Energy Storage Capacity Of Reversible Liquid‐phase Diels Alder Reaction Between Maleic Anhydride And 2‐methyl Furan

Calorimetry was used to determine the heat of reaction and equilibrium constant at 318 K for the reaction between maleic anhydride (A) and 2‐methyl furan (B). The values were −60 kJ/gmol and 614 cm3/gmol, respectively. The motivation for this work was to find a single phase‐reacting system that could be used to store solar energy. Thus, the energy storage capacity was calculated for a mixture of A and B, both initially at 7 kmol/m3, in dioxane. The maximum apparent heat capacity of 7.37 J/cm3·K occurred at 334 K. This maximum value is 76% higher than the heat capacity of pure water. Copyright © 1983 American Institute of Chemical Engineer

Using giant african pouched rats to detect human tuberculosis: a review

Despite its characteristically low sensitivity, sputum smear microscopy remains the standard for diagnosing tuberculosis (TB) in resource-poor countries. In an attempt to develop an alternative or adjunct to microscopy, researchers have recently examined the ability of pouched rats to detect TB-positive human sputum samples and the microbiological variables that affect their detection. Ten published studies, reviewed herein, suggest that the rats are able to detect the specific odor of Mycobacterium tuberculosis, which causes TB, and can substantially increase new-case detections when used for second-line TB screening following microscopy. Further research is needed to ascertain the rats' ability to detect TB in children and in HIV-positive patients, to detect TB when used for first-line screening, and to be useful in broad-scale applications where cost effectiveness is a major consideration

P-Wave Charmonium Production in B-Meson Decays

We calculate the decay rates of $B$ mesons into P-wave charmonium states using new factorization formulas that are valid to leading order in the relative velocity of the charmed quark and antiquark and to all orders in the running coupling constant of QCD. We express the production rates for all four P states in terms of two nonperturbative parameters, the derivative of the wavefunction at the origin and another parameter related to the probability for a charmed-quark-antiquark pair in a color-octet S-wave state to radiate a soft gluon and form a P-wave bound state. Using existing data on $B$ meson decays into $\chi_{c1}$ to estimate the color-octet parameter, we find that the color-octet mechanism may account for a significant fraction of the $\chi_{c1}$ production rate and that $B$ mesons should decay into $\chi_{c2}$ at a similar rate.Comment: 14 page

Bovine oocytes in secondary follicles grow and acquire meiotic competence in severe combined immunodeficient mice

A rigorous methodology is developed that addresses numerical and statistical issues when developing group contribution (GC) based property models such as regression methods, optimization algorithms, performance statistics, outlier treatment, parameter identifiability, and uncertainty of the prediction. The methodology is evaluated through development of a GC method for the prediction of the heat of combustion (Δ<i>H</i>_c^o) for pure components. The results showed that robust regression lead to best performance statistics for parameter estimation. The bootstrap method is found to be a valid alternative to calculate parameter estimation errors when underlying distribution of residuals is unknown. Many parameters (first, second, third order group contributions) are found unidentifiable from the typically available data, with large estimation error bounds and significant correlation. Due to this poor parameter identifiability issues, reporting of the 95% confidence intervals of the predicted property values should be mandatory as opposed to reporting only single value prediction, currently the norm in literature. Moreover, inclusion of higher order groups (additional parameters) does not always lead to improved prediction accuracy for the GC-models; in some cases, it may even increase the prediction error (hence worse prediction accuracy). However, additional parameters do not affect calculated 95% confidence interval. Last but not least, the newly developed GC model of the heat of combustion (Δ<i>H</i>_c^o) shows predictions of great accuracy and quality (the most data falling within the 95% confidence intervals) and provides additional information on the uncertainty of each prediction compared to other Δ<i>H</i>_c^o models reported in literature

