Treatment of bimodality in proficiency test of pH in bioethanol matrix

The pH value in bioethanol is a quality control parameter related to its acidity and to the corrosiveness of vehicle engines when it is used as fuel. In order to verify the comparability and reliability of the measurement of pH in bioethanol matrix among some experienced chemical laboratories, reference material (RM) of bioethanol developed by Inmetro - the Brazilian National Metrology Institute - was used in a proficiency testing (PT) scheme. There was a difference of more than one unit in the value of the pH measured due to the type of internal filling electrolytic solutions (potassium chloride, KCl or lithium chloride, LiCl) from the commercial pH combination electrodes used by the participant laboratories. Therefore, bimodal distribution has occurred from the data of this PT scheme. This work aims to present the possibilities that a PT scheme provider can use to overcome the bimodality problem. Data from the PT of pH in bioethanol were treated by two different statistical approaches: kernel density model and the mixture of distributions. Application of these statistical treatments improved the initial diagnoses of PT provider, by solving bimodality problem and contributing for a better performance evaluation in measuring pH of bioethanol.Comment: 20 pages, 6 figures, Accepted for publication in Accreditation and Quality Assurance (ACQUAL

Modelling of an IR scintillation counter

A systematic study of the excitation and de-excitation mechanisms in ternary gas mixtures Ar+CO2+N2 is presented regarding the possibility of developing a proportional scintillation counter based on the detection of the infrared molecular emissions associated with the lowest vibrational states of molecules. The use of visible or near-infrared photons ([lambda]<1 [mu]m) for applications like imaging and quality control of microstructure detectors has been reported. In view of these applications we analyse the processes leading to near-infrared emissions in pure argon and give an estimation of the number of photons emitted per electron, at several pressures, as a function of the charge gain.http://www.sciencedirect.com/science/article/B6TJM-3YXB101-2M/1/b5bfeb3739389bb6dbe4d84c8746dbf

ANALYSIS OF THE TURBULENCE-RADIATION INTERACTION IN A METHANE-AIR DIFFUSION FLAME

The phenomenon of turbulence-radiation interaction (TRI) has been demonstrated experimentally, theoretically and numerically to be important in a great number of engineering applications. This paper presents a numerical study on the subject, focusing on a methane-air diffusion flame confined in a rectangular enclosure. An open source, Fortran-based code, Fire Dynamics Simulator, is used for the analysis. Large Eddy Simulation (LES) is adopted to model the turbulence, and to resolve the sub-grid scale terms the dynamic Smagorinsky model is employed. To solve the radiative heat transfer, the finite volume method is used alongside the Weighted-Sum-of-Gray-Gases model. The main objective of the present work is to assess the magnitude of TRI effects for the configuration proposed. For this purpose, the time-averaged wall heat fluxes and volumetric radiative heat source, calculated from the LES results, are compared with those same quantities obtained by independent simulations initialized using mean temperature and species concentration fields. TRI effects are found to be responsible for differences up to 30% between results considering and neglecting turbulent fluctuations. These differences are larger for the radiative heat source and for the radiative heat flux to the walls, smaller for the total heat flux, and almost negligible for the convective heat flux. The influence of the fuel stream Reynolds number on the TRI effects is also evaluated, and a slight decrease on the magnitude of TRI is observed with the increase of that parameter

Traumatic Tympanic Bulla Fracture in a Cat With Severe Head Trauma

A nine-year-old male European shorthair cat was referred to our practice with severe head trauma after suffering a road traffic accident (RTA). The patient presented marked facial swelling and multiple skin wounds and bruising, inspiratory dyspnea, palpable mandibular and maxillary fractures, serosanguinolent oronasal discharge and right eye exophthalmos and buphthalmos with loss of menace and pupillary reflex. After stabilizing the patient, a CT scan was performed under general anesthesia and an oesophagostomy tube was placed. The scan revealed the presence of multiple right tympanic bulla fractures. Multiple mandibular, maxillary, and palatine fractures were also present. The cat underwent surgery. Mandibular symphyseal separation and maxillary fractures were stabilized using intraoral cerclage wire fixation reinforced with composite and the right eye was enucleated. The rest of the fractures were treated conservatively. A CT scan 4 months after the trauma was also performed. At this point, the maxillofacial fractures were healing properly, and a bone callus demonstrating fusion of fragments of the right tympanic bulla was evident. There was absence of abnormal content inside the right tympanic bulla. The patient recovered uneventfully with no neurological deficits. To the author''s knowledge this is the first case reporting a traumatic tympanic bulla fracture in the cat with case follow up, and the first case reported using CT as diagnostic imaging test

Quality control of GEM detectors using scintillation techniques

Non destructive quality control of microstructures at the manufacturing stage is an important issue in the foreseen use of huge numbers of such gaseous detectors in the future high luminosity colliders. In this work we report on the use of the scintillation light emitted by the avalanches in GEM channels for checking defects in the foils. The test system is described and data on the relative efficiency of several gaseous mixtures are presented. The foil images obtained with a low-noise CCD system are analysed and compared with the optical images obtained with an industrial inspection system of high magnification. The validity of this test method is established and possible extensions of its use are discussed.Comment: 11 pages, 9 figure

From QCD lattice calculations to the equation of state of quark matter

We describe two-flavor QCD lattice data for the pressure at finite temperature and zero chemical potential within a quasiparticle model. Relying only on thermodynamic selfconsistency, the model is extended to nonzero chemical potential. The results agree with lattice calculations in the region of small chemical potential.Comment: 5 eps figure

Association of socioeconomic status with inflammatory markers: a two cohort comparison.

OBJECTIVE: To assess the association between socioeconomic status (SES) and inflammatory markers using two different European population samples. METHODS: We used data from the CoLaus (N=6412, Lausanne, Switzerland) and EPIPorto (N=1205, Porto, Portugal) studies. Education and occupational position were used as indicators of socioeconomic status (SES). High-sensitivity C-reactive protein (hs-CRP) was available for both cohorts. Interleukin-6 (IL-6) and tumour necrosis factor-α (TNF-α) were available in CoLaus; leukocyte count and fibrinogen in EPIPorto. RESULTS: We showed that low SES was significantly associated with high inflammation in both studies. We also showed that behavioural factors contributed the most to SES differences in inflammation. In both studies the larger difference between the lowest and the highest SES was observed for hs-CRP. In the Swiss sample, a linear association between education and hs-CRP persisted after adjustment for all mediating factors and confounders considered (p for linear trend &lt;0.001). CONCLUSION: Large social differences exist in inflammatory activity, in part independently from demographic and behavioural factors, chronic conditions and medication use. SES differences in inflammation are also similar in countries with different underlying socioeconomic conditions

Quality control of GEM detectors using scintillation techniques

Non-destructive quality control of microstructures at the manufacturing stage is an important issue in the foreseen use of huge numbers of such gaseous detectors in the future high luminosity colliders. In this work we report on the use of the scintillation light emitted by the avalanches in GEM channels for checking defects in the foils. The test system is described and data on the relative efficiency of several gaseous mixtures are presented. The foil images obtained with a low-noise CCD system are analysed and compared with the optical images obtained with an industrial inspection system of high magnification. The validity of this test method is established and possible extensions of its use are discussed.http://www.sciencedirect.com/science/article/B6TJM-3YXB101-2K/1/86489e830e1d4ba436e110adeb1da95