Chiral Symmetry and s-wave Low-Lying Meson-Baryon Resonances

The $s-$wave meson-baryon scattering is analyzed for the isospin-strangeness $I=1/2, S=0$ and $I=0,S=-1$ sectors, in a Bethe-Salpeter coupled channel formalism incorporating Chiral Symmetry. For both sectors, four channels have been considered: $\pi N$, $\eta N$, $K \Lambda$, $K \Sigma$ and $\pi \Sigma$, $\bar K N$, $\eta \Lambda$, $K \Xi$, respectively. The needed two particle irreducible matrix amplitudes are taken from lowest order Chiral Perturbation Theory in a relativistic formalism. There appear undetermined low energy constants, as a consequence of the renormalization of the amplitudes, which are obtained from fits to the available data: elastic $\pi N$ phase-shifts, $\pi^- p \to \eta n$ and $\pi^- p \to K^0 \Lambda$ cross sections and to $\pi\Sigma\to\pi\Sigma$ mass-spectrum, the elastic $\bar K N \to \bar K N$ and $\bar K N\to \pi \Sigma$ $t$--matrices and to the $K^- p \to \eta \Lambda$ cross section data. The position and residues of the complex poles in the second Riemann sheet of the scattering amplitude determine masses, widths and branching ratios of the $S_{11}-$ $N$(1535) and $-N$(1650) and $S_{01}-$ $\Lambda$(1405) and $-\Lambda$(1670) resonances, in reasonable agreement with experiment. A good overall description of data, from threshold up to around 2 GeV is achieved despite the fact that three-body channels have not been explicitly included.Comment: 5 Pages, 2 figures, invited contribution to Focus Session on Nature of Threshold N*, to be published in Proceedings of Nstar 2002, Pittsburgh, USA, October 9-12, 2002 (World Scientific

Non-linear response of single-molecule magnets: field-tuned quantum-to-classical crossovers

Quantum nanomagnets can show a field dependence of the relaxation time very different from their classical counterparts, due to resonant tunneling via excited states (near the anisotropy barrier top). The relaxation time then shows minima at the resonant fields H_{n}=n D at which the levels at both sides of the barrier become degenerate (D is the anisotropy constant). We showed that in Mn12, near zero field, this yields a contribution to the nonlinear susceptibility that makes it qualitatively different from the classical curves [Phys. Rev. B 72, 224433 (2005)]. Here we extend the experimental study to finite dc fields showing how the bias can trigger the system to display those quantum nonlinear responses, near the resonant fields, while recovering an classical-like behaviour for fields between them. The analysis of the experiments is done with heuristic expressions derived from simple balance equations and calculations with a Pauli-type quantum master equation.Comment: 4 pages, 3 figures. Submitted to Phys. Rev. B, brief report

Faint emission lines in the Galactic H II regions M16, M20 and NGC 3603

We present deep echelle spectrophotometry of the Galactic {\hii} regions M16, M20 and NGC 3603. The data have been taken with the Very Large Telescope Ultraviolet-Visual Echelle Spectrograph in the 3100 to 10400 \AA range. We have detected more than 200 emission lines in each region. Physical conditions have been derived using different continuum and line intensity ratios. We have derived He$^{+}$, C$^{++}$ and O$^{++}$ abundances from pure recombination lines as well as abundances from collisionally excited lines for a large number of ions of different elements. We have obtained consistent estimations of the temperature fluctuation parameter, {\ts}, using different methods. We also report the detection of deuterium Balmer lines up to D$\delta$ (M16) and to D$\gamma$ (M20) in the blue wings of the hydrogen lines, which excitation mechanism seems to be continuum fluorescence. The temperature fluctuations paradigm agree with the results obtained from optical CELs and the more uncertain ones from far IR fine structure CELs in NGC 3603, although, more observations covering the same volume of the nebula are necessary to obtain solid conclusions.Comment: 22 pages, 13 Tables, 7 Figures. Accepted for publication by MNRA

Absolute Determination of the 22Na(p,g) Reaction Rate in Novae

Gamma-ray telescopes in orbit around the Earth are searching for evidence of the elusive radionuclide 22Na produced in novae. Previously published uncertainties in the dominant destructive reaction, 22Na(p,g)23Mg, indicated new measurements in the proton energy range of 150 to 300 keV were needed to constrain predictions. We have measured the resonance strengths, energies, and branches directly and absolutely by using protons from the University of Washington accelerator with a specially designed beamline, which included beam rastering and cold vacuum protection of the 22Na implanted targets. The targets, fabricated at TRIUMF-ISAC, displayed minimal degradation over a ~ 20 C bombardment as a result of protective layers. We avoided the need to know the stopping power, and hence the target composition, by extracting resonance strengths from excitation functions integrated over proton energy. Our measurements revealed that resonance strengths for E_p = 213, 288, 454, and 610 keV are stronger by factors of 2.4 to 3.2 than previously reported. Upper limits have been placed on proposed resonances at 198-, 209-, and 232-keV. We have re-evaluated the 22Na(p,g) reaction rate, and our measurements indicate the resonance at 213 keV makes the most significant contribution to 22Na destruction in novae. Hydrodynamic simulations including our rate indicate that the expected abundance of 22Na ejecta from a classical nova is reduced by factors between 1.5 and 2, depending on the mass of the white-dwarf star hosting the nova explosion.Comment: 20 pages, 18 figures; shortened paper, accepted in Phys. Rev.

Improving the activity in hydrodechlorination of Pd/C catalysts by nitrogen doping of activated carbon supports

Aqueous phase 4-chlorophenol hydrodechlorination reaction was used to study the effect of N-doping of activated carbon support on the catalytic activity of Pd catalysts. Activated carbon was doped using pyridine and 1,10-phenantroline, reaching nitrogen contents of 0.42-1.22 and 1.35-4.19 % (w), respectively. All catalysts (0.75 % Pd w, carbon basis) showed relatively large Pd nanoparticles (35-55nm), but they exhibited fast and complete 4-chlorophenol disappearance in batch experiments. In runs at 30°C 4-chlorophenol disappearance was mainly ascribed to hydrodechlorination, although N-doping of the support also increased adsorption. Catalysts with supports doped with pyridine yielded higher 4-chlorophenol disappearance rate in spite of lower bulk nitrogen content, however they showed higher concentration of nitrogen species at the external surface and lower loss of surface area during the doping. 4-chlorophenol disappearance rate was boosted at 60°C, with minor differences between catalysts with undoped and N-doped supports, but generation of cyclohexanone was only observed for the ones with doped support. Phenol generation simultaneous to 4-chlorophenol disappearance was observed with all the catalysts. However, subsequent hydrogenation to cyclohexanone ocurred only with the catalysts supported on N-doped activated carbonThe authors greatly appreciate the financial support of this research from the Spanish Ministry of Economy and Competitiveness through the project CTQ2012-3282