Olhar, lugar, vazio: o teatro crítico de Raúl Antelo

O artigo propõe um breve comentário sobre a obra crítica do professor e pesquisador Raúl Antelo, que é aqui apresentada em termos de um singular teatro crítico, para o qual as categorias de olhar, de lugar e de vazio têm importância fundamental. Através de algumas referências a essa obra, contidas em textos publicados entre os anos 2000 e 2014, bem como também a suas principais fontes de inspiração teórica, estudar-se-á a maneira como, nela, a complexa articulação entre experiência e experimentação promove uma renovação dos lugares do sujeito e do objeto, polos tradicionais do exercício do conhecimento

FRANÇA-BRASIL: ELEMENTOS PARA UMA RELAÇÃO

This paper analyses the French presence in Brazilian Literature and Culture, from the romanticism with its indianism à la Chateaubriand to the Modernism with Oswald de Andrade and Tarsila do Amaral. As in any contact between different peoples, the dialogue Brazil-France has its weak and strong times; in the last one, we can include two important “French missions”, the 1816’s one and the 1934’s one. There is a reflexion on the role of teaching/learning French in Brazil as well as on the issue of French language in the colonial context, through some ideas developed by Derrida and Glissant.Este texto enfoca a presença francesa na literatura e na cultura brasileiras, do romantismo com seu indianismo à la Chateaubriand até o modernismo de oswald de Andrade e tarsila do Amaral. Como todo contato entre povos, o diálogo entre o brasil e a França tem seus tempos fracos e seus tempos fortes; nestes, incluem-se duas importantes “missões francesas”, a de 1816 e a de 1934. Também se busca refletir sobre o papel do ensino do francês no brasil ou no eixo das relações coloniais, a partir do pensamento de autores como Derrida e Glissant

ESCRITA TRADUTÓRIA E ESCRITA LITERÁRIA: ENTREVISTA COM PAULA GLENADEL

O primeiro livro de poemas de Paula Glenadel, "A vida espiralada" (Caetés), data de 1999, três anos após a conclusão do seu doutorado na UFRJ. Em 2005 é lançado "Quase uma arte" (Cosac & Naify), e, em 2008, "A fábrica do feminino" (7Letras). Em 2014, aparece "Rede" (Confraria do Vento). Paralelamente à escrita literária, Paula Glenadel dedica-se à pesquisa acadêmica e à tradução. Michel Deguy, Jacques Roubaud e Nathalie Quintane são alguns dos autores que já traduziu. Nessa entrevista, procuramos explorar as relações, tensões e reverberações que a autora enxerga (e vivencia) entre a escrita tradutória e a escrita literária

Ressurgência barroca: estilo e tradução cultural em Jacques Derrida

Considering the possibility of developing a reflection on the Baroque in all its potential as the preserver of desconstructive marginalities of knowledge and identity, observed from a LatinAmerican condition, this paper proposes a critical approach based on some Derrida's theoretical contributions, which resist to Eurocentrism, manifest an acceptance of dialogue with an "ailleurs", a translation of an "outside", meeting some places of transcendance haunting CrecoLatin-Western culture "itself"

Nouvelles avancées en trifluorométhylthiolation et fluoroalkylsélénolation

Organofluorine compounds are widely known for their various applications (e.g. pharmaceutical and agrochemical industry, materials) whereas only a dozen have been identified in nature. This difference is due to the unique properties of the fluorine atom: lipophilicity, metabolic stability, conformation, etc. The combination of heteroatoms with a fluorinated moiety is able to modulate theses properties. Therefore, since early 2010s, many efforts have been devoted to introduce the SCF3 moiety onto molecules. This substituent shows high lipophilicity (Hansch Leo parameter: p = 1,44). By the end of 2000s, the Billard’s group developed reagents, named trifluoromethanesulfenamides, able to perform trifluoromethylthiolation on a large range of nucleophiles in a direct and electrophilic fashion. Recently, the « second generation » of trifluoromethanesulfenamides has demonstrated another reactivity. Indeed, in the presence of iodide anion, the polarity of the sulfur atom is inverted allowing reactions with electrophiles. Therefore, this stable reagent is able to react with both electrophiles and nucleophiles.Selenium constitutes an essential nutriment to humans. However, only a few methodologies have been developed to introduce SeRf moieties onto molecules. Lately, our group has reported the synthesis of diverse pre reagents able to perform the fluoroalkylselenolation of various nucleophiles in a direct and electrophilic fashion. The range of fluoroalkylselenolated moieties offers modulation of molecules’ physicochemical properties. Finally and for the first time, the Hansch Leo parameter of SeCF3 moiety has been measured (p = 1,29 ± 0,14), establishing this substituent as one of the most lipophilic ones. Many recent advances have been made and published on the topic but there is clearly room for improvement. Therefore, further efforts need to be dedicated for the development of new methodologies and reagentsLes molécules organiques fluorées sont de plus en plus représentées dans une grande diversité de domaines (e.g. industrie pharmaceutique et agroalimentaire, matériaux, etc.) malgré leur faible occurrence dans la nature. Ceci est dû aux propriétés uniques de l’atome de fluor : lipophilie, stabilité métabolique, conformation, etc. L’association d’un groupement fluoré avec un hétéroatome permet d’obtenir de nouvelles propriétés. C’est pourquoi au début des années 2010, certains groupes de recherche se sont focalisés sur la chimie du SCF3 et son introduction sur des molécules organiques. En effet, ce motif présente un des caractères lipophiles les plus élevés (paramètre de Hansch Leo : p = 1,44). A la fin des années 2000, le groupe de Thierry Billard a développé une série de réactifs, les trifluorométhanesulfénamides, permettant de trifluorométhylthioler de manière directe et électrophile une large gamme de nucléophiles. Récemment, nous avons démontré que la « seconde génération » des trifluorométhanesulfénamides pouvait réagir de manière nucléophile par inversion de polarité en présence d’iodures. Ce réactif stable en condition aérobie présente donc deux réactivités différentes suivant les conditions de la réaction.Contrairement à son analogue soufré, très peu de méthodologies ont été développées afin d’introduire le motif SeRf sur des molécules bien que le sélénium constitue un nutriment essentiel chez l’être humain. L’année dernière, nous avons rapporté la synthèse d’une série de pré réactifs permettant la fluoroalkylsélénolation directe et électrophile de divers nucléophiles. La diversité des groupements fluoroalkylséléniés permet donc d’obtenir une modulation des propriétés physico chimiques. Enfin, le paramètre de Hansch Leo de SeCF3 a été mesuré pour la première fois (p = 1,29 ± 0,14) et montre que ce motif est l’un des plus lipophiles derrière son analogue soufré. Bien que des avancées majeures aient été réalisées récemment, la marge de progression autour de cette chimie est encore grande. C’est pourquoi il faut continuer les efforts dans le développement de nouveaux réactifs et de nouvelles méthodologie