101 research outputs found
SULFIDIC GROUND-WATER CHEMISTRY IN THE FRASASSI CAVES, ITALY
A year-long study of the sulfidic aquifer in the Frasassi caves (central Italy) employed chemical analysis of the water and measurements of its level, as well as assessments of the concentration of H(2)S, CO(2), and O(2) in the cave air. Bicarbonate water seepage derives from diffuse infiltration of meteoric water into the karst surface, and contributes to sulfidic ground-water dilution, with a percentage that varies between 30% and 60% during the year. Even less diluted sulfidic ground water was found in a localized area of the cave between Lago Verde and nearby springs. This water rises from a deeper phreatic zone, and its chemistry changes only slightly with the seasons with a contribution of seepage water that does not exceed 20%. In order to understand how the H(2)S oxidation, which is considered the main cave forming process, is influenced by the seasonal changes in the cave hydrology, the sulfide/total sulfur ratio was related to ground-water dilution and air composition. The data Suggest that in the upper phreatic zone, limestone corrosion due to H(2)S oxidation is prominent in the wet season because of the high recharge of O(2)-rich seepage water, while in the dry season, the H(2)S content increases, but the extent of oxidation is lower. In the cave atmosphere, the low H(2)S content in ground water during the wet season inhibits the release of this gas, but the H(2)S concentration increases ill the dry season, favoring its oxidation in the air and the replacement of limestone with gypsum on the cave walls
Effect of plasma-activated water (PAW) soaking on the lipid oxidation of sardine (Sardina pilchardus) fillets
The efficacy of plasma-activated water (PAW) as a chemical-free and environmentally friendly preservative has been documented for a variety of foods, but the onset of lipid oxidation induced by plasma-reactive species has been less extensively studied. In this work, global indices (peroxide value, UV specific absorbance) and direct analytical determinations of volatile and non-volatile oxidation products were performed on sardine lipids extracted from fish fillets immersed in PAW (treatments) and distilled water (controls) for 10-30 min. Evidence of PAW-induced lipid oxidation was provided by higher UV specific absorbances and higher levels of C5-C9 secondary volatile oxidation products in the treated samples. However, the degree of fatty acid oxidation was not sufficient to cause a significant reduction in nutritionally valuable eicosapentaenoic acid and docosahexaenoic acid. Twelve cholesterol oxidation products (COPs) were identified in the sardine lipids, but no significant differences in total COPs content were found between PAW processed and control samples
Plant communities of Italy. The vegetation prodrome
The Vegetation Prodrome of Italy was promoted in 2012 by the Italian "Ministry of Environment, Land and Sea Protection", in collaboration with the "Italian Society of Botany", to provide a comprehensive and systematic catalogue and description of Italian plant communities. The Prodrome that is presented in this paper is the first full organic synthesis of the vegetation of Italy at the alliance syntaxonomic level. It fulfils several needs, the main one being a unified and comprehensive national framework that may make an important contribution to the definition of the European Vegetation Prodrome. Syntaxonomy, as well as taxonomy, is sometimes based on considerations that may in part diverge: several authors tend to favour models that are divisive or aggregative to a greater or lesser extent in terms of flora, biogeography and ecology. These different points of view stimulate the scientific debate and allow the adoption of a framework that is more widely supported. The Prodrome includes 75 classes, 2 subclasses, 175 orders, 6 suborders and 393 alliances. The classes were grouped into nine broad categories according to structural, physiognomic and synecological elements rather than to syntaxonomic criteria. The rank, full valid name, any synonymies and incorrect names are provided for each syntaxon. The short declaration highlights the physiognomy, synecology, syndynamics and distribution of the plant communities that belong to the syntaxon. The Prodrome of the Italian Vegetation is linked to the European Strategy for Biodiversity, the European Habitats Directive and the European Working Groups related to the ecosystems and their services. In addition to basic applications, the Prodrome can be used as a framework for scientific research related to the investigation of the relationships between plant communities and the environmental factors that influence their composition and distribution
Acid-Stable Serine Proteinase Inhibitors in the Urine of Alzheimer Disease Subjects
A comparative study of the levels of acid-stable proteinase inhibitors (kallikrein and trypsin inhibitors) in the urine of healthy and Alzheimer subjects, of both sexes, has been performed. A preliminary characterization of the purified inhibitors indicates that the urinary antitryptic activity is accounted for by the presence of the well known Urinary Trypsin Inhibitor (UTI) while an apparently new molecule appears to be responsible for the anti kallikrein activity. The urinary levels of kallikrein inhibitors are very similar in healthy and sick subjects while the levels of trypsin inhibitors appear significatively increased in Alzheimer subjects of both sexes. The data presented here support the hypothesis that unpaired proteolytic processes could be involved in the pathogenesis of Alzheimer's disease and suggest that the levels of urinary acid-stable inhibitors may prove to be useful markers of the disease
First overview on the 4th Annex I Habitats Report in Italy: methods, criticality, results and future prospects
Like all the other EU/28 countries, in 2019 Italy developed the 4th Italian Report
ex-Art. 17 on the conservation status of the Habitats of Annex I to the 92/43/EEC
Directive. Institutional referent of the process, on behalf of the Ministry for
Environment, Land and Sea Protection (MATTM), was the Italian Institute for
Environmental Protection and Research (ISPRA) with the scientific support of the
Italian Botanical Society (SBI). A huge working group composed of thematic and
territorial experts was formed with the task to collect, analyse, validate the data
resulting from Annex I Habitat monitoring in Italy for the period 2013-2018, whose
collection is in charge to the regional administrations. Data on 124 types of terrestrial
and inland water Habitats present in Italy have been processed in order to assess their
overall conservation status in the Biogeographic Regions of occurrence. The carried out
activity led to the compilation of 278 assessment sheets. The work included a critical
analysis of the data and a broad scientific confrontation aimed at finding
methodologically robust solutions to fill the gaps. The work was structured so as to
guarantee the traceability of the information and to allow the collection of "gray"
literature and scientific articles, phytosociological surveys and unpublished material of
the specialists, composing a substantial pool of data useful for starting a long-term
process to support the next reporting cycles. Cartographic outcomes, associated
databases and additional data used for the assessments will be available online on the
ISPRA Portal as soon as the validation process by the European Commission will be
completed. A freely accessible online archive of phytosociological surveys
representative of the various Annex I Habitats in Italy is being set up within the national
"VegItaly" database, managed by the Italian Society of Vegetation Science, by way of a
dedicated archive named "HAB_IT". Such a long-term vision, oriented to the storage
and enhancement of knowledge, represents an important innovative aspect and a
significant progress towards the construction of an effective monitoring system for the
conservation of Annex I Habitats in Italy
Il supporto della SISV alla realizzazione di un manuale nazionale per il monitoraggio degli habitat della Direttiva 92/43/EEC in Italia.
