163 research outputs found
G-quartet biomolecular nanowires
We present a first-principle investigation of quadruple helix nanowires,
consisting of stacked planar hydrogen-bonded guanine tetramers. Our results
show that long wires form and are stable in potassium-rich conditions. We
present their electronic bandstructure and discuss the interpretation in terms
of effective wide-bandgap semiconductors. The microscopic structural and
electronic properties of the guanine quadruple helices make them suitable
candidates for molecular nanoelectronics.Comment: 7 pages, 3 figures, to be published in Applied Physics Letters (2002
Optimizing Energy Savings from Direct-DC in U.S. Residential Buildings
An increasing number of energy efficient appliances operate on direct current (DC) internally, offering the potential to use DC from renewable energy systems directly and avoiding the losses inherent in converting power to alternating current (AC) and back. This paper investigates that potential for net-metered residences with on-site photovoltaics (PV) by modeling the net power draw of the ‘direct-DC house’ with respect to today’s typical configuration, assuming identical DC-internal loads. Power draws were modeled for houses in 14 U.S. cities, using hourly, simulated PV-system output and residential loads. The latter were adjusted to reflect a 33% load reduction, representative of the most efficient DC-internal technology, based on an analysis of 32 electricity end-uses. The model tested the effect of climate, electric vehicle (EV) loads, electricity storage, and load shifting on electricity savings; a sensitivity analysis was conducted to determine how future changes in the efficiencies of power system components might affect savings potential. Based on this work, we estimate that net-metered PV residences could save 5% of their total electricity load for houses without storage and 14% for houses with storage. Based on residential PV penetration projections for year 2035 obtained from the National Energy Modeling System (2.7% for the reference case and 11.2% for the extended policy case), direct-DC could save the nation 10 trillion Btu (without storage) or 40 trillion Btu (with storage). Shifting the cooling load by two hours earlier in the day (pre-cooling) has negligible benefits for energy savings. Direct-DC provides no energy savings benefits for EV charging, to the extent that charging occurs at night. However, if charging occurred during the day, for example with employees charging while at work, the benefits would be large. Direct-DC energy savings are sensitive to power system and appliance conversion efficiencies but are not significantly influenced by climate. While direct-DC for residential applications will most likely arise as a spin-off of developments in the commercial sector—because of lower barriers to market entry and larger energy benefits resulting from the higher coincidence between load and insolation—this paper demonstrates that there are substantial benefits in the residential sector as well. Among residential applications, space cooling derives the largest energy savings from being delivered by a direct-DC system. It is the largest load for the average residence on a national basis and is particularly so in high-load regions. It is also the load with highest solar coincidence
Self-assembled guanine ribbons as wide-bandgap semiconductors
We present a first principle study about the stability and the electronic
properties of a new biomolecular solid-state material, obtained by the
self-assembling of guanine (G) molecules. We consider hydrogen-bonded planar
ribbons in isolated and stacked configurations. These aggregates present
electronic properties similar to inorganic wide-bandgap semiconductors. The
formation of Bloch-type orbitals is observed along the stacking direction,
while it is negligible in the ribbon plane. Global band-like conduction may be
affected by a dipole-field which spontaneously arises along the ribbon axis.
