179 research outputs found
IN-SYNC. V. Stellar kinematics and dynamics in the Orion A Molecular Cloud
The kinematics and dynamics of young stellar populations enable us to test
theories of star formation. With this aim, we continue our analysis of the
SDSS-III/APOGEE IN-SYNC survey, a high resolution near infrared spectroscopic
survey of young clusters. We focus on the Orion A star-forming region, for
which IN-SYNC obtained spectra of stars. In Paper IV we used these
data to study the young stellar population. Here we study the kinematic
properties through radial velocities (). The young stellar population
remains kinematically associated with the molecular gas, following a
gradient along filament. However, near the center
of the region, the distribution is slightly blueshifted and asymmetric;
we suggest that this population, which is older, is slightly in foreground. We
find evidence for kinematic subclustering, detecting statistically significant
groupings of co-located stars with coherent motions. These are mostly in the
lower-density regions of the cloud, while the ONC radial velocities are
smoothly distributed, consistent with it being an older, more dynamically
evolved cluster. The velocity dispersion varies along the filament.
The ONC appears virialized, or just slightly supervirial, consistent with an
old dynamical age. Here there is also some evidence for on-going expansion,
from a --extinction correlation. In the southern filament, is
-- times larger than virial in the L1641N region, where we infer a
superposition along the line of sight of stellar sub-populations, detached from
the gas. On the contrary, decreases towards L1641S, where the
population is again in agreement with a virial state.Comment: 14 pages, 13 figures, ApJ accepte
Copper (I) SNS Pincer Complexes: Impact of Ligand Design and Solvent Coordination on Conformer Interconversion from Spectroscopic and Computational Studies
The syntheses and detailed characterizations (X-ray crystallography, NMR spectroscopy, cyclic voltammetry, infrared spectroscopy, electrospray mass spectrometry, and elemental analyses) of two new Cu(I) pincer complexes are reported. The pincer ligand coordinates through one nitrogen and two sulfur donor atoms and is based on bis-imidazole or bis-triazole precursors. These tridentate SNS ligands incorporate pyridine and thione-substituted imidazole or triazole functionalities with connecting methylene units that provide flexibility to the ligand backbone and enable high bite-angle binding. Variable temperature 1H NMR analysis of these complexes and of a similar zinc(II) SNS system shows that all are fluxional in solution and permits the determination of ΔGexp‡ and ΔSexp‡. DFT calculations are used to model the fluxionality of these complexes and indicate that a coordinating solvent molecule can promote hemilability of the SNS ligand by lowering the energy barrier involved in the partial rotation of the methylene units
IN-SYNC II: Virial Stars from Sub-Virial Cores -- The Velocity Dispersion of Embedded Pre-Main-Sequence Stars in NGC 1333
The initial velocity dispersion of newborn stars is a major unconstrained
aspect of star formation theory. Using near-infrared spectra obtained with the
APOGEE spectrograph, we show that the velocity dispersion of young (1-2 Myr)
stars in NGC 1333 is 0.92+/-0.12 km/s after correcting for measurement
uncertainties and the effect of binaries. This velocity dispersion is
consistent with the virial velocity of the region and the diffuse gas velocity
dispersion, but significantly larger than the velocity dispersion of the dense,
star-forming cores, which have a sub-virial velocity dispersion of 0.5 km/s.
Since the NGC 1333 cluster is dynamically young and deeply embedded, this
measurement provides a strong constraint on the initial velocity dispersion of
newly-formed stars. We propose that the difference in velocity dispersion
between stars and dense cores may be due to the influence of a 70 micro-Gauss
magnetic field acting on the dense cores, or be the signature of a cluster with
initial sub-structure undergoing global collapse.Comment: Accepted to ApJ. 23 pages, 9 figures and 3 table
Spitzer and HHT observations of starless cores: masses and environments
We present Spitzer observations of a sample of 12 starless cores selected to
have prominent 24 micron shadows. The Spitzer images show 8 and 24 micron
shadows and in some cases 70 micron shadows; these spatially resolved
absorption features trace the densest regions of the cores. We have carried out
a 12CO (2-1) and 13CO (2-1) mapping survey of these cores with the Heinrich
Hertz Telescope (HHT). We use the shadow features to derive optical depth maps.
We derive molecular masses for the cores and the surrounding environment; we
find that the 24 micron shadow masses are always greater than or equal to the
molecular masses derived in the same region, a discrepancy likely caused by CO
freeze--out onto dust grains. We combine this sample with two additional cores
that we studied previously to bring the total sample to 14 cores. Using a
simple Jeans mass criterion we find that ~ 2/3 of the cores selected to have
prominent 24 micron shadows are collapsing or near collapse, a result that is
supported by millimeter line observations. Of this subset at least half have
indications of 70 micron shadows. All cores observed to produce absorption
features at 70 micron are close to collapse. We conclude that 24 micron
shadows, and even more so the 70 micron ones, are useful markers of cloud cores
that are approaching collapse.Comment: 41 pages, 28 figures, 5 tables; accepted by Ap
Academic Cancer Center Phase I Program Development
Multiple factors critical to the effectiveness of academic phase I cancer programs were assessed among 16 academic centers in the U.S. Successful cancer centers were defined as having broad phase I and I/II clinical trial portfolios, multiple investigator‐initiated studies, and correlative science. The most significant elements were institutional philanthropic support, experienced clinical research managers, robust institutional basic research, institutional administrative efforts to reduce bureaucratic regulatory delays, phase I navigators to inform patients and physicians of new studies, and a large cancer center patient base. New programs may benefit from a separate stand‐alone operation, but mature phase I programs work well when many of the activities are transferred to disease‐oriented teams. The metrics may be useful as a rubric for new and established academic phase I programs.This commentary assesses the factors necessary for the effectiveness of academic phase I cancer programs. The metrics presented here may be useful as a rubric for new and established programs.Peer Reviewedhttps://deepblue.lib.umich.edu/bitstream/2027.42/139928/1/onco12106-sup-0001-suppinfo1.pdfhttps://deepblue.lib.umich.edu/bitstream/2027.42/139928/2/onco12106.pdfhttps://deepblue.lib.umich.edu/bitstream/2027.42/139928/3/onco12106-sup-0002-suppinfo2.pd
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