666 research outputs found
Color Detection Using Chromophore-Nanotube Hybrid Devices
We present a nanoscale color detector based on a single-walled carbon
nanotube functionalized with azobenzene chromophores, where the chromophores
serve as photoabsorbers and the nanotube as the electronic read-out. By
synthesizing chromophores with specific absorption windows in the visible
spectrum and anchoring them to the nanotube surface, we demonstrate the
controlled detection of visible light of low intensity in narrow ranges of
wavelengths. Our measurements suggest that upon photoabsorption, the
chromophores isomerize from the ground state trans configuration to the excited
state cis configuration, accompanied by a large change in dipole moment,
changing the electrostatic environment of the nanotube. All-electron ab initio
calculations are used to study the chromophore-nanotube hybrids, and show that
the chromophores bind strongly to the nanotubes without disturbing the
electronic structure of either species. Calculated values of the dipole moments
support the notion of dipole changes as the optical detection mechanism.Comment: Accepted by Nano Letter
Quantum Hall Effects in Graphene-Based Two-Dimensional Electron Systems
In this article we review the quantum Hall physics of graphene based
two-dimensional electron systems, with a special focus on recent experimental
and theoretical developments. We explain why graphene and bilayer graphene can
be viewed respectively as J=1 and J=2 chiral two-dimensional electron gases
(C2DEGs), and why this property frames their quantum Hall physics. The current
status of experimental and theoretical work on the role of electron-electron
interactions is reviewed at length with an emphasis on unresolved issues in the
field, including assessing the role of disorder in current experimental
results. Special attention is given to the interesting low magnetic field limit
and to the relationship between quantum Hall effects and the spontaneous
anomalous Hall effects that might occur in bilayer graphene systems in the
absence of a magnetic field
Unsupervised representation learning with attention and sequence to sequence autoencoders to predict sleepiness from speech
A Toy Model for Testing Finite Element Methods to Simulate Extreme-Mass-Ratio Binary Systems
Extreme mass ratio binary systems, binaries involving stellar mass objects
orbiting massive black holes, are considered to be a primary source of
gravitational radiation to be detected by the space-based interferometer LISA.
The numerical modelling of these binary systems is extremely challenging
because the scales involved expand over several orders of magnitude. One needs
to handle large wavelength scales comparable to the size of the massive black
hole and, at the same time, to resolve the scales in the vicinity of the small
companion where radiation reaction effects play a crucial role. Adaptive finite
element methods, in which quantitative control of errors is achieved
automatically by finite element mesh adaptivity based on posteriori error
estimation, are a natural choice that has great potential for achieving the
high level of adaptivity required in these simulations. To demonstrate this, we
present the results of simulations of a toy model, consisting of a point-like
source orbiting a black hole under the action of a scalar gravitational field.Comment: 29 pages, 37 figures. RevTeX 4.0. Minor changes to match the
published versio
Numerical properties of isotrivial fibrations
In this paper we investigate the numerical properties of relatively minimal
isotrivial fibrations \varphi \colon X \lr C, where is a smooth,
projective surface and is a curve. In particular we prove that, if and is neither ruled nor isomorphic to a quasi-bundle, then K_X^2
\leq 8 \chi(\mO_X)-2; this inequality is sharp and if equality holds then
is a minimal surface of general type whose canonical model has precisely two
ordinary double points as singularities. Under the further assumption that
is ample, we obtain K_X^2 \leq 8 \chi(\mO_X)-5 and the inequality is
also sharp. This improves previous results of Serrano and Tan.Comment: 30 pages. Final version, to appear in Geometriae Dedicat
Real-space mapping of tailored sheet and edge plasmons in graphene nanoresonators
Plasmons in graphene nanoresonators have many potential applications in photonics and optoelectronics, including room-temperature infrared and terahertz photodetectors, sensors, reflect arrays or modulators1, 2, 3, 4, 5, 6, 7. The development of efficient devices will critically depend on precise knowledge and control of the plasmonic modes. Here, we use near-field microscopy8, 9, 10, 11 between λ0 = 10–12 μm to excite and image plasmons in tailored disk and rectangular graphene nanoresonators, and observe a rich variety of coexisting Fabry–Perot modes. Disentangling them by a theoretical analysis allows the identification of sheet and edge plasmons, the latter exhibiting mode volumes as small as 10−8λ03. By measuring the dispersion of the edge plasmons we corroborate their superior confinement compared with sheet plasmons, which among others could be applied for efficient 1D coupling of quantum emitters12. Our understanding of graphene plasmon images is a key to unprecedented in-depth analysis and verification of plasmonic functionalities in future flatland technologies.Peer ReviewedPostprint (author's final draft
Impaired perception of facial motion in autism spectrum disorder
Copyright: © 2014 O’Brien et al. This is an open-access article distributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited.This article has been made available through the Brunel Open Access Publishing Fund.Facial motion is a special type of biological motion that transmits cues for socio-emotional communication and enables the discrimination of properties such as gender and identity. We used animated average faces to examine the ability of adults with autism spectrum disorders (ASD) to perceive facial motion. Participants completed increasingly difficult tasks involving the discrimination of (1) sequences of facial motion, (2) the identity of individuals based on their facial motion and (3) the gender of individuals. Stimuli were presented in both upright and upside-down orientations to test for the difference in inversion effects often found when comparing ASD with controls in face perception. The ASD group’s performance was impaired relative to the control group in all three tasks and unlike the control group, the individuals with ASD failed to show an inversion effect. These results point to a deficit in facial biological motion processing in people with autism, which we suggest is linked to deficits in lower level motion processing we have previously reported
Probing the Role of Protein Surface Charge in the Activation of PrfA, the Central Regulator of Listeria monocytogenes Pathogenesis
Listeria monocytogenes is a food-borne intracellular bacterial pathogen capable of causing serious human disease. L. monocytogenes survival within mammalian cells depends upon the synthesis of a number of secreted virulence factors whose expression is regulated by the transcriptional activator PrfA. PrfA becomes activated following bacterial entry into host cells where it induces the expression of gene products required for bacterial spread to adjacent cells. Activation of PrfA appears to occur via the binding of a small molecule cofactor whose identity remains unknown. Electrostatic modeling of the predicted PrfA cofactor binding pocket revealed a highly positively charged region with two lysine residues, K64 and K122, located at the edge of the pocket and another (K130) located deep within the interior. Mutational analysis of these residues indicated that K64 and K122 contribute to intracellular activation of PrfA, whereas a K130 substitution abolished protein activity. The requirement of K64 and K122 for intracellular PrfA activation could be bypassed via the introduction of the prfA G145S mutation that constitutively activates PrfA in the absence of cofactor binding. Our data indicate that the positive charge of the PrfA binding pocket contributes to intracellular activation of PrfA, presumably by facilitating binding of an anionic cofactor
Intermediate and extreme mass-ratio inspirals — astrophysics, science applications and detection using LISA
Black hole binaries with extreme (gtrsim104:1) or intermediate (~102–104:1) mass ratios are among the most interesting gravitational wave sources that are expected to be detected by the proposed laser interferometer space antenna (LISA). These sources have the potential to tell us much about astrophysics, but are also of unique importance for testing aspects of the general theory of relativity in the strong field regime. Here we discuss these sources from the perspectives of astrophysics, data analysis and applications to testing general relativity, providing both a description of the current state of knowledge and an outline of some of the outstanding questions that still need to be addressed. This review grew out of discussions at a workshop in September 2006 hosted by the Albert Einstein Institute in Golm, Germany
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