulation of up to one second. We obtain a production rate of NO molecules by single halos and elves of 10$^{16}$ and 10$^{14}$ molecules/J, respectively. The results of these local models have been used to estimate the global production of NO by halos and elves in the upper atmopshere at $\sim10^{-7}$ Tg~N/y. This global chemical impact of halos and elves is seven orders of magnitude below the production of NO in the troposphere by lightning discharges

Recursos lingüísticos empleados en una traducción del siglo XV

Los últimos decenios del s. XIV y primeros del XV muestran claros síntomas de la presencia de nuevas directrices culturales que van a provocar la admiración y el interés por todo lo que representa el mundo greco-Iatino, que se convierte así en un modelo ideal al que hay que imitar; hecho que determinó una de las transformaciones más decisivas en el curso de la historia de España en su ámbito cultural. En este proceso desempeña un papel crucial la labor realizada por D. Enrique de Villena, o de Aragón (1384-1434), autor, que tanto en su producción en prosa como en verso, trató de transplantar a nuestra lengua, los nuevos conceptos que descubrió en ese mundo clásico. Ello provocó al tratar de convertirla en vehículo de expresión digno de verter a ella los textos latinos, el desarrollo de una fecunda tarea de enriquecimiento de la lengua romance por no fallar equivalentes vocablos en la romancial texedura en el rudo y desierto romance, para exprimir los angelicos cocebimientos virgilianos (1). Para elaborar el presente trabajo, sometemos a análisis la traducción realizada por Villena de La Eneida de Virgilio. Nos centramos en el Libro I de la traducción para la determinación de los diversos procedimientos lingüísticos utilizados por el autor al llevar a cabo la traducción y adaptación de los términos latino