2,894 research outputs found
Interpretation of very low resolution X-ray electron-density maps using core objects
The interpretation of a 20ā
Ć
resolution electron-density map using segmentation and pattern-recognition-based identification of domain shapes is described
Biogenesis of spiroketals by submerged cultured basidiomycete Trametes hirsuta
Volatile spiroketals are well-documented semiochemicals secreted by beetles and wasps for the intra- and interspecies communication. Its use in insect traps and as natural herbicide makes them of commercial interest. Besides insects, fungi are well-known producers, but the fungal biogenesis of spiroketals has remained speculative. Product formation along fatty acid degradation based on non-labeled feeding experiments was assumed. Thus, the observed occurrence of conophthorin and (E)- and (Z)-chalcograns in submerged cultures of the basidiomycete Trametes hirsuta prompted a precursor study aiming at a more detailed insight into their formation. Supplementation of (9Z,12 Z)-octadecadienoic (linoleic) acid resulted in elevated product yields and the identification of a fourth spiroketal, 2,8-dimethyl-1,7-dioxaspiro[5.5]-undecane. However, no intermediates of fatty acid degradation suitable as spiroketal precursors were identified. In addition, the hyphae lacked lipoxygenase activity, which was formerly supposed to be mandatory for spiroketal formation. Supplementation of 1-/2-13C acetate showed incorporation of the label into chalcogran. Therefore, a formation along the polyketide pathway analogous to insects was concluded. Graphical abstract: [Figure not available: see fulltext.
Avoided Antiferromagnetic Order and Quantum Critical Point in CeCoIn
We measured specific heat and resistivity of heavy fermion CeCoIn5 between
the superconducting critical field and 9 T, with field in the
[001] direction, and at temperatures down to 50mK. At 5T the data show Non
Fermi Liquid behavior down to the lowest temperatures. At field above 8T the
data exhibit crossover from the Fermi liquid to a Non Fermi Liquid behavior. We
analyzed the scaling properties of the specific heat, and compared both
resistivity and the specific heat with the predictions of a spin-fluctuation
theory. Our analysis leads us to suggest that the NFL behavior is due to
incipient antiferromagnetism (AF) in CeCoIn5, with the quantum critical point
in the vicinity of the . Below the AF phase which competes
with the paramagnetic ground state is superseded by the superconducting
transition.Comment: 5 pages, 3 figure
Magnetic-Field Induced Quantum Critical Point in YbRhSi
We report low-temperature calorimetric, magnetic and resistivity measurements
on the antiferromagnetic (AF) heavy-fermion metal YbRhSi ( 70
mK) as a function of magnetic field . While for fields exceeding the
critical value at which the low temperature resistivity
shows an dependence, a divergence of upon
reducing to suggests singular scattering at the whole Fermi
surface and a divergence of the heavy quasiparticle mass. The observations are
interpreted in terms of a new type of quantum critical point separating a
weakly AF ordered from a weakly polarized heavy Landau-Fermi liquid state.Comment: accepted for publication in Phys. Rev. Let
Sinistral shear during Middle Jurassic emplacement of the Matancilla Plutonic Complex in northern Chile (25.4ā¦ S) as evidence of oblique plate convergence during the early Andean orogeny
component of oblique subduction into an intra-arc shear zone. We document a shear zone at latitude 25.4ā¦ S near Taltal, Chile that was associated with intrusion of the Matancilla Plutonic Complex at ~169 Ma to evaluate intra-arc deformation and possible tectonic plate configurations during this time period. Polyphase folding of Paleozoic metasedimentary rocks is overprinted by mylonitic fabrics that are most extensive in a zone up to 1.4 km wide in the thermal aureole of the granodioritic Matancilla pluton, where contact metamorphic andalusite porphyroblasts are synkinematic with fabric development. Mylonite in metasedimentary rocks is overprinted by a ~130 Ma granodiorite (zircon UāPb) and by ~133 Ma postkinematic monazite (UāPb). Within the Jurassic Matancilla granodiorite, pervasive ductile shear occurs along the intrusive contact while centimeter-scale discrete high-strain zones