Metal adsorption on mosses: Toward a universal adsorption model

AbstractThis study quantifies the adsorption of heavy metals on 4 typical moss species used for environmental monitoring in the moss bag technique. The adsorption of Cu2+, Cd2+, Ni2+, Pb2+ and Zn2+ onto Hypnum sp., Sphagnum sp., Pseudoscleropodium purum and Brachytecium rutabulum has been investigated using a batch reactor in a wide range of pH (1.3–11.0) and metal concentrations in solution (1.6μM–3.8mM). A Linear Programming Model (LPM) was applied for the experimental data to derive equilibrium constants and the number of surface binding sites. The surface acid–base titration performed for 4 mosses at a pH range of 3–10 in 0.1M NaNO3 demonstrated that Sphagnum sp. is the most efficient adsorbent as it has the maximal number of proton-binding sites on the surface (0.65mmolg−1). The pKa computed for all the moss species suggested the presence of 5 major functional groups: phosphodiester, carboxyl, phosphoryl, amine and polyphenols. The results of pH-edge experiments demonstrated that B. rutabulum exhibits the highest percentage of metal adsorption and has the highest number of available sites for most of the metals studied. However, according to the results of the constant pH “Langmuirian” isotherm, Sphagnum sp. can be considered as the strongest adsorbent, although the relative difference from other mosses is within 20%. The LPM was found to satisfactorily fit the experimental data in the full range of the studied solution parameters. The results of this study demonstrate a rather similar pattern of five metal adsorptions on mosses, both as a function of pH and as a metal concentration, which is further corroborated by similar values of adsorption constants. Therefore, despite the species and geographic differences between the mosses, a universal adsorption edge and constant pH adsorption isotherm can be recommended for 4 studied mosses. The quantitative comparison of metal adsorption with other common natural organic and inorganic materials demonstrates that mosses are among the most efficient natural adsorbents of heavy metals

Cooling of the Martian thermosphere by CO(2) radiation and gravity waves: an intercomparison study with two general circulation models

©2015. American Geophysical Union. All Rights Reserved. Observations show that the lower thermosphere of Mars (∼100-140 km) is up to 40 K colder than the current general circulation models (GCMs) can reproduce. Possible candidates for physical processes missing in the models are larger abundances of atomic oxygen facilitating stronger CO2 radiative cooling and thermal effects of gravity waves. Using two state-of-the-art Martian GCMs, the Laboratoire de Météorologie Dynamique and Max Planck Institute models that self-consistently cover the atmosphere from the surface to the thermosphere, these physical mechanisms are investigated. Simulations demonstrate that the CO2 radiative cooling with a sufficiently large atomic oxygen abundance and the gravity wave-induced cooling can alone result in up to 40 K colder temperature in the lower thermosphere. Accounting for both mechanisms produce stronger cooling at high latitudes. However, radiative cooling effects peak above the mesopause, while gravity wave cooling rates continuously increase with height. Although both mechanisms act simultaneously, these peculiarities could help to further quantify their relative contributions from future observations.The work was partially supported by German Science Foundation (DFG) grant ME2752/3-1. F.G.G. was funded by a CSIC JAE-Doc contract cofinanced by the European Social Fund. F.G.G. thanks the Spanish MICINN for funding support through the CONSOLIDER program ASTROMOL CSD2009-00038, and through project AYA2011-23552/ESP. E.Y. was partially supported by NASA grant NNX13AO36G.Peer Reviewe

New Fundamental Symmetries of Integrable Systems and Partial Bethe Ansatz

We introduce a new concept of quasi-Yang-Baxter algebras. The quantum quasi-Yang-Baxter algebras being simple but non-trivial deformations of ordinary algebras of monodromy matrices realize a new type of quantum dynamical symmetries and find an unexpected and remarkable applications in quantum inverse scattering method (QISM). We show that applying to quasi-Yang-Baxter algebras the standard procedure of QISM one obtains new wide classes of quantum models which, being integrable (i.e. having enough number of commuting integrals of motion) are only quasi-exactly solvable (i.e. admit an algebraic Bethe ansatz solution for arbitrarily large but limited parts of the spectrum). These quasi-exactly solvable models naturally arise as deformations of known exactly solvable ones. A general theory of such deformations is proposed. The correspondence ``Yangian --- quasi-Yangian'' and ``$XXX$ spin models --- quasi-$XXX$ spin models'' is discussed in detail. We also construct the classical conterparts of quasi-Yang-Baxter algebras and show that they naturally lead to new classes of classical integrable models. We conjecture that these models are quasi-exactly solvable in the sense of classical inverse scattering method, i.e. admit only partial construction of action-angle variables.Comment: 49 pages, LaTe

A comparison of different antibiotic regimens for the treatment of infective endocarditis.

