Surface mixing and biological activity in the four Eastern Boundary Upwelling Systems

Eastern Boundary Upwelling Systems (EBUS) are characterized by a high productivity of plankton associated with large commercial fisheries, thus playing key biological and socio-economical roles. The aim of this work is to make a comparative study of these four upwelling systems focussing on their surface stirring, using the Finite Size Lyapunov Exponents (FSLEs), and their biological activity, based on satellite data. First, the spatial distribution of horizontal mixing is analysed from time averages and from probability density functions of FSLEs. Then we studied the temporal variability of surface stirring focussing on the annual and seasonal cycle. There is a global negative correlation between surface horizontal mixing and chlorophyll standing stocks over the four areas. To try to better understand this inverse relationship, we consider the vertical dimension by looking at the Ekman-transport and vertical velocities. We suggest the possibility of a changing response of the phytoplankton to sub/mesoscale turbulence, from a negative effect in the very productive coastal areas to a positive one in the open ocean.Comment: 12 pages. NPG Special Issue on "Nonlinear processes in oceanic and atmospheric flows". Open Access paper, available also at the publisher site: http://www.nonlin-processes-geophys.net/16/557/2009

Sensitivity of ecosystem parameters to simulated satellite ocean colour data using a coupled physical-biological model of the North Atlantic

A means of assimilating simulated satellite ocean color data with a coupled physical-biological model of the North Atlantic Ocean is implemented, allowing the relative sensitivities of different biological parameters to those data to be investigated. The model consists of an eddy-permitting general circulation model derived from the WOCE Community Modeling Effort and a nitrogen-based, four-compartment NPZD marine ecosystem model. Many of the parameters in marine ecosystem models are poorly known and via assimilation, we hope to better constrain their values. The control parameters chosen for the variational assimilation are the model parameters involved in parameterizations of recycling as these are the most poorly known. Simulated observations are taken while following several floats seeded in varying dynamical biogeochemical provinces of the North Atlantic model domain over a six-month period. Twin experimental results show that, for the given functional forms of growth, mortality and grazing, the following parameters can be successfully recovered from simulated satellite ocean color data: nitrate and detrital recycling parameters in the trade wind domain, zooplankton parameters at higher latitudes (westerly wind and polar domains), and the phytoplankton mortality rate in all regions. By simultaneously assimilating ocean color data in different biological provinces, it becomes possible to successfully constrain all ecosystem parameters at once

Uso de Geotecnologias para avaliação da adequação ambiental referente às Áreas de Preservação Permanente e Reserva Legal no Município de Ribeirão Preto - SP.

No presente trabalho, através de técnicas de geoprocessamento, buscou-se delimitar as APPs na área rural do município de Ribeirão Preto, no nordeste do Estado de São Paulo, no ano de 2014 e verificar sua adequação segundo o Novo Código Florestal Brasileiro e identificar, através da classificação do uso e cobertura do solo, qual o passivo ambiental relativo às áreas de Reserva Legal no município

Multidisciplinary Observing in the World Ocean\u27s Oxygen Minimum Zone Regions: From Climate to Fish - The VOICE Initiative

Multidisciplinary ocean observing activities provide critical ocean information to satisfy ever-changing socioeconomic needs and require coordinated implementation. The upper oxycline (transition between high and low oxygen waters) is fundamentally important for the ecosystem structure and can be a useful proxy for multiple observing objectives connected to eastern boundary systems (EBSs) that neighbor oxygen minimum zones (OMZs). The variability of the oxycline and its impact on the ecosystem (VOICE) initiative demonstrates how societal benefits drive the need for integration and optimization of biological, biogeochemical, and physical components of regional ocean observing related to EBS. In liaison with the Global Ocean Oxygen Network, VOICE creates a roadmap toward observation-model syntheses for a comprehensive understanding of selected oxycline-dependent objectives. Local to global effects, such as habitat compression or deoxygenation trends, prompt for comprehensive observing of the oxycline on various space and time scales, and for an increased awareness of its impact on ecosystem services. Building on the Framework for Ocean Observing (FOO), we present a first readiness level assessment for ocean observing of the oxycline in EBS. This was to determine current ocean observing design and future needs in EBS regions (e.g., the California Current System, the Equatorial Eastern Pacific off Ecuador, the Peru-Chile Current system, the Northern Benguela off Namibia, etc.) building on the FOO strategy. We choose regional champions to assess the ocean observing design elements proposed in the FOO, namely, requirement processes, coordination of observational elements, and data management and information products and the related best practices. The readiness level for the FOO elements was derived for each EBS through a similar and very general ad hoc questionnaire. Despite some weaknesses in the questionnaire design and its completion, an assessment was achievable. We found that fisheries and ecosystem management are a societal requirement for all regions, but maturity levels of observational elements and data management and information products differ substantially. Identification of relevant stakeholders, developing strategies for readiness level improvements, and building and sustaining infrastructure capacity to implement these strategies are fundamental milestones for the VOICE initiative over the next 2-5 years and beyond

