Phase transition in nanomagnetite

Recently, the application of nanosized magnetite particles became an area of growing interest for their potential practical applications. Nanosized magnetite samples of 36 and 9 nm sizes were synthesized. Special care was taken on the right stoichiometry of the magnetite particles. Mössbauer spectroscopy measurements were made in 4.2–300 K temperature range. The temperature dependence of the intensities of the spectral components indicated size dependent transition taking place in a broad temperature range. For nanosized samples, the hyperfine interaction values and their relative intensities changed above the Verwey transition temperature value of bulk megnetite. The continuous transition indicated the formation of dendritelike granular assemblies formed during the preparation of the samples

Vertical Moist Thermodynamic Structure and Spatial–Temporal Evolution of the MJO in AIRS Observations

The atmospheric moisture and temperature profiles from the Atmospheric Infrared Sounder (AIRS)/Advanced Microwave Sounding Unit on the NASA Aqua mission, in combination with the precipitation from the Tropical Rainfall Measuring Mission (TRMM), are employed to study the vertical moist thermodynamic structure and spatial–temporal evolution of the Madden–Julian oscillation (MJO). The AIRS data indicate that, in the Indian Ocean and western Pacific, the temperature anomaly exhibits a trimodal vertical structure: a warm (cold) anomaly in the free troposphere (800–250 hPa) and a cold (warm) anomaly near the tropopause (above 250 hPa) and in the lower troposphere (below 800 hPa) associated with enhanced (suppressed) convection. The AIRS moisture anomaly also shows markedly different vertical structures as a function of longitude and the strength of convection anomaly. Most significantly, the AIRS data demonstrate that, over the Indian Ocean and western Pacific, the enhanced (suppressed) convection is generally preceded in both time and space by a low-level warm and moist (cold and dry) anomaly and followed by a low-level cold and dry (warm and moist) anomaly. The MJO vertical moist thermodynamic structure from the AIRS data is in general agreement, particularly in the free troposphere, with previous studies based on global reanalysis and limited radiosonde data. However, major differences in the lower-troposphere moisture and temperature structure between the AIRS observations and the NCEP reanalysis are found over the Indian and Pacific Oceans, where there are very few conventional data to constrain the reanalysis. Specifically, the anomalous lower-troposphere temperature structure is much less well defined in NCEP than in AIRS for the western Pacific, and even has the opposite sign anomalies compared to AIRS relative to the wet/dry phase of the MJO in the Indian Ocean. Moreover, there are well-defined eastward-tilting variations of moisture with height in AIRS over the central and eastern Pacific that are less well defined, and in some cases absent, in NCEP. In addition, the correlation between MJO-related midtropospheric water vapor anomalies and TRMM precipitation anomalies is considerably more robust in AIRS than in NCEP, especially over the Indian Ocean. Overall, the AIRS results are quite consistent with those predicted by the frictional Kelvin–Rossby wave/conditional instability of the second kind (CISK) theory for the MJO

Effect of an axial magnetic field on the spontaneous emission from an argon hollow cathode discharge, The

Includes bibliographical references (page 122).An applied longitudinal magnetic field is observed to decrease the equilibrium population of excited argon ion levels in a hollow cathode discharge, whereas the excited state populations of neutral argon atoms are not significantly altered. The longitudinal magnetic field is shown to decrease the effective density of beam electrons in the negative glow

Scale-by-scale analysis of probability distributions for global MODIS-AQUA cloud properties: how the large scale signature of turbulence may impact statistical analyses of clouds

