Electron-acoustic-phonon scattering and electron relaxation in two-coupled quantum rings

Electron relaxation, induced by acoustic phonons, is studied for coupled quantum rings in the presence of external fields, both electric and magnetic. We address the problem of a single electron in vertically coupled GaAs quantum rings. Electron-phonon interaction is accounted for both deformation potential and piezoelectric field coupling mechanisms. Depending on the external fields, the ring radii and the separation between the rings, we show that the two different couplings have different weights and importance. Significant oscillations are found in the scattering rates from electron excited states to the ground state, as a function of either the geometry of the system or the external fields.Comment: 17 pages, 8 figures, to appear in Journal of Applied Physic

Pinning and depinning of a classic quasi-one-dimensional Wigner crystal in the presence of a constriction

We studied the dynamics of a quasi-one-dimensional chain-like system of charged particles at low temperature, interacting through a screened Coulomb potential in the presence of a local constriction. The response of the system when an external electric field is applied was investigated. We performed Langevin molecular dynamics simulations for different values of the driving force and for different temperatures. We found that the friction together with the constriction pins the particles up to a critical value of the driving force. The system can depin \emph{elastically} or \emph{quasi-elastically} depending on the strength of the constriction. The elastic (quasi-elastic) depinning is characterized by a critical exponent $\beta\sim0.66$ ($\beta\sim0.95$). The dc conductivity is zero in the pinned regime, it has non-ohmic characteristics after the activation of the motion and then it is constant. Furthermore, the dependence of the conductivity with temperature and strength of the constriction was investigated in detail. We found interesting differences between the single and the multi-chain regimes as the temperature is increased.Comment: 18 pages, 16 figures, accepted for publication in PR

Normal modes of a quasi-one-dimensional multi-chain complex plasma

We studied equally charged particles, suspended in a complex plasma, which move in a plane and interact with a screened Coulomb potential (Yukawa type) and with an additional external confining parabolic potential in one direction, that makes the system quasi-one-dimensional (Q1D). The normal modes of the system are studied in the presence of dissipation. We also investigated how a perpendicular magnetic field couples the phonon modes with each other. Two different ways of exciting the normal modes are discussed: 1) a uniform excitation of the Q1D lattice, and 2) a local forced excitation of the system in which one particle is driven by e.g. a laser. Our results are in very good agreement with recent experimental findings on a finite single chain system (Phys. Rev. Lett. {\bf 91}, 255003 (2003)). Predictions are made for the normal modes of multi-chain structures in the presence of damping.Comment: 15 pages, 14 figures, accepted for publication on PR

A Hippocratic Oath for geologists?

We argue here that the introduction of an ethical code of conduct that follows the example of the Hippocratic Oath of physicians will help geologists to acquire binding awareness of their professional and social responsibilities. The ethical behavior and obligations of modern geologists involve, but are not limited to, the following issues: correct land/ environment use and management; respect of truth and science; and protection of the Earth systems, on both the local and global scales, and therefore, of our well-being. We believe that for geoligists, the explicit acceptance of an ethical code will help to promote: (i) an awareness of their social role, expertise and sense of belonging to a professional community; (ii) an understanding of the expectations of citizens and society; and (iii) cultural growth, with better use of research and implementation of scientific and professional skills. All this should enhance the public recognition of the social mission of geologists, which is essential for the well-being of society. Therefore, we suggest that like in the majority of medical schools, ethical training should be a part of the university curriculum for students in geology

Generic properties of a quasi-one-dimensional classical Wigner crystal

We studied the structural, dynamical properties and melting of a quasi-one-dimensional system of charged particles, interacting through a screened Coulomb potential. The ground-state energy was calculated and, depending on the density and the screening length, the system crystallizes in a number of chains. As a function of the density (or the confining potential), the ground state configurations and the structural transitions between them were analyzed both by analytical and Monte Carlo calculations. The system exhibits a rich phase diagram at zero temperature with continuous and discontinuous structural transitions. We calculated the normal modes of the Wigner crystal and the magnetophonons when an external constant magnetic field B is applied. At finite temperature the melting of the system was studied via Monte Carlo simulations using the modified Lindemann criterion (MLC). The melting temperature as a function of the density was obtained for different screening parameters. Reentrant melting as a function of the density was found as well as evidence of directional dependent melting. The single-chain regime exhibits anomalous melting temperatures according to the MLC and as a check we study the pair-correlation function at different densities and different temperatures, which allowed us to formulate a different melting criterion. Possible connection with recent theoretical and experimental results are discussed and experiments are proposed

Variation in Flavonoids in Leaves, Stems and Flowers of White Clover Cultivars:

