Solubility of H2S in ammonium-based ionic liquids

This work is inserted in a research program that consists mainly in the experimental and theoretical study of gas/liquid solubility in ionic liquids (ILs). In this study the experimental data of hydrogen sulfide solubility in ammonium-based ionic liquids, namely 2-hydroxyethylammonium acetate [2-HEA][Ace], bis(2-hydroxyethyl)ammonium acetate [B-2-HEA][Ace] and 2-hydroxyethyldiethylammonium hydrogen diacetate [2-HEDEA][H(Ace)2], were determined using a volumetric method in the 298 K to 318 K temperature range and at atmospheric pressure. The ionic liquids are functionalized with the OH group in the ammonium-based cations, in order to study the influence of hydroxyl group in the formation of hydrogen bonds between the IL-IL and IL-gas. The data gathered is modelled with the Cubic Plus Association Equation of State (CPA EoS), considering the association schemes four-sites (4C) for hydrogen sulfide and two-sites (2B) for the ILs ([2-HEA][Ace], [B-2-HEA][Ace] and [2-HEDEA][H(Ace)2]).publishe

Morphometric analysis of bite mark patterns caused by domestic dogs (Canis lupus familiaris) using dental wax registers

Dog bites are a known public health problem involving physical, mental and emotional traumas. From a forensic point of view, it has been stated that their morphological characters, and the intercanine and interincisive measurements, could allow a taxonomic and specific identification of the implicated animal. The aim of this study was to differentiate and identify the biological profile of a potential aggressor dog by analysing eight morphometric bite patterns belonging to three different dog breeds. The data obtained were analyzed following three categories: a) breeds; b) sexes among breeds; and c) sex within breed. Significant differences were detected among the variables (p <= 0.05), but only the maximum maxillary intercanines width (MaxCW) allowed a breed differentiation. The other variables allowed a differentiation between two breeds or one breed over the others. The principal components analysis (PCA) allowed visualizing the degree of dispersion and relationship among the scores. It showed three well-defined and separated breed groups, and different degrees of dispersion within and among breeds. The most important variable for such a differentiation was MaxCW. When considering sex among breeds for males, it showed a statistically significant difference, but only the diastema located between the third left mandibular, incisive and the left mandibular canine (C-I-ManL) allowed breed differentiation. For females, only MaxCW allowed a differentiation among breeds. The multivariate analysis permitted with a 95 % confidence interval, a breed and sex differentiation. Besides, the PCA models allowed classifying, identifying, separating and graphically showing the relationship among the variables. This made it possible to differentiate between breeds and sexes. Due to the large range of dog breeds around the world, this multivariate analysis could also help determining the dog's weight and size, narrowing down towards an approximate number of offending dogs, focussing on a certain kind of dog breed, and pinpointing any suspect dog

NEW SEISMIC SOURCE ZONE MODEL FOR PORTUGAL AND AZORES

The development of seismogenic source models is one of the first steps in seismic hazard assessment. In seismic hazard terminology, seismic source zones (SSZ) are polygons (or volumes) that delineate areas with homogeneous characteristics of seismicity. The importance of using knowledge on geology, seismicity and tectonics in the definition of source zones has been recognized for a long time [1]. However, the definition of SSZ tends to be subjective and controversial. Using SSZ based on broad geology, by spreading the seismicity clusters throughout the areal extent of a zone, provides a way to account for possible long-term non-stationary seismicity behavior [2,3]. This approach effectively increases seismicity rates in regions with no significant historical or instrumental seismicity, while decreasing seismicity rates in regions that display higher rates of seismicity. In contrast, the use of SSZ based on concentrations of seismicity or spatial smoothing results in stationary behavior [4]. In the FP7 Project SHARE (Seismic Hazard Harmonization in Europe), seismic hazard will be assessed with a logic tree approach that allows for three types of branches for seismicity models: a) smoothed seismicity, b) SSZ, c) SSZ and faults. In this context, a large-scale zonation model for use in the smoothed seismicity branch, and a new consensus SSZ model for Portugal and Azores have been developed. The new models were achieved with the participation of regional experts by combining and adapting existing models and incorporating new regional knowledge of the earthquake potential. The main criteria used for delineating the SSZ include distribution of seismicity, broad geological architecture, crustal characteristics (oceanic versus continental, tectonically active versus stable, etc.), historical catalogue completeness, and the characteristics of active or potentially-active faults. This model will be integrated into an Iberian model of SSZ to be used in the Project SHARE seismic hazard assessment

