Radiant energy transport in cryogenic condensates

Radiative properties of solid condensed gases with respect to cryodeposit

EFFECT OF HYDROGEN EXPOSURE ON THE ELECTRONIC AND OPTICAL PROPERTIES OF INSULATING TITANATES

Hydrogen exposure of insulating d0-titanates, such as SrTiO3 (STO), has displayed the formation of intriguing conducting states. These conducting states form through the use of forming gas (N2/H2) annealing or hydrogen plasma exposure, where hydrogen gas is exposed to high energy microwaves. The exposure of STO to hydrogen causes metallic conductivity due to the introduction of hydrogen cations on some of the oxygen sites. However, the optical properties of this hydrogen-exposed STO have not been well-studied. Further, Ba0.5Sr0.5TiO3 (BST), an insulating dielectric, also shows changes in its conductivity upon hydrogen exposure. Unlike STO where the conductivity of the hydrogen-exposed material has been characterized, the optical, electronic, and transport properties of hydrogen exposed BST have not been studied. Thus, by studying hydrogen-exposed BST and STO, our understanding of the effects of hydrogen on insulators can be enhanced. In the first study, the effects of the exposure of insulating dielectric BST thin films to a hydrogen plasma is presented. These BST thin films are deposited on GdScO3 (GSO) substrates via Pulsed Laser Deposition (PLD). After deposition, the thin films are exposed to a hydrogen plasma. Just five minutes of hydrogen plasma exposure is enough to induce conductivity in the BST thin film. This conducting state is dominated by the interplay of disorder and strong electron correlations introduced during hydrogen exposure. Further, the optical properties indicate the formation of a transparent conductor, as the introduction of disorder and strong correlations has not changed the optical properties of the BST thin film in the visible spectrum. BST demonstrates an example of a new type of transparent conductor that utilizes large effective mass carriers to generate conductivity. In the second study, the effects of hydrogen doping on the surface of STO is explored. The conducting heterointerface that forms between PLD-deposited thin films of LaAlO3 (LAO) on STO is used as the standard to explore this hydrogen surface doping. The optical, electronic, and transport properties of water-leached and buffered hydrofluoric acid (BHF) etched heterointerfaces are characterized and compared. The recently developed water-leaching method is compared with the well-known BHF etching method, which has been shown to unintentionally dope the STO surface with fluorine and hydrogen. Both methods generate single-terminated atomically flat STO substrate surfaces that are ideal for heterointerface formation. After deposition, the optical, electronic, and transport properties of both the water-leached and BHF-etched heterointerfaces show no meaningful difference, demonstrating that water-leaching may also unintentionally dope the STO substrate surface with hydrogen. However, these results confirm that water-leaching generates a high-quality conducting heterointerface without the safety concerns of BHF

Polyenamines from aromatic diacetylenic diketones and diamines

The synthesis and characterization of several polyenamine ketones are discussed wherein conjugated diacetylenic diketones and aromatic diamines are used as a route to the formation of high molecular weight polyenamine ketones which exhibit good mechanical properties and can be cast into creasible films. Typical polymerization conditions involved the reaction of stoichiometric amounts of 1,4- or 1,3-PPPO and a diamine at 60 to 130 C in m-cresol at (w/w) solids content of 8 to 26% for a specified period of time under a nitrogen atmosphere. Novel polyenamine ketones were prepared with inherent viscosities as high as 1.99 dl/g and tough, clear amber films with tensile strengths of 12,400 psi and tensile moduli of 397,000 psi were cast from solutions of the polymers in chloroform. In most cases, the elemental analyses for the polyenamine ketones agree within + or - 0.3% of the theoretical values

Gamma-Ray Burst Detection with INTEGRAL/SPI

The spectrometer SPI, one of the two main instruments of the INTEGRAL spacecraft, has strong capabilities in the Field of Gamma-Ray Burst (GRB) detections. In its 16 degree Field of view (FoV) SPI is able to trigger and to localize GRBs. With its large anticoincidence shield (ACS) of 512 kg of BGO crystals SPI is able to detect GRBs quasi omnidirectionally with a very high sensitivity. The ACS GRB alerts will provide GRB arrival times with high accuracy but with no or very rough positional information. The expected GRB detection rate in SPI's FoV will be one per month and for the ACS around 300 per year. At MPE two SPI software contributions to the real-time INTEGRAL burst-alert system (IBAS) at the INTEGRAL science data centre ISDC have been developed. The SPI-ACS branch of IBAS will produce burst alerts and light-curves with 50 ms resolution. It is planned to use ACS burst alerts in the 3rd interplanetary network. The SPI-FoV branch of IBAS is currently under development at MPE. The system is using the energy and timing information of single and multiple events detected by the Germanium-camera of SPI. Using the imaging algorithm developed at the University of Birmingham the system is expected to locate strong bursts with an accuracy of better than 1 degree.Comment: 11 pages, 5 figure