Means, standard deviations, homogeneity parameters used in models based on their ratio, and the probability distribution functions (PDFs) of cloud properties from the MODerate resolution Infrared Spectrometer (MODIS) are estimated globally as function of averaging scale varying from 5 to 500 km. The properties – cloud fraction, droplet effective radius, and liquid water path – all matter for cloud-climate uncertainty quantification and reduction efforts. Global means and standard deviations are confirmed to change with scale. For the range of scales considered, global means vary only within 3% for cloud fraction, 7% for liquid water path, and 0.2% for cloud particle effective radius. These scale dependences contribute to the uncertainties in their global budgets. Scale dependence for standard deviations and generalized flatness are compared to predictions for turbulent systems. Analytical expressions are identified that fit best to each observed PDF. While the best analytical PDF fit to each variable differs, <i>all</i> PDFs are well described by log-normal PDFs when the mean is normalized by the standard deviation inside each averaging domain. Importantly, log-normal distributions yield significantly better fits to the observations than gaussians at all scales. This suggests a possible approach for both sub-grid and unified stochastic modeling of these variables at all scales. The results also highlight the need to establish an adequate spatial resolution for two-stream radiative studies of cloud-climate interactions

Influence of electron collisions inside the cathode sheath upon the electron energy spectrum in the negative glow region of a gas discharge

Includes bibliographical references.Computer models have been developed to solve the Boltzmann equation for the electron energy spectrum in both the cathode sheath and the negative glow region of a glow discharge. Electron collisions occurring during acceleration inside the cathode sheath partially determine the structure of the electron energy distribution measured in the negative glow. The relative role of elastic, excitation, and ionization collisions are examined using the computer model. Good qualitative agreement was obtained between calculated electron energy distributions and previous experimental measurements both at the sheath-plasma interface as well as in the negative glow region of the discharge.This work was supported by the National Science Foundation. Quantum Electronics Waves and Beams (ECS-881505I, Dr. L. Goldberg) and the Naval Research Laboratory

Vertical Moist Thermodynamic Structure of the Madden–Julian Oscillation in Atmospheric Infrared Sounder Retrievals: An Update and a Comparison to ECMWF Interim Re-Analysis

The large-scale vertical moist thermodynamic structure of the Madden–Julian oscillation (MJO) was documented using the first 2.5 yr (2002–05) of version 4 atmospheric specific humidity and temperature profiles from the Atmospheric Infrared Sounder (AIRS). In this study, this issue is further examined using currently available 7-yr version 5 AIRS data (2002–09) to test its dependence on the AIRS data record lengths, AIRS retrieval versions, and MJO event selection and compositing methods employed. The results indicate a strong consistency of the large-scale vertical moist thermodynamic structure of the MJO between different AIRS data record lengths (2.5 vs 7 yr), different AIRS retrieval versions (4 vs 5), and different MJO analysis methods [the extended empirical orthogonal function (EEOF) method vs the multivariate empirical orthogonal function (MEOF) method]. The large-scale vertical moist thermodynamic structures of the MJO between the AIRS retrievals and the ECMWF Interim Re-Analysis (ERA-Interim) products are also compared. The results indicate a much better agreement of the MJO vertical structure between AIRS and ERA-Interim than with the NCEP–NCAR reanalysis, although a significant difference exists in the magnitude of moisture anomalies between ERA-Interim and AIRS. This characterization of the vertical moist thermodynamic structure of the MJO by AIRS and ERA-Interim offers a useful observation-based metric for general circulation model diagnostics

Utilizing Humidity and Temperature Data to Advance Monitoring and Prediction of Meteorological Drought

The fraction of land area over the Continental United States experiencing extreme hot and dry conditions has been increasing over the past several decades, consistent with expectation from anthropogenic climate change. A clear concurrent change in precipitation, however, has not been confirmed. Vapor pressure deficit (VPD), combining temperature and humidity, is utilized here as an indicator of the background atmospheric conditions associated with meteorological drought. Furthermore, atmospheric conditions associated with warm season drought events are assessed by partitioning associated VPD anomalies into the temperature and humidity components. This approach suggests that the concurrence of anomalously high temperature and low humidity was an important driver of the rapid development and evolution of the exceptionally severe 2011 Texas and the 2012 Great Plains droughts. By classification of a decade of extreme drought events and tracking them back in time, it was found that near surface atmospheric temperature and humidity add essential information to the commonly used precipitation-based drought indicators and can advance efforts to determine the timing of drought onset and its severity