Tres enfoques de la investigación sobre concepciones alternativas

In the last years the researchers on Science Education have given preferent attention to student's conceptions. Studies have been carried out and their interest is still growing. Our purpose in this paper is to give an approach to three ways of focusing the question: the calternative conceptions», the «ways of reasoning» and the «causal mental models» approaches. Our goal is to compare them and show, without being exhaustive, some of their findings and future spectatives

Olive Leaves as Biotemplates for Enhanced Solar-Light Harvesting by a Titania-Based Solid

Olive leaves (by-product from olive oil production in olive mills) were used as biotemplates to synthesize a titania-based artificial olive leaf (AOL). Scanning electron microscopy (SEM) images of AOL showed the successful replication of trichomes and internal structure channels present in olive leaves. The BET surface area of AOL was 52 m2·g−1. X-ray diffraction (XRD) and Raman spectra revealed that the resulting solid was in the predominantly-anatase crystalline form (7.5 nm average particle size). Moreover, the synthesis led to a red-shift in light absorption as compared to reference anatase (gap energies of 2.98 and 3.2 eV, respectively). The presence of surface defects (as evidenced by X-ray photoelectron spectroscopy, XPS, and electron paramagnetic resonance spectroscopy, EPR) and doping elements (e.g., 1% nitrogen, observed by elemental analysis and XPS) could account for that. AOL was preliminarily tested as a catalyst for hydrogen production through glycerol photoreforming and exhibited an activity 64% higher than reference material Evonik P25 under solar irradiation and 144% greater under ultraviolet radiation, (under voltage) UV

Bio-Templating: An Emerging Synthetic Technique for Catalysts. A Review

In the last few years, researchers have focused their attention on the synthesis of new catalyst structures based on or inspired by nature. Biotemplating involves the transfer of biological structures to inorganic materials through artificial mineralization processes. This approach offers the main advantage of allowing morphological control of the product, as a template with the desired morphology can be pre-determined, as long as it is found in nature. This way, natural evolution through millions of years can provide us with new synthetic pathways to develop some novel functional materials with advantageous properties, such as sophistication, miniaturization, hybridization, hierarchical organization, resistance, and adaptability to the required need. The field of application of these materials is very wide, covering nanomedicine, energy capture and storage, sensors, biocompatible materials, adsorbents, and catalysis. In the latter case, bio-inspired materials can be applied as catalysts requiring different types of active sites (i.e., redox, acidic, basic sites, or a combination of them) to a wide range of processes, including conventional thermal catalysis, photocatalysis, or electrocatalysis, among others. This review aims to cover current experimental studies in the field of biotemplating materials synthesis and their characterization, focusing on their application in heterogeneous catalysis

Hydrogen Production through Glycerol Photoreforming on TiO2/Mesoporous Carbon: Influence of the Synthetic Method

This article explores the effect of the synthetic method of titanium dioxide (TiO2)/C composites (physical mixture and the water-assisted/unassisted sol-gel method) on their photocatalytic activity for hydrogen production through glycerol photoreforming. The article demonstrates that, apart from a high surface area of carbon and the previous activation of its surface to favor titania incorporation, the appropriate control of titania formation is crucial. In this sense, even though the amount of incorporated titania was limited by the saturation of carbon surface groups (in our case, ca. 10 wt.% TiO2), the sol-gel process without water addition seemed to be the best method, ensuring the formation of small homogeneously-distributed anatase crystals on mesoporous carbon. In this way, a ca. 110-fold increase in catalyst activity compared to Evonik P25 (expressed as hydrogen micromole per grams of titania) was achieved

Biosynthesis of Silver Nanoparticles Using Chenopodium ambrosioides

Biosynthesis of silver nanoparticles (AgNPs) was achieved using extract of Chenopodium ambrosioides as a reducer and coating agent at room temperature (25°C). Two molar solutions of AgNO3 (1 mM and 10 mM) and five extract volumes (0.5, 1, 2, 3, and 5 mL) were used to assess quantity, shape, and size of the particles. The UV-Vis spectra gave surface plasmon resonance at 434–436 nm of the NPs synthesized with AgNO3 10 mM and all extract volumes tested, showing a direct relationship between extract volumes and quantity of particles formed. In contrast, the concentration of silver ions was related negatively to particle size. The smallest (4.9 ± 3.4 nm) particles were obtained with 1 mL of extract in AgNO3 10 mM and the larger amount of particles were obtained with 2 mL and 5 mL of extract. TEM study indicated that the particles were polycrystalline and randomly oriented with a silver structure face centered cubic (fcc) and fourier transform infrared spectroscopy (FTIR) indicated that disappearance of the –OH group band after bioreduction evidences its role in reducing silver ions

Photo-astrometric distances, extinctions, and astrophysical parameters for Gaia DR2 stars brighter than G = 18