Decoherence at zero temperature

Most discussions of decoherence in the literature consider the high-temperature regime but it is also known that, in the presence of dissipation, decoherence can occur even at zero temperature. Whereas most previous investigations all assumed initial decoupling of the quantum system and bath, we consider that the system and environment are entangled at all times. Here, we discuss decoherence for a free particle in an initial Schr\"{o}dinger cat state. Memory effects are incorporated by use of the single relaxation time model (since the oft-used Ohmic model does not give physically correct results)

The language of leadership in Laos

© 2016, © The Author(s) 2016. This paper responds to recent calls in the leadership studies literature for anthropologically informed empirical research on leadership phenomena in non-Western and non-Anglophone settings. The authors have worked extensively on rural development projects in Laos and draw on ethnographic ‘observant-participation’ and interview data to explore how leadership is construed in a contested terrain where traditional concepts intersect with those of official government and international development agencies. A theoretical discussion of linguistic relativity and the socially constitutive nature of language in general is offered as background justification for studying the language of leadership in context. The anthropological distinction between etic and emic operations is also introduced to differentiate between various interpretative positions that can be taken in relation to the fieldwork and data discussed in this paper. The study shows how difficult it can be for native Lao speakers to find words to describe leadership or give designations to ‘leaders’ outside of officially sanctioned semantic and social fields. A key finding of the study is that, viewed from the perspective of the Lao People’s Revolutionary Party, authority and leadership are coextensive. This social fact is reflected in the linguistic restrictions on what can and cannot be described as leadership in Laos

Avian Resistance to Campylobacter jejuni Colonization Is Associated with an Intestinal Immunogene Expression Signature Identified by mRNA Sequencing

peer-reviewedThis research was funded by the The Irish Department of Agriculture and Food’s Food Institutional Research Measure (http://www.agriculture.gov.ie/ research/foodinstitutionalresearchmeasurefirm) – Grant No: 06_RDD_486.Campylobacter jejuni is the most common cause of human bacterial gastroenteritis and is associated with several post-infectious manifestations, including onset of the autoimmune neuropathy Guillain-Barré syndrome, causing significant morbidity and mortality. Poorly-cooked chicken meat is the most frequent source of infection as C. jejuni colonizes the avian intestine in a commensal relationship. However, not all chickens are equally colonized and resistance seems to be genetically determined. We hypothesize that differences in immune response may contribute to variation in colonization levels between susceptible and resistant birds. Using high-throughput sequencing in an avian infection model, we investigate gene expression associated with resistance or susceptibility to colonization of the gastrointestinal tract with C. jejuni and find that gut related immune mechanisms are critical for regulating colonization. Amongst a single population of 300 4-week old chickens, there was clear segregation in levels of C. jejuni colonization 48 hours post-exposure. RNAseq analysis of caecal tissue from 14 C. jejuni-susceptible and 14 C. jejuni-resistant birds generated over 363 million short mRNA sequences which were investigated to identify 219 differentially expressed genes. Significantly higher expression of genes involved in the innate immune response, cytokine signaling, B cell and T cell activation and immunoglobulin production, as well as the renin-angiotensin system was observed in resistant birds, suggesting an early active immune response to C. jejuni. Lower expression of these genes in colonized birds suggests suppression or inhibition of a clearing immune response thus facilitating commensal colonization and generating vectors for zoonotic transmission. This study describes biological processes regulating C. jejuni colonization of the avian intestine and gives insight into the differential immune mechanisms incited in response to commensal bacteria in general within vertebrate populations. The results reported here illustrate how an exaggerated immune response may be elicited in a subset of the population, which alters host-microbe interactions and inhibits the commensal state, therefore having wider relevance with regard to inflammatory and autoimmune disease