Polarimetry and photometry of the peculiar main-belt object 7968 = 133P/Elst-Pizarro

133P/Elst-Pizarro is an object that has been described as either an active asteroid or a cometary object in the main asteroid belt. Here we present a photometric and polarimetric study of this object in an attempt to infer additional information about its origin. With the FORS1 instrument of the ESO VLT, we have performed during the 2007 apparition of 133P/Elst-Pizarro quasi-simultaneous photometry and polarimetry of its nucleus at nine epochs in the phase angle range 0 - 20 deg. For each observing epoch, we also combined all available frames to obtain a deep image of the object, to seek signatures of weak cometary activity. Polarimetric data were analysed by means of a novel physical interference modelling. The object brightness was found to be highly variable over timescales <1h, a result fully consistent with previous studies. Using the albedo-polarization relationships for asteroids and our photometric results, we found for our target an albedo of about 0.06-0.07 and a mean radius of about 1.6 km. Throughout the observing epochs, our deep imaging of the comet detects a tail and an anti-tail. Their temporal variations are consistent with an activity profile starting around mid May 2007 of minimum duration of four months. Our images show marginal evidence of a coma around the nucleus. The overall light scattering behaviour (photometry and polarimetry) resembles most closely that of F-type asteroids.Comment: Accepted by Astronomy and Astrophysic

Near-infrared colors of minor planets recovered from VISTA - VHS survey (MOVIS)

The Sloan Digital Sky Survey (SDSS) and Wide-field Infrared Survey Explorer (WISE) provide information about the surface composition of about 100,000 minor planets. The resulting visible colors and albedos enabled us to group them in several major classes, which are a simplified view of the diversity shown by the few existing spectra. We performed a serendipitous search in VISTA-VHS observations using a pipeline developed to retrieve and process the data that corresponds to solar system objects (SSo). The colors and the magnitudes of the minor planets observed by the VISTA survey are compiled into three catalogs that are available online: the detections catalog (MOVIS-D), the magnitudes catalog (MOVIS-M), and the colors catalog (MOVIS-C). They were built using the third data release of the survey (VISTA VHS-DR3). A total of 39,947 objects were detected, including 52 NEAs, 325 Mars Crossers, 515 Hungaria asteroids, 38,428 main-belt asteroids, 146 Cybele asteroids, 147 Hilda asteroids, 270 Trojans, 13 comets, 12 Kuiper Belt objects and Neptune with its four satellites. The colors found for asteroids with known spectral properties reveal well-defined patterns corresponding to different mineralogies. The distributions of MOVIS-C data in color-color plots shows clusters identified with different taxonomic types. All the diagrams that use (Y-J) color separate the spectral classes more effectively than the (J-H) and (H-Ks) plots used until now: even for large color errors (<0.1), the plots (Y-J) vs (Y-Ks) and (Y-J) vs (J-Ks) provide the separation between S-complex and C-complex. The end members A, D, R, and V-types occupy well-defined regions.Comment: 19 pages, 16 figure

Testing the comet nature of main belt comets. The spectra of 133P/Elst-Pizarro and 176P/LINEAR

We present the visible spectrum of MBCs 133P/Elst-Pizarro and 176P/LINEAR, as well as three Themis family asteroids: (62) Erato, (379), Huenna and (383) Janina, obtained in 2007 using three telescopes at "El Roque de los Muchachos"' Observatory, in La Palma, Spain, and the 8m Kueyen (UT2) VLT telescope at Cerro Paranal, Chile. The spectra of 133P and 176P resemble best those of B-type asteroid and are very similar to those of Themis family members and are significantly different from the spectrum of comet 162P/Siding-Spring and most of the observed cometary nuclei. CN gas emission is not detected in the spectrum of 133P. We determine an upper limit for the CN production rate Q(CN) = $= 2.8 \times 10^{21}$ mol/s, three orders of magnitude lower than the Q(CN) of Jupiter family comets observed at similar heliocentric distances. The spectra of 133P/Elst-Pizarro and 176P/LINEAR confirm that they are likely members of the Themis family of asteroids, fragments that probably retained volatiles, and unlikely have a cometary origin in the trans-neptunian belt or the Oort cloud.Comment: Paper sumbmited to A&A. 7 pages and 6 figure

Coordinated thermal and optical observations of Trans-Neptunian object (20000) Varuna from Sierra Nevada

We report on coordinated thermal and optical measurements of trans-Neptunian object (20000) Varuna obtained in January-February 2002, respectively from the IRAM 30-m and IAA 1.5 m telescopes. The optical data show a lightcurve with a period of 3.176+/-0.010 hr, a mean V magnitude of 20.37+/-0.08 and a 0.42+/-0.01 magnitude amplitude. They also tentatively indicate that the lightcurve is asymmetric and double-peaked. The thermal observations indicate a 1.12+/-0.41 mJy flux, averaged over the object's rotation. Combining the two datasets, we infer that Varuna has a mean 1060(+180/-220) km diameter and a mean 0.038(+0.022/-0.010) V geometric albedo, in general agreement with an earlier determination using the same technique.Comment: Accepted for publication in Astronomy & Astrophysics (7 pages, including 3 figures

A route to benzodithiophene systems by exploiting a ligand-free Suzuki-Miyaura coupling reaction in deep eutectic solvents