In the present study, the major flavonoids of white clover ( Trifolium repens L.) cv. Sonja were extracted, isolated and identified. The major flavonoids in leaves and stems were the four flavonol glycosides: kaempferol-3- O-{Xyl(1→2)-Gal} (kaempferol-Xyl-Gal), kaempferol-3- O-{Rha(1→6)-[Xyl(1→2)]-Gal} (kaempferol-Rha-Xyl-Gal), quercetin-3- O-{Xyl(1→2)-Gal} (quercetin-Xyl-Gal), and quercetin-3- O-{Rha(1→6)-[Xyl(1→2)]-Gal} (quercetin-Rha-Xyl-Gal). Quercetin-Rha-Xyl-Gal has never been reported before and kaempferol-Rha-Xyl-Gal has not previously been identified in clover aerial parts. Concentrations of those compounds, together with aglyconic flavonoids previously described in white clover, as well as their glycosides, were quantified in leaves/stems and flowers of four white clover cvs Rabani, Klondike, Ramona and Aran using tandem mass spectrometry. There were significant differences in flavonoid concentrations in the two plant parts, with the highest concentrations of most aglycones in flowers and the highest concentrations of most glycosides in leaves/stems. This distribution of compounds may indicate different ways of storage and/or different mechanisms of action of the compounds. The cultivars were selected for genetic diversity, which resulted in distinctly different amounts of flavonoids in the plants. Concentrations of 17 of 24 compounds varied significantly – for some compounds up to a factor of 10 – among cultivars. Total flavonoid concentrations in flowers did not vary greatly among cultivars, at 28.9–35.8 mmol/g dry material (DM). In contrast, in leaves/stems, the cvs Rabani and Klondike had lower concentrations of most flavonoids (total concentrations 10.0 and 12.7 mmol/gDM, respectively) compared to cvs Aran and Ramona (32.3 and 22.1 mmol/gDM, respectively). There is a potential for breeding/selection of cultivars with targeted concentrations of particular flavonoids

Generic properties of a quasi-one dimensional classical Wigner crystal

We studied the structural, dynamical properties and melting of a quasi-one-dimensional system of charged particles, interacting through a screened Coulomb potential. The ground state energy was calculated and, depending on the density and the screening length, the system crystallizes in a number of chains. As a function of the density (or the confining potential), the ground state configurations and the structural transitions between them were analyzed both by analytical and Monte Carlo calculations. The system exhibits a rich phase diagram at zero temperature with continuous and discontinuous structural transitions. We calculated the normal modes of the Wigner crystal and the magneto-phonons when an external constant magnetic field $B$ is applied. At finite temperature the melting of the system was studied via Monte Carlo simulations using the $modified$ $Lindemann$ $criterion$ (MLC). The melting temperature as a function of the density was obtained for different screening parameters. Reentrant melting as a function of the density was found as well as evidence of directional dependent melting. The single chain regime exhibits anomalous melting temperatures according to the MLC and as a check we study the pair correlation function at different densities and different temperatures, formulating a different criterion. Possible connection with recent theoretical and experimental results are discussed and experiments are proposed.Comment: 13 pages text, 21 picture

Direct interation of garcinol and related polyisoprenylated benzophenones of Garcinia cambogia fruits with the transcription factor STAT-1 as a likely mechanism of their inhibitory effect on cytokine signaling pathways.

Garcinol (1), a polyisoprenylated benzophenone occurring in Garcinia species, has been reported to exert anti-inflammatory activity in LPS-stimulated macrophages, through inhibition of NF-κB and/or JAK/STAT-1 activation. In order to provide deeper insight into its effects on the cytokine signaling pathway and to clarify the underlying molecular mechanisms, 1 was isolated from the fruits of Garcinia cambogia along with two other polyisoprenylated benzophenones, guttiferones K (2) and guttiferone M (3), differing from each other in their isoprenyl moieties and their positions on the benzophenone core. The affinities of 1-3 for the STAT-1 protein have been evaluated by surface plasmon resonance and molecular docking studies and resulted in KD values in the micromolar range. Consistent with the observed high affinity toward the STAT-1 protein, garcinol and guttiferones K and M were able to modulate cytokine signaling in different cultured cell lines, mainly by inhibiting STAT-1 nuclear transfer and DNA binding, as assessed by an electrophorectic mobility shift assay

Industrial upcycling of almond skin through production of novel brioches

The global sustainability policy emphasizes reusing of agri-food waste and by-products to enhance food bioactive properties. Thus, brioches were processed incorporating almond skin powder (ASP): control (CTR), without ASP addition; 5-ASP, with 5% (w/w) ASP; and 10-ASP, with 10% (w/w) ASP. Seven different brioches shapes were obtained for each recipe. Flavonoids were mainly detected in Tuono almond skin by Ultra-High Performance Liquid Chromatography coupled to High-Resolution Mass Spectrometry (UHPLC-HRMSMS), in particular, flavan-3-ol monomers. The ethanolic extract of Tuono almond skins contained polar lipids (oxylipins and phospholipids). Gas Chromatography–Mass Spectrometry (GC-MS) identified six major fatty acids, mainly oleic acid (48.01%). Photothermal degradation impact on bioactive compounds was evaluated using a first-order kinetic model. Antioxidant activity was studied using 2,2′-azino-bis(3-ethylbenzothiazoline-6-sulfonic acid), 2,2-diphenyl-1-picrylhydrazyl and β-carotene bleaching test. α-amylase, α-glucosidase, and lipase inhibitory effect were also tested. The acidification of the doughs was consistent across all trials. Lactic acid bacteria and yeast levels increased. Importantly, the final products were free from undesirable microorganisms. The addition of ASP led to reduced weight loss and specific volume for all seven brioche types. Furthermore, the firmness, crumb structure, and sensory profile of the final products were noticeably influenced. Tasters clearly favoured the Treccina brioches. The production of sweet leavened baked goods was carried out in triplicate in two independent experiments. The statistical model applied to the data considered the effects of brioche shape and the addition of ASP. Kinetic data revealed that the half-life extension for both total phenol and flavonoid content was observed in the 10-ASP sample (18.00382). 10-ASP sample exhibited promising ABTS radical scavenging activity, with inhibitory concentration 50% (IC50) values of 18.64 mg/mL after 9 days of photothermal degradation. Moreover, when testing 10-ASP Treccina against α-amylase and α-glucosidase, the IC50 values were 198.16 and 190.23 μg/mL, respectively, even after 9 days