167 research outputs found
Sustainability assessment of organic dairy farms in mountainous areas of Austria
Dairy farming plays a major role in mountainous regions of Austria, mostly due to high proportion of grasslands. In general, Austria’s dairy farming faces challenges regarding sustainability, e.g. environmental impacts, but specifically for alpine areas low productivity and dependency on direct payments are lowering sustainability. Organic farming is considered as a strategy to overcome these challenges.
Considering this general background, we analysed the sustainability performance and its main drivers of organic dairy farms in mountainous regions of Austria
Functionalization of transparent conductive oxide electrode for TiO2-free perovskite solar cells
Many of the best performing solar cells based on perovskite-halide light absorbers use TiO2 as an electron selective contact layer. However, TiO2 usually requires high temperature sintering, is related to electrical instabilities in perovskite solar cells, and causes cell performance degradation under full solar spectrum illumination. Here we demonstrate an alternative approach based on the modification of transparent conductive oxide electrodes with self-assembled siloxane-functionalized fullerene molecules, eliminating TiO2 or any other additional electron transporting layer. We demonstrate that these molecules spontaneously form a homogenous monolayer acting as an electron selective layer on top of the fluorine doped tin oxide (FTO) electrode, minimizing material consumption. We find that the fullerene-modified FTO is a robust, chemically inert charge selective contact for perovskite based solar cells, which can reach 15% of stabilised power conversion efficiency in a flat junction device architecture using a scalable, low temperature, and reliable process. In contrast to TiO2, devices employing a molecularly thin functionalized fullerene layer show unaffected performance after 67 h of UV light exposure
Diamagnetism of real-space pairs above Tc in hole doped cuprates
The nonlinear normal state diamagnetism reported by Lu Li et al. [Phys. Rev.
B 81, 054510 (2010)] is shown to be incompatible with an acclaimed Cooper
pairing and vortex liquid above the resistive critical temperature. Instead it
is perfectly compatible with the normal state Landau diamagnetism of real-space
composed bosons, which describes the nonlinear magnetization curves in less
anisotropic cuprates La-Sr-Cu-O (LSCO) and Y-Ba-Cu-O (YBCO) as well as in
strongly anisotropic bismuth-based cuprates in the whole range of available
magnetic fields.Comment: 4 pages, 4 figure
Electron-Phonon Coupling in High-Temperature Cuprate Superconductors Determined from Electron Relaxation Rates
We determined electronic relaxation times via pump-probe optical spectroscopy
using sub-15 fs pulses for the normal state of two different cuprate
superconductors.We show that the primary relaxation process is the
electron-phonon interaction and extract a measure of its strength, the second
moment of the Eliashberg function\lambda=800\pm200 meV^{2} for
La_{1.85}Sr_{0.15}CuO_{4} and \lambda=400\pm100 meV^{2} for
YBa_{2}Cu_{3}O_{6.5}. These values suggest a possible fundamental role of the
electron-phonon interaction in the superconducting pairing mechanism.Comment: As published in PR
Disentangling the electronic and phononic glue in a high-Tc superconductor
Unveiling the nature of the bosonic excitations that mediate the formation of
Cooper pairs is a key issue for understanding unconventional superconductivity.
