The Evolution of Anodic Hydrogen on High Purity Magnesium in Acidic Buffer Solution

Hydrogen evolution (HE) on anodically polarized Mg, commonly referred to as Negative Difference Effect, was studied by galvanodynamic measurements coupled with real-time gravimetric H2 volume collection, the Scanning Vibrating Electrode Technique and potentiodynamic polarization experiments. High purity Mg (99.96% Mg) electrodes were studied in chloride-free 0.1 M citric acid solution buffered at pH with the aim of determining the source of anodic HE and the role of the corrosion film on the process. In such conditions of pH, the typical dark corrosion product exhibited in neutral and alkaline solutions was not found but the HE rate still increased with increasing potential. Evidence that HE on dissolving high purity Mg is associated with the regions dominated by the anodic dissolution reaction is provided. The role of noble impurity enrichment on the electrode surface during anodic polarization and the effect of Fe re-deposition are also discussed

Extended x-ray absorption fine structure study of porous GaSb formed by ion implantation

Porous GaSb has been formed by Ga ion implantation into crystalline GaSb substrates at either room temperature or −180 °C. The morphology has been characterized using scanning electron microscopy and the atomic structure was determined using extended x-ray absorption fine structure spectroscopy. Room-temperature implantation at low fluences leads to the formation of ∼20-nm voids though the material remains crystalline. Higher fluences cause the microstructure to evolve into a network of amorphous GaSb rods ∼15 nm in diameter. In contrast, implantation at −180 °C generates large, elongated voids but no rods. Upon exposure to air, the surface of the porous material is readily oxidized yielding Ga₂O₃ and metallic Sb precipitates, the latter resulting from the reduction of unstable Sb₂O₃. We consider and discuss the atomic-scale mechanisms potentially operative during the concurrent crystalline-to-amorphous and continuous-to-porous transformations

The formation of supermassive black holes in the first galaxies

We discuss the formation of supermassive black holes in the early universe, and how to probe their subsequent evolution with the upcoming mm/sub-mm telescope ALMA. We first focus on the chemical and radiative conditions for black hole formation, in particular considering radiation trapping and molecular dissociation effects. We then turn our attention towards the magnetic properties in the halos where the first black holes form, and show that the presence of turbulence may lead to a magnetic dynamo, which could support the black hole formation process by providing an efficient means of transporting the angular momentum. We finally focus on observable properties of high-redshift black holes with respect to ALMA, and discuss how to distinguish between chemistry driven by the starburst and chemistry driven by X-rays from the black hole.Comment: Contribution to AIP conference proceedings "First Stars and Galaxies: Challenges in the Next Decade". 4 pages, 3 figure

In vitro measurement of nucleus pulposus swelling pressure: A new technique for studies of spinal adaptation to gravity

Swelling of the intervertebral disc nucleus pulposus is altered by posture and gravity. We have designed and tested a new osmometer for in vitro determination of nucleus pulposus swelling pressure. The functional principle of the osmometer involves compressing a sample of nucleus pulposus with nitrogen gas until saline pressure gradients across a 0.45 microns Millipore filter are eliminated. Swelling pressure of both pooled dog and pooled pig lumbar disc nucleus pulposus were measured on the new osmometer and compared to swelling pressures determined using the equilibrium dialysis technique. The osmometer measured swelling pressures comparable to those obtained by the dialysis technique. This osmometer provides a rapid, direct, and accurate measurement of swelling pressure of the nucleus pulposus

NNLO QCD corrections to event shape variables in electron positron annihilation

Precision studies of QCD at electron-positron colliders are based on measurements of event shapes and jet rates. To match the high experimental accuracy, theoretical predictions to next-to-next-to-leading order (NNLO) in QCD are needed for a reliable interpretation of the data. We report the first calculation of NNLO corrections O(alpha_s^3) to three-jet production and related event shapes, and discuss their phenomenological impact.Comment: Contributed to 2007 Europhysics Conference on High Energy Physics, Manchester, England 19-25 July 200

Dynamic fluctuations in the superconductivity of NbN films from microwave conductivity measurements

We have measured the frequency and temperature dependences of complex ac conductivity, \sigma(\omega)=\sigma_1(\omega)-i\sigma_2(\omega), of NbN films in zero magnetic field between 0.1 to 10 GHz using a microwave broadband technique. In the vicinity of superconducting critical temperature, Tc, both \sigma_1(\omega) and \sigma_2(\omega) showed a rapid increase in the low frequency limit owing to the fluctuation effect of superconductivity. For the films thinner than 300 nm, frequency and temperature dependences of fluctuation conductivity, \sigma(\omega,T), were successfully scaled onto one scaling function, which was consistent with the Aslamazov and Larkin model for two dimensional (2D) cases. For thicker films, \sigma(\omega,T) data could not be scaled, but indicated that the dimensional crossover from three dimensions (3D) to 2D occurred as the temperature approached Tc from above. This provides a good reference of ac fluctuation conductivity for more exotic superconductors of current interest.Comment: 8 pages, 7 Figures, 1 Table, Accepted for publication in PR