COMPILATION OF ACTIVE FAULT DATA IN PORTUGAL FOR USE IN SEISMIC HAZARD ANALYSIS

To estimate where future earthquakes are likely to occur, it is essential to combine information about past earthquakes with knowledge about the location and seismogenic properties of active faults. For this reason, robust probabilistic seismic hazard analysis (PSHA) integrates seismicity and active fault data. Existing seismic hazard assessments for Portugal rely exclusively on seismicity data and do not incorporate data on active faults. Project SHARE (Seismic Hazard Harmonization in Europe) is an EC-funded initiative (FP7) that aims to evaluate European seismic hazards using an integrated, standardized approach. In the context of SHARE, we are developing a fully-parameterized active fault database for Portugal that incorporates existing compilations, updated according to the most recent publications. The seismogenic source model derived for SHARE will be the first model for Portugal to include fault data and follow an internationally standardized approach. This model can be used to improve both seismic hazard and risk analyses and will be combined with the Spanish database for use in Iberian- and European-scale assessments

Influence of temperature and pressure on the density and speed of sound of 2-hydroxyethylammonium propionate ionic liquid

The alkanolammonium ILs are protic ionic liquids (PILs) with huge potential in a variety of industrial fields. Among other advantages, these PILs have low cost of preparation, simple synthesis and purification methodologies and low toxicity. This study aims at obtaining significant data on the fundamental thermophysical properties of hydroxyethylammonium-based PILs with carboxylate anions. The density was measured within the temperature and pressure intervals (298.15–343.15) K and (0.1–35.0) MPa for 2-hydroxyethylammonium propionate, [2-HEA][Pr]. The speed of sound was determined in the ranges (303.15–353.15) K and (0.1–20.0) MPa for the same substance. The estimated combined standard uncertainties are ±0.45 kg·m−3 for density and ±1.6 m·s−1 for speed of sound. The experimental pVT data were fitted using the Goharshadi–Morsali-Abbaspour equation of state (GMA EoS) with average relative absolute deviation (%AARD) of 0.03%. Thermomechanical coefficients as the thermal expansivity, isothermal compressibility, and internal pressure, were calculated using GMA EoS with the internal pressure being further compared with calculated values of cohesive energy density. The experimental pVT data were further successfully described by the predictive methods of Gardas and Coutinho and Paduszyńki and Domańska.publishe

Elastic p-3He and n-3H scattering with two- and three-body forces

We report on a microscopic calculation of n-3H and p-3He scattering employing the Argonne v_{18} and v_8' nucleon-nucleon potentials with and without additional three-nucleon force. An R-matrix analysis of the p-3He and n-3H scattering data is presented. Comparisons are made for the phase shifts and a selection of measurements in both scattering systems. Differences between our calculation and the R-matrix results or the experimental data can be attributed to only two partial waves (3P0 and 3P2). We find the effect of the Urbana IX and the Texas-Los Alamos three-nucleon forces on the phase shifts to be negligible.Comment: submitted to Phys. Rev.

