Cheese whey valorisation: Production of valuable gaseous and liquid chemicals from lactose by aqueous phase reforming

Cheese effluent management has become an important issue owing to its high biochemical oxygen demand and chemical oxygen demand values. Given this scenario, this work addresses the valorisation of lactose (the largest organic constituent of this waste) by aqueous phase reforming, analysing the influence of the most important operating variables (temperature, pressure, lactose concentration and mass of catalyst/lactose mass flow rate ratio) as well as optimising the process for the production of either gaseous or liquid value-added chemicals. The carbon converted into gas, liquid and solid products varied as follows: 5–41%, 33–97% and 0–59%, respectively. The gas phase was made up of a mixture of H2 (8–58 vol.%), CO2 (33–85 vol.%), CO (0–15 vol.%) and CH4 (0–14 vol.%). The liquid phase consisted of a mixture of aldehydes: 0–11%, carboxylic acids: 0–22%, monohydric alcohols: 0–23%, polyhydric-alcohols: 0–48%, C3-ketones: 4–100%, C4-ketones: 0–18%, cyclic-ketones: 0–15% and furans: 0–85%. H2 production is favoured at high pressure, elevated temperature, employing a high amount of catalyst and a concentrated lactose solution. Liquid production is preferential using diluted lactose solutions. At high pressure, the production of C3-ketones is preferential using a high temperature and a low amount of catalyst, while a medium temperature and a high amount of catalyst favours the production of furans. The production of alcohols is preferential using medium temperature and pressure and a low amount of catalyst

An insight into the separation of 1, 2-propanediol, ethylene glycol, acetol and glycerol from an aqueous solution by adsorption on activated carbon

Glycerol conversion processes such as aqueous phase reforming and hydrogenolysis generate value-added compounds highly diluted in water. Because distillation is a high energy demand separation step, adsorption could be an attractive alternative to recover these chemicals. Adsorption isotherms of 1, 2-propanediol, acetol, ethylene glycol and glycerol onto activated carbon were determined by batch adsorption experiments. These isotherms were fitted slightly better to the Freundlich equation than to the Langmuir equation. Acetol is the compound with the highest adsorption at concentrations smaller than 1 M. Properties of the adsorbate such as the -OH group number, chain length, molecular size and dipole moment, besides characteristics of the adsorbent such as the surface area, oxygen and ash content, are considered to explain the observed results. Moreover, adsorption experiments were performed with mixtures of compounds and it was determined that the molar amount adsorbed is less than predicted from the adsorption isotherms of the individual compounds treated separately. In addition, the influence of the activated carbon thermal pretreatment temperature on the adsorption capacity has been studied, the optimum being 800¿C. An analysis of the influence of the activated carbon characteristics showed that the most important parameters are the total pore volume and the ash content. © 2021 by the authors. Licensee MDPI, Basel, Switzerland

Effect of biodiesel-derived impurities (acetic acid, methanol and potassium hydroxide) on the aqueous phase reforming of glycerol

This work analyses the influence of three biodiesel-derived impurities (CH3OH, CH3COOH and KOH) on the aqueous phase reforming of glycerol at 220 °C and 44 bar using a Ni-La/Al2O3 catalyst. The experiments were planed according to a factorial 2k design and analysed by means of an analysis of variance (ANOVA) test to identify the effect of each impurity and all possible binary and ternary combinations. The presence of CH3OH decreased the glycerol conversion, while CH3COOH and KOH decreased and increased the gas production, respectively. Catalyst deactivation took place under acidic conditions due to the loss of part of the active phase of the catalyst through leaching. The gas phase was made up of H2, CO2, CO and CH4. KOH exerted the greatest influence on the gas composition, increasing H2 production due to the greater gas production and the lower H2 consumption in the hydrogenation reactions. The liquid phase was made up of aldehydes, monohydric and polyhydric alcohols, C3 and C4 ketones and esters. CH3OH increased the proportion of monohydric alcohols, while CH3COOH promoted dehydration reactions, leading to an increase in the relative amount of C3-ketones

Study of ni/al-fe catalyst stability in the aqueous phase hydrogenolysis of glycerol

The present work studied the stability and reusability of Ni/Al-Fe catalyst in the aqueous phase hydrogenolysis of glycerol without external hydrogen addition. The catalyst based on 28 molar % of Ni with 3/1 molar ratio of Al/Fe was prepared through co-precipitation. This catalyst presented the best performance in our last study which compares several Ni/Al-Fe catalysts with different molar ratios of Al/Fe. To see the influence of the pressurized water on the physicochemical characteristics of Ni/Al-Fe catalyst, a test of up to 9 h has been carried out. Fresh and used catalysts were characterized by various techniques: X-ray Diffraction (XRD), N2-physisorption, field emission scanning electron microscopy (FESEM) and STEM. Glycerol conversion and carbon yield to gases and liquids did not vary significantly when compared at 3 h and 9 h. Furthermore, the morphology of the catalyst remains stable after continuous recycling under severe hydrothermal conditions. The nickel rich phase of the catalyst, which was determined by XRD and scanning transmission electron microscopy (STEM) techniques, showed a stable size after 9 h under reaction

