7 research outputs found

    Selective Facet Engineering of Ni<sub>12</sub>P<sub>5</sub> Nanoparticle for Maximization of Electrocatalytic Oxidative Reaction of Biomass Chemicals

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    Electrocatalytic hydrogen generation is a prime research topic for the large-scale production of hydrogen fuel. High energy demanding oxygen evolution process impedes the production of H2 at low potentials. Conversion of biomass to value-added chemicals or fuels is appraised as an upcycling process, which is advantageous for resource management. Coupling of hydrogen generation at the cathode with oxidative conversion of biomass to market-demanded chemicals at the anode is a sustainable approach to increase energy efficiency in hybrid electrolysis. For that purpose, Ni-based anode electrocatalysts are in the forefront for ease of formation of hypervalent NiIII species, at a mild anodic potential, which act as an oxidant to propagate the oxidation and dehydrogenation reactions. Herein, we synthesized Ni12P5 nanohexagon via kinetic stabilization of high index {425̀…} facets and compared the electrocatalytic activity toward various biomass-derived platform chemicals oxidation with the thermodynamically stable Ni12P5 nanosphere. The Ni12P5 nanohexagon outperforms the current state-of-the-art catalysts regarding mass activity, product conversion, and Faradaic yield. Ease of formation of active species, faster charge transfer, and enhanced adsorption of substrates over {425̀…} facets resulted in this superior activity. This shape-directing effects on Ni12P5 ensured potential advantage of 150 mV in hybrid electrolysis over water splitting reaction when ethanol was used as a substrate in a two-electrode electrolyzer cell
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