Master crossover behavior of parachor correlations for one-component fluids

The master asymptotic behavior of the usual parachor correlations, expressing surface tension $\sigma$ as a power law of the density difference $\rho_{L}-\rho_{V}$ between coexisting liquid and vapor, is analyzed for a series of pure compounds close to their liquid-vapor critical point, using only four critical parameters $(\beta_{c})^{-1}$, $\alpha_{c}$, $Z_{c}$ and $Y_{c}$, for each fluid. ... The main consequences of these theoretical estimations are discussed in the light of engineering applications and process simulations where parachor correlations constitute one of the most practical method for estimating surface tension from density and capillary rise measurements

Suppressed Decays of D_s^+ Mesons to Two Pseudoscalar Mesons

Using data collected near the Ds*+ Ds- peak production energy Ecm = 4170 MeV by the CLEO-c detector, we study the decays of Ds+ mesons to two pseudoscalar mesons. We report on searches for the singly-Cabibbo-suppressed Ds+ decay modes K+ eta, K+ eta', pi+ K0S, K+ pi0, and the isospin-forbidden decay mode Ds+ to pi+ pi0. We normalize with respect to the Cabibbo-favored Ds+ modes pi+ eta, pi+ eta', and K+ K0S, and obtain ratios of branching fractions: Ds+ to K+ eta / Ds+ to pi+ eta = (8.9 +- 1.5 +- 0.4)%, Ds+ to K+ eta' / Ds+ to pi+ eta' = (4.2 +- 1.3 +- 0.3)%, Ds+ to pi+ K0S / Ds+ to K+ K0S = (8.2 +- 0.9 +- 0.2)%, Ds+ to K+ pi0 / Ds+ to K+ K0S = (5.0 +- 1.2 +- 0.6)%, and Ds+ to pi+ pi0 / Ds+ to K+ K0S < 4.1% at 90% CL, where the uncertainties are statistical and systematic, respectively.Comment: 9 pages postscript,also available through http://www.lns.cornell.edu/public/CLNS/2007/, Submitted to PR

B Physics at the Tevatron: Run II and Beyond

This report provides a comprehensive overview of the prospects for B physics at the Tevatron. The work was carried out during a series of workshops starting in September 1999. There were four working groups: 1) CP Violation, 2) Rare and Semileptonic Decays, 3) Mixing and Lifetimes, 4) Production, Fragmentation and Spectroscopy. The report also includes introductory chapters on theoretical and experimental tools emphasizing aspects of B physics specific to hadron colliders, as well as overviews of the CDF, D0, and BTeV detectors, and a Summary.Comment: 583 pages. Further information on the workshops, including transparencies, can be found at the workshop's homepage: http://www-theory.lbl.gov/Brun2/. The report is also available in 2-up http://www-theory.lbl.gov/Brun2/report/report2.ps.gz or chapter-by-chapter http://www-theory.lbl.gov/Brun2/report

Correlated /\c-/\cbar production in e+e- annihilations at sqrt{s}~10.5 GeV

Using 13.6/fb of continuum two-jet e+e- -> ccbar events collected with the CLEO detector, we have searched for baryon number correlations at the primary quark level. We have measured the likelihood for a /\c+ charmed baryon to be produced in the hemisphere opposite a /\c- relative to the likelihood for a /\c+ charmed baryon to be produced opposite an anticharmed meson Dbar; in all cases, the reconstructed hadrons must have momentum greater than 2.3 GeV/c. We find that, given a /\c- (reconstructed in five different decay modes), a /\c+ is observed in the opposite hemisphere (0.72+/-0.11)% of the time (not corrected for efficiency). By contrast, given a Dbar in one hemisphere, a /\c+ is observed in the opposite hemisphere only (0.21+/-0.02)% of the time. Normalized to the total number of either /\c- or Dbar ``tags'', it is therefore 3.52+/-0.45+/-0.42 times more likely to find a /\c+ opposite a /\c- than a Dbar meson. This enhancement is not observed in the JETSET 7.3 e+e- -> ccbar Monte Carlo simulation.Comment: 19 pages, Latex, one figure separat