A fundamen- tal step toward this goal would be to identify the relative weight
of the electronic and phononic contributions to the overall frequency (\Omega)
dependent bosonic function, \Pi(\Omega). We perform optical spectroscopy on
Bi2212 crystals with simultaneous time- and frequency-resolution; this
technique allows us to disentangle the electronic and phononic contributions by
their different temporal evolution. The strength of the interaction
({\lambda}~1.1) with the electronic excitations and their spectral distribution
fully account for the high critical temperature of the superconducting phase
transition.Comment: 9 pages, 4 figure
Theory of excited state absorptions in phenylene-based -conjugated polymers
Within a rigid-band correlated electron model for oligomers of
poly-(paraphenylene) (PPP) and poly-(paraphenylenevinylene) (PPV), we show that
there exist two fundamentally different classes of two-photon A states in
these systems to which photoinduced absorption (PA) can occur. At relatively
lower energies there occur A states which are superpositions of one
electron - one hole (1e--1h) and two electron -- two hole (2e--2h) excitations,
that are both comprised of the highest delocalized valence band and the lowest
delocalized conduction band states only. The dominant PA is to one specific
member of this class of states (the mA). In addition to the above class of
A states, PA can also occur to a higher energy kA state whose 2e--2h
component is {\em different} and has significant contributions from excitations
involving both delocalized and localized bands. Our calculated scaled energies
of the mA and the kA agree reasonably well to the experimentally
observed low and high energy PAs in PPV. The calculated relative intensities of
the two PAs are also in qualitative agreement with experiment. In the case of
ladder-type PPP and its oligomers, we predict from our theoretical work a new
intense PA at an energy considerably lower than the region where PA have been
observed currently. Based on earlier work that showed that efficient
charge--carrier generation occurs upon excitation to odd--parity states that
involve both delocalized and localized bands, we speculate that it is the
characteristic electronic nature of the kA that leads to charge generation
subsequent to excitation to this state, as found experimentally.Comment: Revtex4 style, 2 figures inserted in the text, three tables, 10 page
Strain-induced enhancement of the electron energy relaxation in strongly correlated superconductors
We use femtosecond optical spectroscopy to systematically measure the primary
energy relaxation rate k1 of photoexcited carriers in cuprate and pnictide
superconductors. We find that k1 increases monotonically with increased
negative strain in the crystallographic a-axis. Generally, the Bardeen-Shockley
deformation potential theorem and, specifically, pressure-induced Raman shifts
reported in the literature suggest that increased negative strain enhances
electron-phonon coupling, which implies that the observed direct correspondence
between a and k1 is consistent with the canonical assignment of k1 to the
electron-phonon interaction. The well-known non-monotonic dependence of the
superconducting critical temperature Tc on the a-axis strain is also reflected
in a systematic dependence Tc on k1, with a distinct maximum at intermediate
values (~16 ps-1 at room temperature). The empirical non-monotonic systematic
variation of Tc with the strength of the electron-phonon interaction provides
us with unique insight into the role of electron-phonon interaction in relation
to the mechanism of high-Tc superconductivity as a crossover phenomenon.Comment: manuscript as accepted in PRX, main paper (20 pages, 3 figures) plus
supplementary material (25 pages, 19 figures
Exciton bimolecular annihilation dynamics in supramolecular nanostructures of conjugated oligomers
We present femtosecond transient absorption measurements on -conjugated
supramolecular assemblies in a high pump fluence regime.
Oligo(\emph{p}-phenylenevinylene) monofunctionalized with
ureido-\emph{s}-triazine (MOPV) self-assembles into chiral stacks in dodecane
solution below 75C at a concentration of M. We
observe exciton bimolecular annihilation in MOPV stacks at high excitation
fluence, indicated by the fluence-dependent decay of B-exciton
spectral signatures, and by the sub-linear fluence dependence of time- and
wavelength-integrated photoluminescence (PL) intensity. These two
characteristics are much less pronounced in MOPV solution where the phase
equilibrium is shifted significantly away from supramolecular assembly,
slightly below the transition temperature. A mesoscopic rate-equation model is
applied to extract the bimolecular annihilation rate constant from the
excitation fluence dependence of transient absorption and PL signals. The
results demonstrate that the bimolecular annihilation rate is very high with a
square-root dependence in time. The exciton annihilation results from a
combination of fast exciton diffusion and resonance energy transfer. The
supramolecular nanostructures studied here have electronic properties that are
intermediate between molecular aggregates and polymeric semiconductors
Effect of screening of the electron-phonon interaction on the temperature of Bose-Einstein condensation of intersite bipolarons
Here we consider an interacting electron-phonon system within the framework
of extended Holstein-Hubbard model at strong enough electron-phonon interaction
limit in which (bi)polarons are the essential quasiparticles of the system. It
is assumed that the electron-phonon interaction is screened and its potential
has Yukawa-type analytical form. An effect of screening of the electron-phonon
interaction on the temperature of Bose-Einstein condensation of the intersite
bipolarons is studied for the first time. It is revealed that the temperature
of Bose-Einstein condensation of intersite bipolarons is higher in the system
with the more screened electron-phonon interaction.Comment: 6 pages, 4 figure
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