1,303 research outputs found
Two modes of peri-interaction between an aldehyde group and a carboxylate anion in naphthalaldehydate salts
Crystal structures of the salts of 1,8-naphthalaldehydic acid (8-formyl-1-naphthoic acid) show one of two types of interaction between the functional groups. In the more commonly observed case, a carboxylate oxygen lies close to the aldehyde carbonyl carbon atom (OâŻC: 2.445â2.630 Ă
) and makes an nâpi* interaction. However, in two other cases the carboxylate group has rotated so that the aldehyde now directs its hydrogen atom at the face of the carboxylate group and forms a surprisingly short contact with the carbon atom (HâŻC: 2.29 and 2.42 Ă
). This interaction is likely to be electrostatic in nature
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Radiation exposure awareness from patients undergoing nuclear medicine diagnostic 99mTc-MDP bone scans and 2-deoxy-2-(18F) fluoro-D-glucose PET/computed tomography scans
INTRODUCTION: Medical imaging is on average the largest source of artificial radiation exposure worldwide. This study seeks to understand patient's awareness of radiation exposure derived from nuclear medicine diagnostic scans and assess if current information provided by leaflets is adequate.
METHODS: Single-centre cross-sectional questionnaire study applied to bone scan and FDG PET/computed tomography patients, at a nuclear medicine and PET/computed tomography department over a 15-week period in 2018. Questionnaires on dose comparators were designed in collaboration with patients, public, and experts in radiation exposure. Qualitative data were analysed using thematic analysis and quantitative data using SPSS (V. 24).
RESULTS: A total of 102 questionnaires were completed (bone scan = 50; FDG PET/computed tomography = 52). Across both groups, 33/102 (32.4%) patients reported having a reasonable understanding of nuclear medicine and 21/102 (20.6%) reported a reasonable knowledge of ionising radiations. When asked to compare the exposure dose of respective scans with common comparators 8/50 (16%) of bone scan patients and 11/52 (21.2%) FDG PET/computed tomography answered correctly. On leaflet information, 15/85 (17.6%) patients reported the leaflets do not provide enough information on radiation exposure and of these 10/15 (66.7%) commented the leaflets should incorporate more information on radiation exposure dose.
CONCLUSION: More observational and qualitative studies in collaboration with patients are warranted to evaluate patients' understanding and preferences in communication of radiation exposure from nuclear medicine imaging. This will ensure communication tools and guidelines developed to comply with ionising radiation (medical exposure) regulation 2017 are according to patients needs and preferences
Present-day trends of vertical ground motion along the coast lines
International audienceVertical ground motion (VGM) rates stand as crucial information, either for predicting the impact of the actual sea level rise along low-lying coasts or refining geodynamic problems. Because present day VGM rates have a magnitude smaller than 10 mm/yr, they remain challenging to quantify and often elusive. We focus on the quantification of global-scale VGM rates in order to identify global or regional trends. We computed VGM rates by combining tide gauges records and local satellite altimetry, which yield a new dataset of 634 VGM rates. We further compare this database to previous studies that use geodetic techniques and tide gauges records in order to evaluate the consistency of both our results and previous ones. The magnitudes differ by less than 5 mm/yr, and similar subsidence and uplift general tendencies appear. Even if the asset of our database stands in the greater number of sites, the combination of all studies, each with different pros and cons, yields a hybrid dataset that makes our attempt to extract VGM trends more robust than any other, independent study. Fennoscandia, the West coast of North America, and the eastern coast of Australia are uplifting, while the eastern coast of North America, the British Isles and Western Europe, the eastern Mediterranean Sea, Japan, and the western coast of Australia are subsiding. Glacial Isostatic Adjustment (GIA) is expected to provide a major contribution to the present-day signal. Aside from Fennoscandia, observed VGM often depart from the GIA model predictions of Peltier (2004). This either results from an underestimate of the model predictions or from the influence of other processes: indeed, the influence of the geodynamic setting appears in particular along the coasts of western North America or Japan, where the alternation of transform faults and subduction zones makes it possible to assign contrasted behaviours to the local geodynamic context. Local mechanisms like anthropogenic processes or sediment compaction, also contribute to VGM. This remains true for the critical cases of Venice, the Gulf of Mexico, the Ganges delta, and the Maldives, which are particularly exposed to the current sea level rise
