Non-Adiabatic Spin Transfer Torque in Real Materials

The motion of simple domain walls and of more complex magnetic textures in the presence of a transport current is described by the Landau-Lifshitz-Slonczewski (LLS) equations. Predictions of the LLS equations depend sensitively on the ratio between the dimensionless material parameter $\beta$ which characterizes non-adiabatic spin-transfer torques and the Gilbert damping parameter $\alpha$. This ratio has been variously estimated to be close to 0, close to 1, and large compared to 1. By identifying $\beta$ as the influence of a transport current on $\alpha$, we derive a concise, explicit and relatively simple expression which relates $\beta$ to the band structure and Bloch state lifetimes of a magnetic metal. Using this expression we demonstrate that intrinsic spin-orbit interactions lead to intra-band contributions to $\beta$ which are often dominant and can be (i) estimated with some confidence and (ii) interpreted using the "breathing Fermi surface" model.Comment: 18 pages, 9 figures; submitted to Phys. Rev.

Method and apparatus for the synthesis of dihydroartemisinin and artemisinin derivatives

The present invention is directed to a method for continuous production of dihydroartemisinin and also artemisinin derivatives derived from dihydroartemisinin by using artemisinin or dihydroartemisinic acid (DHAA) as starting material as well as to a continuous flow reactor for producing dihydroartemisinin as well as the artemisinin derivatives. It was found that the reduction of artemisinin to dihydroartemisinin in a continuous process requires a special kind of reactor and a special combination of reagents comprising a hydride reducing agent, at least one activator such as an inorganic activator, at least one solid base, at least one aprotic solvent and at least one C1-C5 alcohol

Identification of the dominant precession damping mechanism in Fe, Co, and Ni by first-principles calculations

The Landau-Lifshitz equation reliably describes magnetization dynamics using a phenomenological treatment of damping. This paper presents first-principles calculations of the damping parameters for Fe, Co, and Ni that quantitatively agree with existing ferromagnetic resonance measurements. This agreement establishes the dominant damping mechanism for these systems and takes a significant step toward predicting and tailoring the damping constants of new materials.Comment: 4 pages, 1 figur

The Tamm-Dancoff Approximation as the boson limit of the Richardson-Gaudin equations for pairing

A connection is made between the exact eigen states of the BCS Hamiltonian and the predictions made by the Tamm-Dancoff Approximation. This connection is made by means of a parametrised algebra, which gives the exact quasi-spin algebra in one limit of the parameter and the Heisenberg-Weyl algebra in the other. Using this algebra to construct the Bethe Ansatz solution of the BCS Hamiltonian, we obtain parametrised Richardson-Gaudin equations, leading to the secular equation of the Tamm-Dancoff Approximation in the bosonic limit. An example is discussed in depth.Comment: Submitted to the proceedings of the Group28 conference (Newcastle-upon-Tyne, UK). Journal of Physics: Conference Serie

Remote participation during glycosylation reactions of galactose building blocks: Direct evidence from cryogenic vibrational spectroscopy

The stereoselective formation of 1,2‐cis‐glycosidic bonds is challenging. However, 1,2‐cis‐selectivity can be induced by remote participation of C4 or C6 ester groups. Reactions involving remote participation are believed to proceed via a key ionic intermediate, the glycosyl cation. Although mechanistic pathways were postulated many years ago, the structure of the reaction intermediates remained elusive owing to their short‐lived nature. Herein, we unravel the structure of glycosyl cations involved in remote participation reactions via cryogenic vibrational spectroscopy and first principles theory. Acetyl groups at C4 ensure α‐selective galactosylations by forming a covalent bond to the anomeric carbon in dioxolenium‐type ions. Unexpectedly, also benzyl ether protecting groups can engage in remote participation and promote the stereoselective formation of 1,2‐cis‐glycosidic bonds

Applying the National Health Educator Competencies Update Project Model to Health Education

A brief overview of the six-year National Health Educator Competencies Update Project (CUP) research is provided as an introduction to a discussion of applications of the resulting CUP Hierarchical Model. Considerations for application of the model to the professional preparation, credentialing and professional development of health educators are explored. In addition, examples of the applicability of the CUP Hierarchical Model to three different work settings are presented at the Entry, Advanced 1, and Advanced 2 levels of professional practice. The benefits of being guided by a validated practice model are discussed with implications for future research endeavors

Evaluating an unconfined aquifer by analysis of age-dating tracers in stream water

The mean transit time (MTT) is a fundamental property of a groundwater flow system that is strongly related to the ratio of recharge rate to storage volume. However, obtaining samples for estimating the MTT using environmental tracers is problematic as flow-weighted samples over the full spectrum of transit times are needed. Samples collected fromthe base flow of a gaining stream in the North Carolina Coastal Plain (West Bear Creek) that were corrected for exchange with the atmosphere yielded environmental tracer concentrations (SF6 and CFC-11) very similar to flow-weighted values from nine or ten streambed piezometers that directly sampled groundwater during low streamflow. At higher streamflow on the falling limb of the hydrograph, stream tracer concentrations (after correction for gas exchange) were significantly higher than the flow-weighted mean from piezometers, consistent with dominance of the streamtracer signal by transient influx of surface water and/or younger subsurface water. The apparent MTT derived from SF6 in low flow stream water samples was 26 years, suggesting a groundwater recharge rate of about 210 mm/yr, that is consistent with vertical profiles obtained by sampling nested piezometers in the aquifer. When sampled under low flow conditions when streamflow consists of a high component of groundwater discharge, West Bear Creek appears to act as a flow-weighted integrator of transit times and, streamflow samples can provide fundamental information regarding groundwater recharge rate and MTT. Our study suggests that watershed-scale evaluation of some groundwater flow systems is possible without utilizing monitoring wells

A new low mass for the Hercules dSph: the end of a common mass scale for the dwarfs?

We present a new mass estimate for the Hercules dwarf spheroidal galaxy (dSph), based on the revised velocity dispersion obtained by Aden et al. (2009, arXiv:0908.3489). The removal of a significant foreground contamination using newly acquired Stromgren photometry has resulted in a reduced velocity dispersion. Using this new velocity dispersion of 3.72 +/- 0.91 km/s, we find a mass of M_300=1.9^{+1.1}_{-0.8} 10^6 M_sun within the central 300 pc, which is also the half-light radius, and a mass of M_433=3.7_{-1.6}^{+2.2} 10^6 M_sun within the reach of our data to 433 pc, significantly lower than previous estimates. We derive an overall mass-to-light ratio of M_433/L=103^{+83}_{-48} M_sun/L_sun. Our mass estimate calls into question recent claims of a common mass scale for dSph galaxies. Additionally, we find tentative evidence for a velocity gradient in our kinematic data of 16 +/- 3 km/s/kpc, and evidence of an asymmetric extension in the light distribution at about 0.5 kpc. We explore the possibility that these features are due to tidal interactions with the Milky Way. We show that there is a self-consistent model in which Hercules has an assumed tidal radius of r_t = 485 pc, an orbital pericentre of r_p = 18.5 +/- 5 kpc, and a mass within r_t of M_{tid,r_t}=5.2 +/- 2.7 10^6 M_sun. Proper motions are required to test this model. Although we cannot exclude models in which Hercules contains no dark matter, we argue that Hercules is more likely to be a dark matter dominated system which is currently experiencing some tidal disturbance of its outer parts.Comment: 10 pages, 3 figures, Accepted for publication by ApJ