Data on granulometric composition of calcium phosphate obtained by dispersion method

The kinetics of calcium phosphate crystallization from model solutions of saliva and liquid phase of dental plaque has been studied by the dispersion method. It was found that the composition of the saliva model system is favorable for the growth of larger crystals. The size of the particles in crystallization varies nonlinearly. As supersaturation grows, the amount of formed particles increases, however, the average rate of crystallite growth decreases

Bio resorbability of the modified hydroxyapatite in Tris-HCL buffer

The solubility of carbonated hydroxyapatite powders and granulated carbonated hydroxyapatite produced from the synovial biofluid model solution has been studied. The kinetic characteristics of dissolution were determined. It was found that the solubility of carbonated hydroxyapatite is higher as compared to that of hydroxyapatite. The impact of the organic matrix on the rate of sample dissolution was revealed. For HA-gelatin composites, as the gelatin concentration grows, the dissolution rate becomes greater, and a sample of 6.0 g / L concentration has higher resorbability. The results of the research can be used to study the kinetics of dissolution and the biocompatibility of ceramic materials for medicine, namely for reconstructive surgery, dentistry, and development of drug delivery systems

Lower Eocene sedimentary succession and microfossil biostratigraphy in the central northern Caucasus basin

The lower Eocene sediments from the classical Paleogene section exposed along the Kheu River, northern Caucasus, southern Russia are here studied. This ca. 50m thick succession is lithologically contrasting: the lower and upper parts are composed by soft marls separated by a thick Radiolaria-rich unit of non-calcareous and low-calcareous mudstones with intercalations of compact cherty layers. According to nannofossil and dinocyst biostratigraphy, the unique intercalation of Total Organic Carbon (TOC)-rich sediment (sapropelitic bed) in the lower part of the lower Eocene correspond to the Paleocene-Eocene Thermal Maximum (PETM) and a series of sapropelitic interlayers in the upper marly part of the lower Eocene succession correlates with the Early Eocene Climatic Optimum (EECO). The study of nannofossil and dinocyst assemblages enabled detailed zonal subdivision and first-order calibration of nannofossil and dinocyst bio-events during this time-span. The studied interval of the section embraces the complete succession of nannofossil zones NP9-NP13 of Martini, 1971, CP8-CP11 of Okada and Bukry, 1980 and CNP11-CNE5 of Agnini et al., 2014. By means of dinocyst stratigraphy, the succession of Apectodinium hyperacanthum, Axiodinium augustum, Deflandrea oebisfeldensis, Dracodinium astra, Stenodinium meckelfeldense, Dracodinium varielongitudum, Ochetodinium romanum/Samlandia chlamydophora and Areosphaeridium diktyoplokum zones are identified in the Ypresian part of the Kheu section

Study of thermal effects of silicate-containing hydroxyapatites

The possibility of modifications of hydroxyapatite silicate ions, from the extracellular fluid prototype solution under near-physiological conditions has been studied. Formation of silicon-structured hydroxyapatite with different extent of substitution of phosphate groups in the silicate group has been established through chemical and X-ray diffraction analyses, FTIR spectroscopy and optical microscopy. The results obtained are in agreement and suggest the possibility of substitution of phosphate groups for silicate groups in the hydroxyapatite structure when introducing different sources of silica, tetraethoxysilane and sodium silicate, in the reaction mixture. Growth in the amount of silicon in Si-HA results in the increase in the thermal stability of the samples. The greatest mass loss occurs at temperatures in the range of 25-400 °С that is caused by the removal of the crystallization and adsorption water and volatile impurities. It is shown that the modified apatites are of imperfect structure and crystallize in a nanocrystalline state

Lower Eocene sedimentary succession and microfossil biostratigraphy in the central northern Caucasus basin