throughout the pluton are associated with focused hydrothermal alteration and reaction weakening. Mylonitic foliation in the metasedimentary rocks and within the pluton strikes N- to NE and dips steeply, while stretching lineations are subhorizontal on average. Kinematic indicators record dominantly sinistral shear, though some dextral or symmetric indicators and S \u3e L fabrics suggest a component of coaxial strain and flattening. Sinistral strike-slip kinematics in the Matancilla shear zone may indicate that Middle Jurassic convergence had sinistral obliquity that was locally partitioned into the contemporaneous magmatic arc. Sinistral-oblique convergence would require the Phoenix- Farallon spreading center to be north of ~25ā¦ S in the Middle Jurassic, providing a constraint to plate reconstructions during the early Andean orogeny
READING and FEELING: the effects of a literature-based intervention designed to increase emotional competence in second and third graders
Emotional competence has an important inļ¬uence on development in school. We hypothesized that reading and discussing childrenās books with emotional content increases childrenās emotional competence. To examine this assumption, we developed a literature- based intervention, named READING and FEELING, and tested it on 104 second and third graders in their after-school care center. Children who attended the same care center but did not participate in the emotion-centered literary program formed the control group (n = 104). Our goal was to promote emotional competence and to evaluate the effectiveness of the READING and FEELING program. Emotional competence variables were measured prior to the intervention and 9 weeks later, at the end of the program. Results revealed signiļ¬cant improvements in the emotional vocabulary, explicit emotional knowledge, and recognition of masked feelings. Regarding the treatment effect for detecting masked feelings, we found that boys beneļ¬ted signiļ¬cantly more than girls. These ļ¬ndings underscore the assumption that childrenās literature is an appropriate vehicle to support the development of emotional competence in middle childhood
Sinistral shear during Middle Jurassic emplacement of the Matancilla Plutonic Complex in northern Chile (25.4\u3csup\u3eā¦\u3c/sup\u3e S) as evidence of oblique plate convergence during the early Andean orogeny
Arc magmatism in a continental subduction zone facilitates rheological weakening of the rigid upper plate, and can accommodate the partitioned trench-parallel component of oblique subduction into an intra-arc shear zone. We document a shear zone at latitude 25.4ā¦ S near Taltal, Chile that was associated with intrusion of the Matancilla Plutonic Complex at ~169 Ma to evaluate intra-arc deformation and possible tectonic plate configurations during this time period. Polyphase folding of Paleozoic metasedimentary rocks is overprinted by mylonitic fabrics that are most extensive in a zone up to 1.4 km wide in the thermal aureole of the granodioritic Matancilla pluton, where contact metamorphic andalusite porphyroblasts are synkinematic with fabric development. Mylonite in metasedimentary rocks is overprinted by a ~130 Ma granodiorite (zircon UāPb) and by ~133 Ma postkinematic monazite (UāPb). Within the Jurassic Matancilla granodiorite, pervasive ductile shear occurs along the intrusive contact while centimeter-scale discrete high-strain zones throughout the pluton are associated with focused hydrothermal alteration and reaction weakening. Mylonitic foliation in the metasedimentary rocks and within the pluton strikes N- to NE and dips steeply, while stretching lineations are subhorizontal on average. Kinematic indicators record dominantly sinistral shear, though some dextral or symmetric indicators and S \u3e L fabrics suggest a component of coaxial strain and flattening. Sinistral strike-slip kinematics in the Matancilla shear zone may indicate that Middle Jurassic convergence had sinistral obliquity that was locally partitioned into the contemporaneous magmatic arc. Sinistral-oblique convergence would require the Phoenix- Farallon spreading center to be north of ~25ā¦ S in the Middle Jurassic, providing a constraint to plate reconstructions during the early Andean orogeny
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