From mobile phone data to the spatial structure of cities

Pervasive infrastructures, such as cell phone networks, enable to capture large amounts of human behavioral data but also provide information about the structure of cities and their dynamical properties. In this article, we focus on these last aspects by studying phone data recorded during 55 days in 31 Spanish metropolitan areas. We first define an urban dilatation index which measures how the average distance between individuals evolves during the day, allowing us to highlight different types of city structure. We then focus on hotspots, the most crowded places in the city. We propose a parameter free method to detect them and to test the robustness of our results. The number of these hotspots scales sublinearly with the population size, a result in agreement with previous theoretical arguments and measures on employment datasets. We study the lifetime of these hotspots and show in particular that the hierarchy of permanent ones, which constitute the "heart" of the city, is very stable whatever the size of the city. The spatial structure of these hotspots is also of interest and allows us to distinguish different categories of cities, from monocentric and "segregated" where the spatial distribution is very dependent on land use, to polycentric where the spatial mixing between land uses is much more important. These results point towards the possibility of a new, quantitative classification of cities using high resolution spatio-temporal data.Comment: 14 pages, 15 figure

Uncovering the spatial structure of mobility networks

The extraction of a clear and simple footprint of the structure of large, weighted and directed networks is a general problem that has many applications. An important example is given by origin-destination matrices which contain the complete information on commuting flows, but are difficult to analyze and compare. We propose here a versatile method which extracts a coarse-grained signature of mobility networks, under the form of a $2\times 2$ matrix that separates the flows into four categories. We apply this method to origin-destination matrices extracted from mobile phone data recorded in thirty-one Spanish cities. We show that these cities essentially differ by their proportion of two types of flows: integrated (between residential and employment hotspots) and random flows, whose importance increases with city size. Finally the method allows to determine categories of networks, and in the mobility case to classify cities according to their commuting structure.Comment: 10 pages, 5 figures +Supplementary informatio

Influence of the Ni-Co/Al-Mg catalyst loading in the continuous aqueous phase reforming of the bio-oil aqueous fraction

The effect of catalyst loading in the Aqueous Phase Reforming (APR) of bio-oil aqueous fraction has been studied with a Ni-Co/Al-Mg coprecipitated catalyst. Because of the high content of water in the bio-oil aqueous fraction, APR could be a useful process to convert this fraction into valuable products. Experiments of APR with continuous feeding of aqueous solution of acetol, butanol and acetic acid as the only compound, together with a simulated and a real aqueous fraction of bio-oil, were carried out. Liquid products in the liquid effluent of the APR model compounds were quantified and the reaction pathways were revised. The increase of catalyst loading produced an increase of gas production and a gas with higher alkanes content. Acetol was the compound with the highest reactivity while the conversion of acetic acid was very low. The presence of acetic acid in the feed caused catalyst deactivation

Peoples and sovereignty: constitutional law lessons from Greenland and Denmark

What does Greenland reveal about independence debates in other contexts (e.g. Scotland or Catalonia) and the nature of a "People" for the purposes of international law. How might the concept of "Constitutional Culture" be beneficial in addressing these debates

Edad, crecimiento y reproducción de Gobio gobio L. (Pisces, Cyprinidae) en un tramo regulado del río Segura (SE de España)

The age, growth and reproduction of Gobio gobio, were studied during a period of two years in a section of the Segura River regulated by the effect of a small upstream hydroelectric power station. A total of 254 specimens were caught monthly by electrofishing. The studied population showed a maximum of six age classes in females (0+–5+) and five in males (1+–5+). All females were mature at 2+ age class, whereas only 62.5% 2+ males showed mature gonads. During the studied period, both sexes showed maximum values of Gonadosomatic Index in May and spawn was different between the two studied periods. Compared with other populations, the studied population from a regulated locality is characterized by a non–seasonal body condition cycle and low captures of juvenile fish (0+, 1+) probably due to the effect of washing produced by drastic and unpredictable flow changes.La edad, crecimiento y reproducción de Gobio gobio, ha sido estudiada a lo largo de dos años en un tramo del río Segura regulado por una pequeña central hidroeléctrica. Mediante pesca eléctrica fueron capturados, mensualmente, un total de 254 ejemplares. Las hembras presentaron seis clases de edad (0+–5+) mientras que los machos presentaron cinco clases (1+–5+). Todas las hembras de clase de edad 2+ resultaron maduras mientras que los machos 2+ resultaron maduros en un 62,5% de los casos. Durante el periodo de estudio, ambos sexos presentaron los máximos valores del Índice Gonadosomático durante los meses de mayo aunque el desove resultó diferente entre los dos periodos estudiados. En comparación con otras poblaciones, la población estudiada en un tramo regulado del río se caracteriza por no presentar un ciclo estacional en la condición somática y bajas capturas de ejemplares juveniles (0+, 1+) debido, probablemente, al efecto de lavado provocado por los drásticos e impredecibles cambios en el caudal

Stabilization of a Large Paleo-Landslide Reactivated Because of the Works to Install a New Ski Lift in Formigal Skiing Resort

The paper presents the study and stabilization of a paleo-landslide reactivated because of the excavation works carried out at its foot to construct a new lift in Formigal skiing resort. Inclinometers were installed and surface movements were controlled by GPS techniques in order to analyse the sliding surface and to define the stabilization measures to undertake. The data obtained from the instrumentation was used to perform a back-analysis that allowed to determine the kinematics of the movement as well as to define the appropriate stabilization measures. Presently, the evolution of the movement is controlled by GPS