Организация работ по защите от коррозии линейной части магистрального газопровода с применением статистических методов

Объектом исследования является магистральный газопровод с диаметром 1220 мм и толщиной стенки 9,5 мм. Цель работы - выбор оптимальных параметров работы станции катодной защиты с применением статистических методов для обеспечения надежной эксплуатации газопровода. В данной исследовательской работе рассмотрены методы оптимизации параметров катодной станции. В результате исследования был применен статистический метод контрольных карт Шухарта и расчет электрохимических параметров трубопровода с подбором оборудования.The subject of the research is a gas main line with a diameter of 1220 mm and a wall thickness of 9.5 mm. The objective of the work is to choose the optimal parameters of the cathode protection station using statistical methods to ensure the reliable operation of the gas pipeline. In this research work methods optimization parameters of cathode station are considered. The research applied the statistical method of Shewhart control chart and the calculation of electrochemical parameters of the pipeline with the selection of equipment

The interrelation between the electronic parameters of nitrogen atom and intramolecular interactions in ammonia derivatives

The electronic parameters and intramolecular interactions in the ground and transition states of inversion of the amines H₂NXHn (XHn=CH₃, NH₂, OH, F, SiH₃, PH₂, SH, Cl) were calculated using DFT (PBE96/def2-tzvpp) method. It was established that the electronacceptor properties of the XHn substituents has a prevailing influence on the change of the electronic parameters of nitrogen atom. Its increase leads to both a decrease of the charge on the nitrogen atom and an increase of the s-character and population of nitrogen lone pair (LP). All parameters under consideration correlate with the χ- and σᵢ-constants of the XHn substituents. The correlation coefficients increase when amines that contain X atoms only from one period are considered separately. It was found that the ρ values for amines containing X atoms from the second or third period are substantially different. The changes of the donor-acceptor interaction energies, s-character and LP population cannot be probable causes for different sensitivity of the electronic parameters of amines containing X atoms from different periods to the change of electron-acceptor properties of the XHn substituents. It was established that the mentioned parameters has only a subordinated influence in comparison with the influence of electron-acceptor ability of the XHn substituents. The negative charge on the nitrogen atom decreases with the increase of s-character and LP population and also with the decrease of energies of donor-acceptor interactions which lead to the withdrawal of electron density from the nitrogen atom. The s-character and LP population increase with the decrease of energies of donor-acceptor interactions which result in the reduction of electron density on the nitrogen atom. The total positive charges of the XHn groups and hydrogen atoms at the nitrogen atom decrease with increasing the electron-acceptor ability of the XHn substituents. The representation of the electron-acceptor properties of the substituents was shown to be more valid by using the χ-constants than by using the σᵢ-constants. The chlorine atom is a weak electron acceptor in comparison with an amino group

“It’s not something I chose you know”: making sense of pedophiles’ sexual interest in children and the impact on their psychosexual identity

Sexual interest in children is one of the most strongly predictive of the known risk factors for sexual reconviction. It is an important aspect of risk assessment to identify the presence of such interest, and an important task for treatment providers to address such a sexual interest where it is present. It has been argued that understanding pedophiles’ deviant sexual interest in children can enhance risk assessment, management, and treatment planning. This research study aims to explore the phenomenology of deviant sexual interest in children, the impact it has on pedophilic offenders’ identities, and their views on the treatability of that interest. The study used semistructured interviews and repertory grids to make sense of participants’ experiences. The results revealed three superordinate themes: “‘living’ with a deviant sexual interest,” “relational sexual self,” and “possible and feared sexual self.” The analysis unpacks these themes and repertory grid analysis is used to explore a subset of participants’ identities in more detail. The results reveal that there needs to be an acceptance from both client and therapist that their sexual interest in children may never go away. Through this acceptance, clients could work on enhancing sexual self-regulation, recognizing their triggers, and so managing their sexual thoughts, feelings, and behavior. Implications for treatment are also discussed

Two-Dimensional Optical Control of Electron Spin Orientation by Linearly Polarized Light in InGaAs

Optical absorption of circularly polarized light is well known to yield an electron spin polarization in direct band gap semiconductors. We demonstrate that electron spins can even be generated with high efficiency by absorption of linearly polarized light in InxGa1-xAs. By changing the incident linear polarization direction we can selectively excite spins in both polar and transverse directions. These directions can be identified by the phase during spin precession using time-resolved Faraday rotation. We show that the spin orientations do not depend on the crystal axes suggesting an extrinsic excitation mechanism