762 research outputs found

    First-principles study of the effects of gold adsorption on the Al(001) surface properties

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    In this work, we have studied theoretically the effects of gold adsorption on the Al(001) surface, using {\it ab initio} pseudo-potential method in the framework of the density functional theory. Having found the hollow sites at the Al(001) surface as the most preferred adsorption sites, we have investigated the effects of the Au adsorption with different coverages (Θ\Theta=0.11, 0.25, 0.50, 0.75, 1.00 ML) on the geometry, adsorption energy, surface dipole moment, and the work-function of the Al(001) surface. The results show that, even though the work-function of the Al substrate increases with the Au coverage, the surface dipole moment decreases with the changes in coverage from Θ=0.11\Theta=0.11 ML to Θ=0.25\Theta=0.25 ML. We have explained this behavior by analyzing the electronic and ionic charge distributions. Furthermore, by studying the diffusion of Au atoms in to the substrate, we have shown that at room temperature the diffusion rate of Au atoms in to the substrate is negligible but, increasing the temperature to about 200^\circ C the Au atoms significantly diffuse in to the substrate, in agreement with the experiment.Comment: 19 pages, 9 eps figure

    On the algorithmic construction of classifying spaces and the isomorphism problem for biautomatic groups

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    We show that the isomorphism problem is solvable in the class of central extensions of word-hyperbolic groups, and that the isomorphism problem for biautomatic groups reduces to that for biautomatic groups with finite centre. We describe an algorithm that, given an arbitrary finite presentation of an automatic group Γ\Gamma, will construct explicit finite models for the skeleta of K(Γ,1)K(\Gamma,1) and hence compute the integral homology and cohomology of Γ\Gamma.Comment: 21 pages, 4 figure

    Soft-core meson-baryon interactions. I. One-hadron-exchange potentials

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    The Nijmegen soft-core model for the pseudoscalar-meson baryon interaction is derived, analogous to the Nijmegen NN and YN models. The interaction Hamiltonians are defined and the resulting amplitudes for one-meson-exchange and one-baryon-exchange in momentum space are given for the general mass case. The partial wave projection is carried through and explicit expressions for the momentum space partial wave meson-baryon potentials are presented.Comment: 25 pages, 2 PostScript figures, revtex4, submitted to Phys. Rev.

    Beat-wave generation of plasmons in semiconductor plasmas

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    It is shown that in semiconductor plasmas, it is possible to generate large amplitude plasma waves by the beating of two laser beams with frequency difference close to the plasma frequency. For narrow gap semiconductors (for example n-type InSb), the system can simulate the physics underlying beat wave generation in relativistic gaseous plasmas.Comment: 11 pages, LaTex, no figures, no macro

    Inversion of Randomly Corrugated Surfaces Structure from Atom Scattering Data

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    The Sudden Approximation is applied to invert structural data on randomly corrugated surfaces from inert atom scattering intensities. Several expressions relating experimental observables to surface statistical features are derived. The results suggest that atom (and in particular He) scattering can be used profitably to study hitherto unexplored forms of complex surface disorder.Comment: 10 pages, no figures. Related papers available at http://neon.cchem.berkeley.edu/~dan

    Maxwell Equations in Complex Form of Majorana - Oppenheimer, Solutions with Cylindric Symmetry in Riemann S_{3} and Lobachevsky H_{3} Spaces

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    Complex formalism of Riemann - Silberstein - Majorana - Oppenheimer in Maxwell electrodynamics is extended to the case of arbitrary pseudo-Riemannian space - time in accordance with the tetrad recipe of Tetrode - Weyl - Fock - Ivanenko. In this approach, the Maxwell equations are solved exactly on the background of static cosmological Einstein model, parameterized by special cylindrical coordinates and realized as a Riemann space of constant positive curvature. A discrete frequency spectrum for electromagnetic modes depending on the curvature radius of space and three parameters is found, and corresponding basis electromagnetic solutions have been constructed explicitly. In the case of elliptical model a part of the constructed solutions should be rejected by continuity considerations. Similar treatment is given for Maxwell equations in hyperbolic Lobachevsky model, the complete basis of electromagnetic solutions in corresponding cylindrical coordinates has been constructed as well, no quantization of frequencies of electromagnetic modes arises.Comment: 39 page

    Isospin-Violating Meson-Nucleon Vertices as an Alternate Mechanism of Charge-Symmetry Breaking

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    We compute isospin-violating meson-nucleon coupling constants and their consequent charge-symmetry-breaking nucleon-nucleon potentials. The couplings result from evaluating matrix elements of quark currents between nucleon states in a nonrelativistic constituent quark model; the isospin violations arise from the difference in the up and down constituent quark masses. We find, in particular, that isospin violation in the omega-meson--nucleon vertex dominates the class IV CSB potential obtained from these considerations. We evaluate the resulting spin-singlet--triplet mixing angles, the quantities germane to the difference of neutron and proton analyzing powers measured in elastic np\vec{n}-\vec{p} scattering, and find them commensurate to those computed originally using the on-shell value of the ρ\rho-ω\omega mixing amplitude. The use of the on-shell ρ\rho-ω\omega mixing amplitude at q2=0q^2=0 has been called into question; rather, the amplitude is zero in a wide class of models. Our model possesses no contribution from ρ\rho-ω\omega mixing at q2=0q^2=0, and we find that omega-meson exchange suffices to explain the measured npn-p analyzing power difference~at~183 MeV.Comment: 20 pages, revtex, 3 uuencoded PostScript figure

    A human MAP kinase interactome.

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    Mitogen-activated protein kinase (MAPK) pathways form the backbone of signal transduction in the mammalian cell. Here we applied a systematic experimental and computational approach to map 2,269 interactions between human MAPK-related proteins and other cellular machinery and to assemble these data into functional modules. Multiple lines of evidence including conservation with yeast supported a core network of 641 interactions. Using small interfering RNA knockdowns, we observed that approximately one-third of MAPK-interacting proteins modulated MAPK-mediated signaling. We uncovered the Na-H exchanger NHE1 as a potential MAPK scaffold, found links between HSP90 chaperones and MAPK pathways and identified MUC12 as the human analog to the yeast signaling mucin Msb2. This study makes available a large resource of MAPK interactions and clone libraries, and it illustrates a methodology for probing signaling networks based on functional refinement of experimentally derived protein-interaction maps
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