Labour Turnover and Firm Performance

We explore the impact of labour turnover on firm performance by analysing the predictions of an extension of the efficiency wage model of Salop (1979) developed by Garino and Martin (2007), which separates incumbent and newly hired workers in the production function. Within this theoretical framework, an exogenous increase in the turnover rate can increase profits if firms do not choose wages unilaterally. We test the theoretical predictions of the model using UK cross-section establishment-level data, the 2004 Workplace and Employee Relations Survey. In accordance with our theoretical priors, the empirical results support the standard inverse relationship between the quit rate and firm performance where firms unilaterally choose the wage and generally support a positive relationship between firm performance and the quit rate where trade unions influence wage setting

Dipyridylmethane ethers as ligands for luminescent Ir complexes

This work reports two new cationic heteroleptic cyclometalated iridium complexes, containing ether derivatives of di(pyridin-2-yl)methanol. The new ligands are based on dipyridin-2-ylmethane and are designed to obtain ether-based intermediates with extended electronic conjugation by insertion of π system such as phenyl, allyl and ethynyl. Different synthetic strategies were employed to introduce these units, as molecular wires, between the dipyridin-2-ylmethane chelating portion and the terminal N-containing functional group, such as amine and carbamide. The corresponding complexes show luminescence in the blue region of the spectrum, lifetimes between 0.6 and 2.1 μs, high quantum yield and good electrochemical behavior. The computational description (DFT) of the electronic structure highlights the key role of the conjugated π systems on optical and electrochemical properties of the final products

NUMISTAMP: a research project for assessment of finite-element models for stamping processes

This paper describes the objectives and current status of the research project NUMISTAMP currently under development at the International Center for Numerical Methods in Engineering of (CIMNE) located in Barcelona, Spain. The aim of this project is the assesment of different finite element models for simulation of sheet stamping processes. The models currently analyzed include: quasistatic viscoplastic flow and elastoplastic solid models and explicit dynamic models. Both shell and continuum elements are considered in most of these cases. The paper presents an overview of the basic features of the different models. Examples of application including some benchmark test cases proposed at NUMISHEET are also presented

Mesoporous Si and multi-layered Si/C films by Pulsed Laser Deposition as Li-ion microbattery anodes

Silicon is a very attractive Li-ion battery anode material due to its high theoretical capacity, but proper nanostructuring is needed to accommodate the large volume expansion/shrinkage upon reversible cycling. Hereby, novel mesoporous Si nanostructures are grown at room temperature by simple and rapid Pulsed Laser Deposition (PLD) directly on top of the Cu current collector surface. The samples are characterised from the structural/morphological viewpoint and their promising electrochemical behaviour demonstrated in lab-scale lithium cells. Depending on the porosity, easily tuneable by PLD, specific capacities approaching 250 μAh cm−2 are obtained. Successively, newly elaborated bicomponent silicon/carbon nanostructures are fabricated in one step by alternating PLD deposition of Si and C, thus resulting in novel multi-layered composite mesoporous films exhibiting profoundly improved performance. Alternated deposition of Si/C layers by PLD is proven to be a straightforward method to produce multi-layered anodes in one processing step. The addition of carbon and mild annealing at 400 °C stabilize the electrochemical performance of the Si based nanostructures in lab-scale lithium cells, allowing to reach very stable prolonged reversible cycling at improved specific capacity values. This opens the way to further reducing processing steps and processing time, which are key aspects when upscaling is sought

Angle resolved IBIC analysis of 4H-SiC Schottky diodes

We present a new experimental procedure based on the ion beam induced charge collection (IBIC) to characterise semiconductor detectors and devices. It consists in measuring the charge collection efficiency (q) as a function of the angle of incidence (eta) of a strongly penetrating MeV ion beam focussed onto a partially depleted semiconductor detector. The unidimensional model based on the drift-diffusion model derived from the Shockley-Ramo-Gunn's theorem gives the theoretical background to fit the eta(alpha) curve and to estimate both the extension of the depletion layer, the dead layer thickness and the minority carrier diffusion length. To illustrate the analytical capability of this technique, a 2 MeV proton beam was focussed at different incident angles onto a 4H-SiC Schottky diode; the experimental results and the theoretical approach are presented and discussed. (c) 2006 Published by Elsevier B.V