A partire dall'entrata in vigore della Direttiva 92/43/EEC, la sorveglianza dello stato di conservazione degli habitat elencati nell'Allegato I ed il relativo monitoraggio periodico a intervalli di sei anni sono diventati un obbligo per tutti i paesi membri dell'UE, in base a quanto previsto negli Articoli 11 e 17. Nel 2011 è stato pubblicato un documento che fornisce le linee guida di riferimento europee per il monitoraggio di habitat e specie (Evans & Arvela 2011). Su questa base metodologica, la Società Italiana di Scienza della Vegetazione (SISV), avvalendosi di un ampio gruppo di soci esperti, ha avviato un dibattito interno su principi, criteri, parametri e strumenti per il monitoraggio degli habitat di Allegato I e dei tipi di vegetazione in essi rappresentati. Il progetto è stato promosso dal Ministero dell'Ambiente e della Tutela del Territorio e del Mare e coordinato dall'Istituto Superiore per la Protezione e la Ricerca Ambientale, e si trova al momento in una fase prossima alla conclusione. A partire dalla documentazione già prodotta a livello nazionale per gli habitat italiani (Biondi et al., 2009, 2012, 2014; Genovesi et al., 2014), diversi aspetti critici sono stati esaminati attraverso una discussione scientifica ampiamente condivisa. In particolare, sono stati affrontati: gli aspetti legati alla scelta di strumenti adeguati per valutare i parametri area, struttura e funzione, prospettive future; il concetto di "specie tipica"; i metodi di campionamento habitat-specifici appropriati. Il protocollo sviluppato si pone come uno strumento pratico ed efficace, scientificamente valido e in linea con gli standard metodologici internazionali. Il suo utilizzo permetterà una raccolta armonizzata di dati su scala nazionale, rendendo possibile una valutazione comparata dello stato di conservazione di ciascun habitat
Il Reporting ex-Art. 17 degli Habitat di All. I alla Direttiva 92/43/CEE in Italia: metodi, criticità, stato dell'arte e prospettive future.
Habitat conservation in Italy: the state of the art in the light of the first European Red List of Terrestrial and Freshwater Habitats
The importance of taking into account ecosystems, plant communities and habitats for the development of biodiversity conservation strategies is increasingly acknowledged. Recently, the first ever European Red List of Habitats was produced, which provided an evaluation of the extinction risk of EUNIS-based natural and semi-natural habitats in Europe. As assessment unit, it used the habitat intended as a plant community, thus representing a landmark for the role of vegetation science in nature conservation. In the present paper, the results of the European Red List of Habitats are analyzed at the national scale with specific reference to the terrestrial and freshwater habitat types occurring in Italy. More than three-quarters of the assessed European habitat types were recognized for the Italian territory. The distribution of the threat categories reflects approximately the situation at the EU28 level. About 35% of the assessed habitat types are referred to a threat category; no critically endangered habitat is present in Italy. The most frequently used criteria are those related to a reduction in quantity. Some critical issues arising from the analyses are discussed. In particular, the presence of knowledge gaps is pointed out, with remarkable reference to the poor availability of spatial and quantitative data, severely affecting the application of the criteria adopted for the assessment. Descriptions of habitat types from Italy are reported, some of which are representative, emblematic or even exclusive to the Italian territory. The outcomes of the analysis represent the starting point for the future development of a national-scale Red List of Habitats. Results also emphasized how habitat types with a too broad definition pose a limit to a proper evaluation of the regional biogeographic variability, often very high in Italy, with local floristic and phytocoenotic peculiarities which do not find room in the adopted European typology. This is the reason why the development of national subtypes stands as a necessary step for the development of a realistic and effective assessment at the national scale
ACTIVE HYPOGENIC KARST IN ITALY
Hypogenic speleogenesis, dissolution by aggressive and deep-seated fluids, is the dominant cave formation process for the most important karst systems in Italy. Endogenic H2S and CO2 are the main corrosive agents
of underground karst corrosion. Throughout the region, evidence of all end-members of karst processes can be found, from solution limestone caves to deposition of carbonate travertine. The redox reactions in the groundwater and in the atmosphere involve chemoautotrophic microbial activity. The presence of active hypogene branches in many caves permits a direct study of the karst-forming processes, as well as a comparison with resultant morphologies
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