Infective endocarditis is a microbial infection of the endocardial surface of the heart. Antibiotics are the cornerstone of treatment, but due to the differences in presentation, populations affected, and the wide variety of micro-organisms that can be responsible, their use is not standardised. This is an update of a review previously published in 2016. Objectives: To assess the existing evidence about the clinical benefits and harms of different antibiotics regimens used to treat people with infective endocarditis. Search methods: We searched the Cochrane Central Register of Controlled Trials (CENTRAL), MEDLINE, Embase Classic and Embase, LILACS, CINAHL, and the Conference Proceedings Citation Index - Science on 6 January 2020. We also searched three trials registers and handsearched the reference lists of included papers. We applied no language restrictions. Selection criteria: We included randomised controlled trials (RCTs) assessing the effects of antibiotic regimens for treating definitive infective endocarditis diagnosed according to modified Duke's criteria. We considered all-cause mortality, cure rates, and adverse events as the primary outcomes. We excluded people with possible infective endocarditis and pregnant women. Data collection and analysis: Two review authors independently performed study selection, 'Risk of bias' assessment, and data extraction in duplicate. We constructed 'Summary of findings' tables and used GRADE methodology to assess the quality of the evidence. We described the included studies narratively. Main results: Six small RCTs involving 1143 allocated/632 analysed participants met the inclusion criteria of this first update. The included trials had a high risk of bias. Three trials were sponsored by drug companies. Due to heterogeneity in outcome definitions and different antibiotics used data could not be pooled. The included trials compared miscellaneous antibiotic schedules having uncertain effects for all of the prespecified outcomes in this review. Evidence was either low or very low quality due to high risk of bias and very low number of events and small sample size. The results for all-cause mortality were as follows: one trial compared quinolone (levofloxacin) plus standard treatment (antistaphylococcal penicillin (cloxacillin or dicloxacillin), aminoglycoside (tobramycin or netilmicin), and rifampicin) versus standard treatment alone and reported 8/31 (26%) with levofloxacin plus standard treatment versus 9/39 (23%) with standard treatment alone; risk ratio (RR) 1.12, 95% confidence interval (CI) 0.49 to 2.56. One trial compared fosfomycin plus imipenem 3/4 (75%) versus vancomycin 0/4 (0%) (RR 7.00, 95% CI 0.47 to 103.27), and one trial compared partial oral treatment 7/201 (3.5%) versus conventional intravenous treatment 13/199 (6.53%) (RR 0.53, 95% CI 0.22 to 1.31). The results for rates of cure with or without surgery were as follows: one trial compared daptomycin versus low-dose gentamicin plus an antistaphylococcal penicillin (nafcillin, oxacillin, or flucloxacillin) or vancomycin and reported 9/28 (32.1%) with daptomycin versus 9/25 (36%) with low-dose gentamicin plus antistaphylococcal penicillin or vancomycin; RR 0.89, 95% CI 0.42 to 1.89. One trial compared glycopeptide (vancomycin or teicoplanin) plus gentamicin with cloxacillin plus gentamicin (13/23 (56%) versus 11/11 (100%); RR 0.59, 95% CI 0.40 to 0.85). One trial compared ceftriaxone plus gentamicin versus ceftriaxone alone (15/34 (44%) versus 21/33 (64%); RR 0.69, 95% CI 0.44 to 1.10), and one trial compared fosfomycin plus imipenem versus vancomycin (1/4 (25%) versus 2/4 (50%); RR 0.50, 95% CI 0.07 to 3.55). The included trials reported adverse events, the need for cardiac surgical interventions, and rates of uncontrolled infection, congestive heart failure, relapse of endocarditis, and septic emboli, and found no conclusive differences between groups (very low-quality evidence). No trials assessed quality of life. Authors' conclusions: This first update confirms the findings of the original version of the review. Limited and low to very low-quality evidence suggests that the comparative effects of different antibiotic regimens in terms of cure rates or other relevant clinical outcomes are uncertain. The conclusions of this updated Cochrane Review were based on few RCTs with a high risk of bias. Accordingly, current evidence does not support or reject any regimen of antibiotic therapy for the treatment of infective endocarditis.post-print876 K

A Mixed Hybrid Algorithm for Integral Wind Farm Optimum Design

. Nowadays, the weight of the generation of renewable energies has grown spectacularly with regard to other conventional energies. This is due to diverse factors: a bigger environmental concern (Kyoto protocol, white-book in EU, etc.), the raising prices of the traditional fuels, etc. On the other hand, wind power has experienced a bigger grown, among the renewable energies. That is why the development of an effective tool for the design and lay-out of wind farms has a special relevance. This paper present a mix of evolutionary algorithms to look for the optimum integral design of the wind park taking into account all the part involved: number of wind generators, the type and the height of the wind generators, its location, the number and location of substations, the best layout of lowvoltage and high-voltage lines among wind generators, substations and the existing transmission lines, etc. Due to problem complexity, and as a first approach, the global optimization problem has been splitted in two main (uncoupled) parts, first the wind generators lay out and then the network configurationMinisterio de Ciencia y Tecnología ENE2004-03342/CONMinisterio de Ciencia y Tecnología DPI2002-04416-C04-02Junta de Andalucía ACC-1021-TIC-200