Our results indicate that G-ribbon assemblies are promising materials for
biomolecular nanodevices, consistently with recent experimental results.Comment: 7 pages, 3 figures, to be published in Physica
Catalog of DC Appliances and Power Systems
This document catalogs the characteristics of current and potential future DC products and power systems
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Optimizing Energy Savings from Direct-DC in U.S. Residential Buildings
An increasing number of energy efficient appliances operate on direct current (DC) internally, offering the potential to use DC from renewable energy systems directly and avoiding the losses inherent in converting power to alternating current (AC) and back. This paper investigates that potential for net-metered residences with on-site photovoltaics (PV) by modeling the net power draw of the ‘direct-DC house’ with respect to today’s typical configuration, assuming identical DC-internal loads. Power draws were modeled for houses in 14 U.S. cities, using hourly, simulated PV-system output and residential loads. The latter were adjusted to reflect a 33% load reduction, representative of the most efficient DC-internal technology, based on an analysis of 32 electricity end-uses. The model tested the effect of climate, electric vehicle (EV) loads, electricity storage, and load shifting on electricity savings; a sensitivity analysis was conducted to determine how future changes in the efficiencies of power system components might affect savings potential. Based on this work, we estimate that net-metered PV residences could save 5% of their total electricity load for houses without storage and 14% for houses with storage. Based on residential PV penetration projections for year 2035 obtained from the National Energy Modeling System (2.7% for the reference case and 11.2% for the extended policy case), direct-DC could save the nation 10 trillion Btu (without storage) or 40 trillion Btu (with storage). Shifting the cooling load by two hours earlier in the day (pre-cooling) has negligible benefits for energy savings. Direct-DC provides no energy savings benefits for EV charging, to the extent that charging occurs at night. However, if charging occurred during the day, for example with employees charging while at work, the benefits would be large. Direct-DC energy savings are sensitive to power system and appliance conversion efficiencies but are not significantly influenced by climate. While direct-DC for residential applications will most likely arise as a spin-off of developments in the commercial sector—because of lower barriers to market entry and larger energy benefits resulting from the higher coincidence between load and insolation—this paper demonstrates that there are substantial benefits in the residential sector as well. Among residential applications, space cooling derives the largest energy savings from being delivered by a direct-DC system. It is the largest load for the average residence on a national basis and is particularly so in high-load regions. It is also the load with highest solar coincidence
Biomolecular electronic devices based on self-organized deoxyguanosine nanocrystals.
We report on a new class of hybrid electronic devices based on a DNA nucleoside (deoxyguanosine lipophilic derivative) whose assembled polymeric ribbons interconnect a submicron metallic gate. The device exhibits large conductivity at room temperature, rectifying behavior and strong current-voltage hysteresis. The transport mechanism through the molecules is investigated by comparing films with different self-assembling morphology. We found that the main transport mechanism is connected to pi-pi interactions between guanosine molecules and to the formation of a strong dipole along ribbons, consistently with the results of our first-principles calculations
Ab-initio study of model guanine assemblies: The role of pi-pi coupling and band transport
Several assemblies of guanine molecules are investigated by means of
first-principle calculations. Such structures include stacked and
hydrogen-bonded dimers, as well as vertical columns and planar ribbons,
respectively, obtained by periodically replicating the dimers. Our results are
in good agreement with experimental data for isolated molecules, isolated
dimers, and periodic ribbons. For stacked dimers and columns, the stability is
affected by the relative charge distribution of the pi orbitals in adjacent
guanine molecules. pi-pi coupling in some stacked columns induces dispersive
energy bands, while no dispersion is identified in the planar ribbons along the
connections of hydrogen bonds. The implications for different materials
comprised of guanine aggregates are discussed. The bandstructure of dispersive
configurations may justify a contribution of band transport (Bloch type) in the
conduction mechanism of deoxyguanosine fibres, while in DNA-like configurations
band transport should be negligible.Comment: 21 pages, 6 figures, 3 tables, to be published in Phys. Rev.
Planck-LFI: Design and Performance of the 4 Kelvin Reference Load Unit
The LFI radiometers use a pseudo-correlation design where the signal from the
sky is continuously compared with a stable reference signal, provided by a
cryogenic reference load system. The reference unit is composed by small
pyramidal horns, one for each radiometer, 22 in total, facing small absorbing
targets, made of a commercial resin ECCOSORB CR (TM), cooled to approximately
4.5 K. Horns and targets are separated by a small gap to allow thermal
decoupling. Target and horn design is optimized for each of the LFI bands,
centered at 70, 44 and 30 GHz. Pyramidal horns are either machined inside the
radiometer 20K module or connected via external electro-formed bended
waveguides. The requirement of high stability of the reference signal imposed a
careful design for the radiometric and thermal properties of the loads.
Materials used for the manufacturing have been characterized for thermal, RF
and mechanical properties. We describe in this paper the design and the
performance of the reference system.Comment: This is an author-created, un-copyedited version of an article
accepted for publication in JINST. IOP Publishing Ltd is not responsible for
any errors or omissions in this version of the manuscript or any version
derived from it. The definitive publisher authenticated version is available
online at [10.1088/1748-0221/4/12/T12006]. 14 pages, 34 figure
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