14 research outputs found
Numerical assessment of diffusion-convection-reaction model for the catalytic abatement of phenolic wastewaters in packed-bed reactors under trickling flow conditions
Computational Fluid Dynamics (CFD) modeling of trickle-bed reactors with detailed
interstitial flow solvers has remained elusive mostly due to the extreme CPU and memory
intensive constraints. Here, we developed a comprehensible and scalable CFD model based
on the conservative unstructured finite volume methodology to bring new insights from the
perspective of catalytic reactor engineering to gas-liquid-solid catalytic wet oxidation. First,
the heterogeneous flow constitutive equations of the trickle bed system have been derived by
means of diffusion-convection-reaction model coupled within a Volume-of-Fluid framework.
The multiphase model was investigated to gain further evidence on how the effect of process
variables such as liquid velocity, surface tension and wetting phenomena affect the overall
performance of high-pressure trickle-bed reactor. Second, as long as the application of underrelaxation
parameters, mesh density, and time stepping strategy play a major role on the final
corroboration, several computational runs on the detoxification of liquid pollutants were
validated accordingly and evaluated in terms of convergence and stability criteria. Finally, the
analysis of spatial mappings for the reaction properties enables us to identify the existence of
relevant dry zones and unveil the channeling phenomena within in the trickle-bed reactor
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Strategies for enhancing the effectiveness of metagenomic-based enzyme discovery in lignocellulytic microbial communities
Producing cellulosic biofuels from plant material has recently emerged as a key U.S. Department of Energy goal. For this technology to be commercially viable on a large scale, it is critical to make production cost efficient by streamlining both the deconstruction of lignocellulosic biomass and fuel production. Many natural ecosystems efficiently degrade lignocellulosic biomass and harbor enzymes that, when identified, could be used to increase the efficiency of commercial biomass deconstruction. However, ecosystems most likely to yield relevant enzymes, such as tropical rain forest soil in Puerto Rico, are often too complex for enzyme discovery using current metagenomic sequencing technologies. One potential strategy to overcome this problem is to selectively cultivate the microbial communities from these complex ecosystems on biomass under defined conditions, generating less complex biomass-degrading microbial populations. To test this premise, we cultivated microbes from Puerto Rican soil or green waste compost under precisely defined conditions in the presence dried ground switchgrass (Panicum virgatum L.) or lignin, respectively, as the sole carbon source. Phylogenetic profiling of the two feedstock-adapted communities using SSU rRNA gene amplicon pyrosequencing or phylogenetic microarray analysis revealed that the adapted communities were significantly simplified compared to the natural communities from which they were derived. Several members of the lignin-adapted and switchgrass-adapted consortia are related to organisms previously characterized as biomass degraders, while others were from less well-characterized phyla. The decrease in complexity of these communities make them good candidates for metagenomic sequencing and will likely enable the reconstruction of a greater number of full length genes, leading to the discovery of novel lignocellulose-degrading enzymes adapted to feedstocks and conditions of interest
Magnetic resonance imaging (MRI): a technique to study flow an microstructure of concentrated emulsions
Nuclear magnetic resonance (NMR) and magnetic resonance imaging (MRI) have recently been recognized as important techniques for R&D of products and processes, as is attested by several successful applications in different areas of chemical engineering in recent years. In this article we present new experimental methods based on MRI to study flow and microstructure of concentrated emulsions. The objective is to present the unique features of this noninvasive technique to accurately measure different properties of flowing particulate opaque systems. Experimental results of velocity profiles, spatial distribution of droplet sizes and spatial homogeneity of an oil-in-water dispersion in a horizontal, concentric cylinder geometry using different pulse sequences are presented. The application of these techniques allowed probing important information on flow and microstructure of multiphase systems of interest in chemical engineering and food science