Citrus phenylpropanoids and defence against pathogens. Part I: Metabolic profiling in elicited fruits

Penicillium spp. are among the major postharvest pathogens of citrus fruit. Induction of natural resistance in fruits constitutes one of the alternatives to chemical fungicides. Here, we investigated the involvement of the phenylpropanoid pathway in the induction of resistance in Navelate oranges by examining changes in the metabolic profile of upon eliciting citrus fruits. By using both HPLC-PDA-FD and HPLC-PDA-QTOF-MS allowed the identification of several compounds that seem to be relevant for induced resistance. In elicited fruits, a greater diversity of phenolic compounds was observed in the flavedo (outer coloured part of the peel) when compared to the albedo (inner white part). Moreover, only small changes were detected in the most abundant citrus flavonoids. The coumarin scoparone was among the compounds with the highest induction upon elicitation. Two other highly induced compounds were identified as citrusnin A and drupanin aldehyde. All three compounds are known to exert antimicrobial activity. Our results suggest that phenylpropanoids and their derivatives play an important role in the induction of resistance in citrus fruit.This work was supported by Research Grants AGL2008-04828-C03-02, AGL2009-11969 and CONSOLIDER FUNC-FOOD from the Spanish Ministry of Science and Technology, and PROMETEO/2010/010 from the Generalitat Valenciana.Peer Reviewe

Effect Of Fixative Type And Fixation Time On The Morphology Of Equine Preantral Ovarian Follicles

The aim of this study was to investigate the efficacy of the tissue fixatives Bouin, Carnoy and 10% Formaldehyde in equine ovarian fragments. Ovaries (n=4) from mares of mixed breeds were obtained at a local slaughterhouse and transported at 20 oC in a thermo container. Immediately after collection, the ovaries were washed with a modified PBS solution (CultilabR, Campinas-SP, Brazil) and divided into nine fragments with approximately 5x5x1 mm, removed from the parenchyma of each ovary. The ovarian fragments were then immersed in three different fixatives, Bouin (B) Carnoy (C) or 10% Formaldehyde (F) for 6, 12 or 24 hours. Each fragment was individually immersed in a 20 mL tube containing 20 times the volume of fixative solution. After this period, the fragments were held in 70% ethanol for 24 hours. Each procedure was performed in four replicates. For histological analysis, the specimens were dehydrated in increasing concentrations of alcohol, submitted to diaphanization in xylol and embedded in paraffin. Serial sections of 5 'Êm were made with the use of a rotating microtome (LeicaR type, Wetzlar, Germany), followed by slide mounting and staining with periodic acid-Schiff (PAS) and hematoxylin. A total of 540 slides with 1,620 sections were evaluated, which contained 465 preantral follicles that were classified as normal or degenerated. Follicles were considered as degenerated when presented at least one of the following aspects: cytoplasm retraction, pyknotic nucleus, cytoplasmic vacuoles, displacement of granulosa cells and/or disruption of the basal membrane. A logistic regression test was used for statistical analysis, and differences were considered significant when P<0.05. The Carnoy fixative, when used for 24 hours, provided the best conditions of morphological integrity (53.3%; 32/60) compared to all others, and the use of Boiun for 24 hours was considered the worst treatment (19.1%; 9/47). The other treatments lead to the following results: C12h 50% (30/60), C6 H 40% (24/60), F24h 37.8% (17/45), F12h 35.1% (13/37), F6h 32% (16/50), B12h 30.5% (18/59) and B6h 24.4% (11/45). Therefore, we suggest that fixation of equine ovarian tissue with Carnoy for 24 hours is the most suitable protocol for morphological preservation of pre-antral follicles.37124325

Wormholes and Ringholes in a Dark-Energy Universe

The effects that the present accelerating expansion of the universe has on the size and shape of Lorentzian wormholes and ringholes are considered. It is shown that, quite similarly to how it occurs for inflating wormholes, relative to the initial embedding-space coordinate system, whereas the shape of the considered holes is always preserved with time, their size is driven by the expansion to increase by a factor which is proportional to the scale factor of the universe. In the case that dark energy is phantom energy, which is not excluded by present constraints on the dark-energy equation of state, that size increase with time becomes quite more remarkable, and a rather speculative scenario is here presented where the big rip can be circumvented by future advanced civilizations by utilizing sufficiently grown up wormholes and ringholes as time machines that shortcut the big-rip singularity.Comment: 11 pages, RevTex, to appear in Phys. Rev.