Synthesising, using, and correcting for telluric features in high-resolution astronomical spectra
We present a technique to synthesise telluric absorption and emission
features both for in-situ wavelength calibration and for their removal from
astronomical spectra. While the presented technique is applicable for a wide
variety of optical and infrared spectra, we concentrate in this paper on
selected high-resolution near-infrared spectra obtained with the CRIRES
spectrograph to demonstrate its performance and limitation. We find that
synthetic spectra reproduce telluric absorption features to about 2%, even
close to saturated line cores. Thus, synthetic telluric spectra could be used
to replace the observation of telluric standard stars, saving valuable
observing time. This technique also provides a precise in-situ wavelength
calibration, especially useful for high-resolution near-infrared spectra in the
absence of other calibration sources.Comment: 11 pages, 11 figures, accepted for publication in A&A (updated
version
Electronic band structure and carrier effective mass in calcium aluminates
First-principles electronic band structure investigations of five compounds
of the CaO-Al2O3 family, 3CaO.Al2O3, 12CaO.7Al2O3, CaO.Al2O3, CaO.2Al2O3 and
CaO.6Al2O3, as well as CaO and alpha-, theta- and kappa-Al2O3 are performed. We
find that the conduction band in the complex oxides is formed from the oxygen
antibonding p-states and, although the band gap in Al2O3 is almost twice larger
than in CaO, the s-states of both cations. Such a hybrid nature of the
conduction band leads to isotropic electron effective masses which are nearly
the same for all compounds investigated. This insensitivity of the effective
mass to variations in the composition and structure suggests that upon a proper
degenerate doping, both amorphous and crystalline phases of the materials will
possess mobile extra electrons
CVM studies on the atomic ordering in complex perovskite alloys
The atomic ordering in complex perovskite alloys is investigated by the
cluster variation method (CVM). For the 1/3\{111\}-type ordered structure, the
order-disorder phase transition is the first order, and the order parameter of
the 1:2 complex perovskite reaches its maximum near x=0.25. For the
1/2\{111\}-type ordered structure, the ordering transition is the second order.
Phase diagrams for both ordered structures are obtained. The order-disorder
line obeys the linear law.Comment: 10 pages, 6 figure
Measurement of the 3He mass diffusion coefficient in superfluid 4He over the 0.45-0.95 K temperature range
We have measured the mass diffusion coefficient D of 3He in superfluid 4He at
temperatures lower than were previously possible. The experimental technique
utilizes scintillation light produced when neutron react with 3He nuclei, and
allows measurement of the 3He density integrated along the trajectory of a
well-defined neutron beam. By measuring the change in 3He density near a heater
as a function of applied heat current, we are able to infer values of D with
20% accuracy. At temperatures below 0.7 K and for concentrations of order
10^{-4} we find D=(2.0+2.4-1.2)T^-(6.5 -/+ 1.2) cm^2/s, in agreement with a
theoretical approximation.Comment: 8 pages, 5 figures. Submitted to Europhysics Letters and prepared in
that journal's forma
Electrostatic model of atomic ordering in complex perovskite alloys
We present a simple ionic model which successfully reproduces the various
types of compositional long-range order observed in a large class of complex
insulating perovskite alloys. The model assumes that the driving mechanism
responsible for the ordering is simply the electrostatic interaction between
the different ionic species. A possible new explanation for the anomalous
long-range order observed in some Pb relaxor alloys, involving the proposed
existence of a small amount of Pb^4+ on the B sublattice, is suggested by an
analysis of the model.Comment: 4 pages, two-column style with 1 postscript figure embedded. Uses
REVTEX and epsf macros. Also available at
http://www.physics.rutgers.edu/~dhv/preprints/index.html#lb_orde
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