Benzo[1,2-b:4,3-b\u2019]dithiophene (BDT) and its derivatives belong to an interesting class of thiophene-based aromatic \uf070-conjugated compounds that are widely studied as functional organic materials inserted, for instance, as units in mono and polydisperse oligomers [1], or as \uf070-spacers in push-pull organic chromophores for photovoltaic applications [2]. Moreover, BDTs are key intermediates for the synthesis of inherent chiral tetrathia[7]helicenes, which are an attractive class of heterohelicenes with unique physicochemical and chiroptical properties due to their helix-like structure [3]. Thus, BDT is a key starting molecule which can allow access to more complex and interesting systems through a selective and judicious functionalization of the \uf061 and \uf062-positions of the terminal thiophene rings. Building on our recent studies on the synthesis and functionalization of BDTs [4], we questioned whether a novel class of 2,7-diarylsubstituted BDTs 1 (Figure 1) could be synthesized via a palladium-catalysed Suzuki-Miyaura reaction between heteroaryl halides 2 and organoboron derivatives 3 in Deep Eutectic Solvents (DESs), which have proven to be effective as sustainable and environmentally responsible reaction media in several transition-metal-catalyzed reactions [5].In this communication, we report our preliminary results on the preparation of diarylsubstituted BDTs 1, and discuss the substrate scope of the proposed protocol. Some of the compounds so far obtained display interesting photophysical properties, which are currently under investigation

Transmission curves and effective refraction indices of MKO near infrared consortium filters at cryogenic temperatures

We report transmission measurements at cryogenic temperatures for 4 broad-band filters of the Mauna Kea Observatories (MKO) near-infrared filter set and 5 narrow-band filters. The spectral scans were collected using the multi-mode IR instrument of the TNG telescope (NICS) in which these filters are permanently mounted and commonly used for astronomical observations. We determined the transmission curves at a temperature of 78K and found no significant red-leak up to 2.6 microns, the data are available in electronic form on the TNG web page. We also estimated the variation of the wavelength response with the incidence angle and found it compatible with an effective refractive index of about 2

Water-ice driven activity on Main-Belt Comet P/2010 A2 (LINEAR) ?

The dust ejecta of Main-Belt Comet P/2010 A2 (LINEAR) have been observed with several telescopes at the at the Observatorio del Roque de los Muchachos on La Palma, Spain. Application of an inverse dust tail Monte Carlo method to the images of the dust ejecta from the object indicates that a sustained, likely water-ice driven, activity over some eight months is the mechanism responsible for the formation of the observed tail. The total amount of dust released is estimated to be 5E7 kg, which represents about 0.3% of the nucleus mass. While the event could have been triggered by a collision, this cannot be decided from the currently available data.Comment: Accepted for ApJ Letter

Structure based modeling of small molecules binding to the TLR7 by atomistic level simulations

Toll-Like Receptors (TLR) are a large family of proteins involved in the immune system response. Both the activation and the inhibition of these receptors can have positive effects on several diseases, including viral pathologies and cancer, therefore prompting the development of new compounds. In order to provide new indications for the design of Toll-Like Receptor 7 (TLR7)-targeting drugs, the mechanism of interaction between the TLR7 and two important classes of agonists (imidazoquinoline and adenine derivatives) was investigated through docking and Molecular Dynamics simulations. To perform the computational analysis, a new model for the dimeric form of the receptors was necessary and therefore created. Qualitative and quantitative differences between agonists and inactive compounds were determined. The in silico results were compared with previous experimental observations and employed to define the ligand binding mechanism of TLR7

Exploring miR-9 Involvement in Ciona intestinalis Neural Development Using Peptide Nucleic Acids

The microRNAs are small RNAs that regulate gene expression at the post-transcriptional level and can be involved in the onset of neurodegenerative diseases and cancer. They are emerging as possible targets for antisense-based therapy, even though the in vivo stability of miRNA analogues is still questioned. We tested the ability of peptide nucleic acids, a novel class of nucleic acid mimics, to downregulate miR-9 in vivo in an invertebrate model organism, the ascidian Ciona intestinalis, by microinjection of antisense molecules in the eggs. It is known that miR-9 is a well-conserved microRNA in bilaterians and we found that it is expressed in epidermal sensory neurons of the tail in the larva of C. intestinalis. Larvae developed from injected eggs showed a reduced differentiation of tail neurons, confirming the possibility to use peptide nucleic acid PNA to downregulate miRNA in a whole organism. By identifying putative targets of miR-9, we discuss the role of this miRNA in the development of the peripheral nervous system of ascidians

Technology, Market Structure and the Gains from Trade

We study the gains from trade in a new model with oligopolistic competition, firm heterogeneity, and innovation. Lowering trade costs reduces markups on domestic sales but increases markups on export sales, as firms do not pass the entire reduction in trade costs onto foreign consumers. Trade liberalisation can also reduce the number of firms competing in each market, thereby increasing markups on both domestic and export sales. For the majority of exporters, however, the procompetitive effect prevails and their avera ge markups decline. The incomplete pass-though and the reduction in the number of competitors instead dominate for top-exporters – the top 0:1% of firms which end up increasing their markup. In a quantitative exercise we find that the aggregate effect of trade-induced markup changes is pro-competitive and accounts for the majority of the welfare gains from trade. Trade-induced changes in competition affect survival on domestic and export markets and firms’ decision to innovate. All exporters, and especially the top exporters, increase their market size after liberalisation which, in turn, encourages them to innovate more. Hence, top exporters contribute negatively to welfare gains by increasing their markups but positively by increasing innovation and productivity. Firms’ innovation response accounts for a small but non-negligible share of the welfare gains while the contribution of selection is U-shaped, being negative for small liberalisations and positive otherwise. A more globalised economy is therefore populated by larger, fewer and more innovative firms, each feature representing an important source of the gains from trade