The lower Eocene sediments from the classical Paleogene section exposed along the Kheu River, northern Caucasus, southern Russia are here studied. This ca. 50m thick succession is lithologically contrasting: the lower and upper parts are composed by soft marls separated by a thick Radiolaria-rich unit of non-calcareous and low-calcareous mudstones with intercalations of compact cherty layers. According to nannofossil and dinocyst biostratigraphy, the unique intercalation of Total Organic Carbon (TOC)-rich sediment (sapropelitic bed) in the lower part of the lower Eocene correspond to the Paleocene-Eocene Thermal Maximum (PETM) and a series of sapropelitic interlayers in the upper marly part of the lower Eocene succession correlates with the Early Eocene Climatic Optimum (EECO). The study of nannofossil and dinocyst assemblages enabled detailed zonal subdivision and first-order calibration of nannofossil and dinocyst bio-events during this time-span. The studied interval of the section embraces the complete succession of nannofossil zones NP9-NP13 of Martini, 1971, CP8-CP11 of Okada and Bukry, 1980 and CNP11-CNE5 of Agnini et al., 2014. By means of dinocyst stratigraphy, the succession of Apectodinium hyperacanthum, Axiodinium augustum, Deflandrea oebisfeldensis, Dracodinium astra, Stenodinium meckelfeldense, Dracodinium varielongitudum, Ochetodinium romanum/Samlandia chlamydophora and Areosphaeridium diktyoplokum zones are identified in the Ypresian part of the Kheu section

Study of thermal effects of silicate-containing hydroxyapatites

The possibility of modifications of hydroxyapatite silicate ions, from the extracellular fluid prototype solution under near-physiological conditions has been studied. Formation of silicon-structured hydroxyapatite with different extent of substitution of phosphate groups in the silicate group has been established through chemical and X-ray diffraction analyses, FTIR spectroscopy and optical microscopy. The results obtained are in agreement and suggest the possibility of substitution of phosphate groups for silicate groups in the hydroxyapatite structure when introducing different sources of silica, tetraethoxysilane and sodium silicate, in the reaction mixture. Growth in the amount of silicon in Si-HA results in the increase in the thermal stability of the samples. The greatest mass loss occurs at temperatures in the range of 25-400 °С that is caused by the removal of the crystallization and adsorption water and volatile impurities. It is shown that the modified apatites are of imperfect structure and crystallize in a nanocrystalline state

Crystallization of modified hydroxyapatite on titanium implants

Carbonated-hydroxyapatite (CHA) and Si-hydroxyapatite (Si-HA) precipitation have been synthesized from the model bioliquid solutions (synovial fluid and SBF). It is found that all the samples synthesized from the model solutions are single-phase and represent hydroxyapatite. The crystallization of the modified hydroxyapatite on alloys of different composition, roughness and subjected to different treatment techniques was investigated. Irradiation of the titanium substrates with the deposited biomimetic coating can facilitate further growth of the crystal and regeneration of the surface

Physics and chemistry of producing silicon-hydroxylapatite-titanium composite materials

In the research, Si-HA poweders have been synthesized using SBF solution with different content of silicon. It was found that all the samples synthesized from the model solution of extracellular fluid under varying concentration of silicate ions are single-phase and repesent hydroxyapatite. The nature of the reagent containing SiO[44]- ions does not affect the hydroxyapatite structure. In the study of the surface and morphological characteristics of the phosphate coatings modified by silicon ions, it was found that as the degree of phosphate calcium substitution by SiO[44]- ions increases, the surface wettability on the titanium substrates deteriorates and cohesive energy decreases. It is shown that the titanium coating is formed in three stages. After irradiation of titanium substrates coated with Si-HA, the crystals can keep growing and the surface can keep regenerating

Data on granulometric composition of calcium phosphate obtained by dispersion method

The kinetics of calcium phosphate crystallization from model solutions of saliva and liquid phase of dental plaque has been studied by the dispersion method. It was found that the composition of the saliva model system is favorable for the growth of larger crystals. The size of the particles in crystallization varies nonlinearly. As supersaturation grows, the amount of formed particles increases, however, the average rate of crystallite growth decreases

Effect of cations (Mg2+, Zn2+, Cd2+) on formation of the mineral phase in Ca(NO3)2-Mg(NO3)2-Na2HPO4-H2O system

Synthesis of hydroxyapatite in the system Ca(NO3)2-Me(NO3)2-NaHPO4-H2O with pH in the range of 6-12.2 is performed, and hydroxyapatite of B-type is formed. The effect of magnesium, zinc and cadmium ions on the properties of hydroxyapatite is studied. It is shown that as the concentration of these ions increases, the crystallinity of hydroxyapatite and the Ca/P ratio decreases. It is found that in all the experiments Zn2+ cations affect the hydroxyapatite structure to a lesser extent which results in less structural defects, wherein the Ca/P ratio attains the highest values. It is shown that the solubility of the samples containing zinc ions is greater than that of the samples with other additives