Potential for macro and micronutrients extraction from tomato plants with different soil water stresses

Different tomato cultivars may present differentiated water needs, making it indispensable to study water demand. Thus, the objective of this work was to evaluate the influence of six water stresses in the soil on the extraction potential of macro and micronutrients in the aerial part of tomato in vegetative stage, cultivar ‘Dominador’ F1, under protected cultivation and drip. The experiment was installed in a greenhouse with a randomized block design with four replications. The treatments consisted of six soil water stresses as indicative of the time of irrigation. The preset stresses were 20, 45, 70, 95, 120 and 145 kPa at 20 cm depth. At 140 days after transplanting, the variables evaluated were: the macro and micronutrient content of shoots. The results showed that to obtain higher levels of macro (P and S) and micronutrients (B and Cu) of the total aerial part of the ‘Dominador’ tomato plant F1, it was obtained at a voltage of 20 kPa, and its value was reduced linearly with the increase of the water tension in the soil

Creation and manipulation of entanglement in spin chains far from equilibrium

We investigate creation, manipulation, and steering of entanglement in spin chains from the viewpoint of quantum communication between distant parties. We demonstrate how global parametric driving of the spin-spin coupling and/or local time-dependent Zeeman fields produce a large amount of entanglement between the first and the last spin of the chain. This occurs whenever the driving frequency meets a resonance condition, identified as "entanglement resonance". Our approach marks a promising step towards an efficient quantum state transfer or teleportation in solid state system. Following the reasoning of Zueco et al. [1], we propose generation and routing of multipartite entangled states by use of symmetric tree-like structures of spin chains. Furthermore, we study the effect of decoherence on the resulting spin entanglement between the corresponding terminal spins.Comment: 10 pages, 8 figure

Rethinking health sector procurement as developmental linkages in East Africa

Health care forms a large economic sector in all countries, and procurement of medicines and other essential commodities necessarily creates economic linkages between a country's health sector and local and international industrial development. These procurement processes may be positive or negative in their effects on populations' access to appropriate treatment and on local industrial development, yet procurement in low and middle income countries (LMICs) remains under-studied: generally analysed, when addressed at all, as a public sector technical and organisational challenge rather than a social and economic element of health system governance shaping its links to the wider economy. This article uses fieldwork in Tanzania and Kenya in 2012–15 to analyse procurement of essential medicines and supplies as a governance process for the health system and its industrial links, drawing on aspects of global value chain theory. We describe procurement work processes as experienced by front line staff in public, faith-based and private sectors, linking these experiences to wholesale funding sources and purchasing practices, and examining their implications for medicines access and for local industrial development within these East African countries. We show that in a context of poor access to reliable medicines, extensive reliance on private medicines purchase, and increasing globalisation of procurement systems, domestic linkages between health and industrial sectors have been weakened, especially in Tanzania. We argue in consequence for a more developmental perspective on health sector procurement design, including closer policy attention to strengthening vertical and horizontal relational working within local health-industry value chains, in the interests of both wider access to treatment and improved industrial development in Africa

Incorporating Descriptive Metadata into Seismic Source Zone Models for Seismic Hazard Assessment: A case study of the Azores-West Iberian region

In probabilistic seismic-hazard analysis (PSHA), seismic source zone (SSZ) models are widely used to account for the contribution to the hazard from earth- quakes not directly correlated with geological structures. Notwithstanding the impact of SSZ models in PSHA, the theoretical framework underlying SSZ models and the criteria used to delineate the SSZs are seldom explicitly stated and suitably docu- mented. In this paper, we propose a methodological framework to develop and docu- ment SSZ models, which includes (1) an assessment of the appropriate scale and degree of stationarity, (2) an assessment of seismicity catalog completeness-related issues, and (3) an evaluation and credibility ranking of physical criteria used to delin- eate the boundaries of the SSZs. We also emphasize the need for SSZ models to be supported by a comprehensive set of metadata documenting both the unique character- istics of each SSZ and the criteria used to delineate its boundaries. This procedure ensures that the uncertainties in the model can be properly addressed in the PSHA and that the model can be easily updated whenever new data are available. The pro- posed methodology is illustrated using the SSZ model developed for the Azores–West Iberian region in the context of the Seismic Hazard Harmonization in Europe project (project SHARE) and some of the most relevant SSZs are discussed in detail