Location of laccase in ordered mesoporous materials

The functionalization with amine groups was developed on the SBA-15, and its effect in the laccase immobilization was compared with that of a Periodic Mesoporous Aminosilica. A method to encapsulate the laccase in situ has now been developed. In this work, spherical aberration (Cs) corrected scanning transmission electron microscopy combined with high angle annular dark field detector and electron energy loss spectroscopy were applied to identify the exact location of the enzyme in the matrix formed by the ordered mesoporous solids

Chemical reaction monitoring using zero-field nuclear magnetic resonance enables study of heterogeneous samples in metal containers

We demonstrate that heterogeneous/biphasic chemical reactions can be monitored with high spectroscopic resolution using zero-field nuclear magnetic resonance spectroscopy. This is possible because magnetic susceptibility broadening is negligible at ultralow magnetic fields. We show the two-step hydrogenation of dimethyl acetylenedicarboxylate with para-enriched hydrogen gas in conventional glass NMR tubes, as well as in a titanium tube. The low frequency zero-field NMR signals ensure that there is no significant signal attenuation arising from shielding by the electrically conductive sample container. This method paves the way for in situ monitoring of reactions in complex heterogeneous multiphase systems and in reactors made of conductive materials while maintaining resolution and chemical specificity

Uso de geotecnologias para avaliação da adequação ambiental nos municípios de São Carlos e Ibaté - SP.

Este trabalho buscou, através de técnicas de geoprocessamento, delimitar as APPs na área rural dos municípios de São Carlos e Ibaté e verificar sua adequação segundo o Novo Código Florestal Brasileiro e identificar, através da classificação do uso e cobertura do solo, qual o passivo ambiental relativo às áreas de APP e Reserva Legal nos municípios

Chiral effective theory predictions for deuteron form factor ratios at low Q^2

We use chiral effective theory to predict the deuteron form factor ratio G_C/G_Q as well as ratios of deuteron to nucleon form factors. These ratios are calculated to next-to-next-to-leading order. At this order the chiral expansion for the NN isoscalar charge operator (including consistently calculated 1/M corrections) is a parameter-free prediction of the effective theory. Use of this operator in conjunction with NLO and NNLO chiral effective theory wave functions produces results that are consistent with extant experimental data for Q^2 < 0.35 GeV^2. These wave functions predict a deuteron quadrupole moment G_Q(Q^2=0)=0.278-0.282 fm^2-with the variation arising from short-distance contributions to this quantity. The variation is of the same size as the discrepancy between the theoretical result and the experimental value. This motivates the renormalization of G_Q via a two-nucleon operator that couples to quadrupole photons. After that renormalization we obtain a robust prediction for the shape of G_C/G_Q at Q^2 < 0.3 GeV^2. This allows us to make precise, model-independent predictions for the values of this ratio that will be measured at the lower end of the kinematic range explored at BLAST. We also present results for the ratio G_C/G_M.Comment: 31 pages, 7 figure

Top marine predators track Lagrangian coherent structures

Meso- and submesoscales (fronts, eddies, filaments) in surface ocean flow have a crucial influence on marine ecosystems. Their dynamics partly control the foraging behaviour and the displacement of marine top predators (tuna, birds, turtles, and cetaceans). In this work we focus on the role of submesoscale structures in the Mozambique Channel on the distribution of a marine predator, the Great Frigatebird. Using a newly developed dynamical concept, namely the Finite-Size Lyapunov Exponent (FSLE), we have identified Lagrangian coherent structures (LCSs) present in the surface flow in the Channel over a 2-month observation period (August and September 2003). By comparing seabirds' satellite positions with LCSs locations, we demonstrate that frigatebirds track precisely these structures in the Mozambique Channel, providing the first evidence that a top predator is able to track these FSLE ridges to locate food patches. After comparing bird positions during long and short trips, and different parts of these trips, we propose several hypotheses to understand how frigatebirds can follow these LCSs. The birds might use visual and/or olfactory cues and/or atmospheric current changes over the structures to move along these biological corridors. The birds being often associated to tuna schools around foraging areas, a thorough comprehension of their foraging behaviour and movement during the breeding season is crucial not only to seabirds' ecology but also to an appropriate ecosystemic approach of fisheries in the Channel

Measurement of the tensor Ayy and vector Ay analyzing powers of the deuteron inelastic scattering off berillium at 5.0 GeV/c and 178 mr

Tensor Ayy and vector Ay analyzing powers in the inelastic scattering of deuterons with the momentum of 5.0 GeV/c on beryllium at an angle of 178 mr in the vicinity of the excitation of baryonic resonances with masses up to 1.8 GeV/c^2 have been measured. The Ayy data are in a good agreement with the previous data obtained at 4.5 and 5.5 GeV/c. The results of the experiment are compared with the predictions of the plane wave impulse approximation and \omega-meson exchange models.Comment: 18 pages, 9 figure