Combining the precise parallaxes and optical photometry delivered by Gaia's second data release (Gaia DR2) with the photometric catalogues of PanSTARRS-1, 2MASS, and AllWISE, we derive Bayesian stellar parameters, distances, and extinctions for 265 million stars brighter than G=18. Because of the wide wavelength range used, our results substantially improve the accuracy and precision of previous extinction and effective temperature estimates. After cleaning our results for both unreliable input and output data, we retain 137 million stars, for which we achieve a median precision of 5% in distance, 0.20 mag in V-band extinction, and 245 K in effective temperature for G<14, degrading towards fainter magnitudes (12%, 0.20 mag, and 245 K at G=16; 16%, 0.23 mag, and 260 K at G=17, respectively). We find a very good agreement with the asteroseismic surface gravities and distances of 7000 stars in the Kepler, the K2-C3, and the K2-C6 fields, with stellar parameters from the APOGEE survey, as well as with distances to star clusters. Our results are available through the ADQL query interface of the Gaia mirror at the Leibniz-Institut f\"{u}r Astrophysik Potsdam (gaia.aip.de) and as binary tables at data.aip.de. As a first application, in this paper we provide distance- and extinction-corrected colour-magnitude diagrams, extinction maps as a function of distance, and extensive density maps, demonstrating the potential of our value-added dataset for mapping the three-dimensional structure of our Galaxy. In particular, we see a clear manifestation of the Galactic bar in the stellar density distributions, an observation that can almost be considered a direct imaging of the Galactic bar.Comment: 25 pages, 23 figures + appendix, accepted for publication in A&A. Data (doi:10.17876/gaia/dr.2/51) are available through ADQL queries at gaia.aip.d

Factores demográficos y psicosociales asociados al exceso de peso en una población de Colombia

Introducción: la obesidad es una enfermedad de alto interés en salud pública y de etiología multifactorial. Es necesario conocer los aspectos ambientales propios de cada región que contribuyen al desarrollo de esta patología. El objetivo del estudio fue evaluar en la actualidad en una población colombiana la asociación entre diversos factores demográficos y psicosociales de la infancia y la edad adulta con tener exceso de peso. Materiales y métodos: se realizó un estudio observacional, descriptivo y de corte transversal mediante una encuesta electrónica realizada a pacientes y acompañantes en la Clínica FOSCAL, donde se evaluaron las variables demográficas, las condiciones de vida en la infancia y los hábitos actuales. Fueron incluidos sujetos mayores de 18 años. Las personas con déficit cognitivo, pérdida involuntaria de más del 10 % del peso y embarazadas fueron excluidas. Resultados: en el análisis se incluyeron 490 participantes con edad promedio de 31,4±15 años; el 58,8 % fue mujeres y el 91,4 % procedía del área urbana. El 44,8 % de los encuestados tenía exceso de peso (32,6 % sobrepeso y 12,2 % obesidad). Se encontró asociación entre la edad actual (OR: 1,11; IC 95 %: 1,04-1,19; p=0,0,002), el peso alcanzado a los 18 años (OR: 1,10; IC 95%: 1,06-1,15; p<0,001) y haber vivido en la infancia en un conjunto residencial (OR: 0,40; IC 95 %: 0,18-0,88; p<0,001) con tener exceso de peso en la actualidad. Se apreció una ganancia de peso de 0,35 kg por año de vida cumplido. Otros hallazgos, como el consumo de alcohol y sustancias psicoactivas, así como la actividad física semanal no tuvieron asociación. Conclusiones: la edad, el peso alcanzado a los 18 años y el no haber vivido en un conjunto residencial en la infancia fueron los factores asociados a tener exceso de peso en una población adulta colombiana

Evolution of substrate specificity in a recipient's enzyme following horizontal gene transfer

Despite the prominent role of horizontal gene transfer (HGT) in shaping bacterial metabolism, little is known about the impact of HGT on the evolution of enzyme function. Specifically, what is the influence of a recently acquired gene on the function of an existing gene? For example, certain members of the genus Corynebacterium have horizontally acquired a whole L-tryptophan biosynthetic operon, whereas in certain closely related actinobacteria, for example, Mycobacterium, the trpF gene is missing. In Mycobacterium, the function of the trpF gene is performed by a dual-substrate (βα)8 phosphoribosyl isomerase (priA gene) also involved in L-histidine (hisA gene) biosynthesis. We investigated the effect of a HGT-acquired TrpF enzyme upon PriA’s substrate specificity in Corynebacterium through comparative genomics and phylogenetic reconstructions. After comprehensive in vivo and enzyme kinetic analyses of selected PriA homologs, a novel (βα)8 isomerase subfamily with a specialized function in L-histidine biosynthesis, termed subHisA, was confirmed. X-ray crystallography was used to reveal active-site mutations in subHisA important for narrowing of substrate specificity, which when mutated to the naturally occurring amino acid in PriA led to gain of function. Moreover, in silico molecular dynamic analyses demonstrated that the narrowing of substrate specificity of subHisA is concomitant with loss of ancestral protein conformational states. Our results show the importance of HGT in shaping enzyme evolution and metabolism