¿Influyen las mujeres directivas en el coste de la financiación bancaria? La experiencia de Australia

We investigate the effect of women directors on the cost of bank loans for a sample of Australian listed firms during the period 2002-2017. More women on both boards and committees are associated with lower loan spreads, reduced default risk, and improved financial reporting quality. The reduction in loan spread is seen from when the first female director joins the board, and the effect of that is stronger than the effects of additional (second and subsequent) women joining the board. Moreover, womens leadership status reinforces this effect. Our results are consistent with the idea that female directors exhibit greater risk aversion than male directors, that women are not treated as tokens and are influential even as a minority group on the board and that they enhance corporate governance and reporting quality.Investigamos el efecto de las mujeres consejeras en el coste de los préstamos bancarios para una muestra de empresas australianas que cotizan en bolsa durante el período 2002-2017. Un mayor número de mujeres tanto en los consejos de administración como en los comités se asocia con menores diferenciales de los préstamos, un menor riesgo de impago y una mejor calidad de los informes financieros. La reducción del diferencial de los préstamos se observa desde la primera mujer consejera, y resulta más intensa que los efectos asociados a las siguientes (segunda y siguientes) mujeres incorporadas al consejo. Además, el estatus de liderazgo de la mujer refuerza este efecto. Nuestros resultados son coherentes con las nociones de que las mujeres consejeras muestran una mayor aversión al riesgo que los hombres consejeros, que las mujeres no son tratadas como símbolo siendo influyentes incluso como grupo minoritario en el consejo y que mejoran el gobierno corporativo y la calidad de la información

Growth, blood metabolites and hormones in calves fed diets with different amounts of energy and protein during the pre- or post-weaning periods

We investigated the effects of diets differing in energy and protein concentrations given during pre- and post-weaning on hormone and metabolite levels in association to parameters of growth. Sixteen Aberdeen Angus calves four-day-old were allocated in individual pens during 105 days in a randomized complete design. Animals consumed ad libitum various diets differing in proportion of energy and protein (A: 80% of concentrate, 20% alfalfa hay; B: 60% concentrate, 40% of alfalfa hay; C: 40% concentrate, 60% alfalfa hay, and D: 20% concentrate, 80% alfalfa hay). Also, calves consumed milk substitute up to 60-day-old day. Serum growth hormone and cortisol levels were not altered with diet changes (P > 0.05) neither during the pre- nor the post-weaning periods. Plasma insulin concentration average daily intake, glucose and thyroid hormone levels, and concentrations of ammonia nitrogen and propionic acid were greater (P < 0.01) for diets having higher than lower energy and protein levels during the post-weaning but not during the pre-weaning period. These results suggest inclusion of higher amounts of concentrate in the diet of weaned calves.Fil: Fernández, H. T.. Universidad Nacional del Sur. Departamento de Agronomía; ArgentinaFil: Busso, Carlos Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Centro de Recursos Naturales Renovables de la Zona Semiarida. Universidad Nacional del Sur. Centro de Recursos Naturales Renovables de la Zona Semiarida; ArgentinaFil: Laborde, Hugo Eduardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Centro de Recursos Naturales Renovables de la Zona Semiarida. Universidad Nacional del Sur. Centro de Recursos Naturales Renovables de la Zona Semiarida; ArgentinaFil: Torrea, M. B.. Universidad Nacional del Sur. Departamento de Agronomía; ArgentinaFil: Fernández, L. M.. Universidad Nacional del Sur. Departamento de Biología, Bioquímica y Farmacia; ArgentinaFil: López, G. H.. Universidad Nacional del Sur. Departamento de Biología, Bioquímica y Farmacia; ArgentinaFil: Delucchi, F.. Universidad Nacional del Sur. Departamento de Biología, Bioquímica y Farmacia; ArgentinaFil: García, B. N.. Universidad Nacional del Sur. Departamento de Biología, Bioquímica y Farmacia; Argentin

Parto y distocias en la perra y en la gata

El conocimiento de la fisiología normal del parto, eutocia, resulta indispensable para reconocer y, por lo tanto, establecer un adecuado plan de actuación clínica ante un parto patológico o distócico. En la primera parte de este artículo revisamos los mecanismos del parto en la perra y en la gata poniendo especial interés en aquellos aspectos de mayor trascendencia clínica; posteriormente estudiamos el parto patológico, su diagnóstico y las técnicas obstétricas que debemos emplear para resolver el problema que plantea un parto distócico en los animales de compañía.An adequate knowledge of the physiological parturition, eutocya, results essential in order to recognize and then establishing an accurate plan of clinicalperformance, to cope with the pathological whelping or dystocia. That's why in the first part of this article the mechanism of parturition in the bitch and the queen are reviewed, watching especiaUythose aspects of clinical significance; after this we study the pathological parturition, its identification and the obstetrical techniques to use in order to get successin the resolution of the trouble that a dystocia in companion animals represents

Synthesis and Structural Characterization of Branched Bimetallic AuPd Nanoparticles with a Highly Tunable Optical Response

Funding Information: This work received financial support from Portugal national funds [Fundação para a Ciência e Tecnologia and Ministério da Ciência, Tecnologia e Ensino Superior (FCT/MCTES)] through the Projects UIDB/50006/2020 and UIDP/50006/2020. Silvia Nuti, Carlos Lodeiro, José-Luis Capelo-Martinez, Adrián Fernández-Lodeiro, and Javier Fernández-Lodeiro thank the financial support from national funds (FCT/MCTES) through Project Met4Cat (EXPL/QUI-COL/0263/2021). The authors thank the financial support by the PROTEOMASS Scientific Society (Portugal) (General Funding Grant 2023). The authors acknowledge funding from the European Union’s Horizon 2020 Research and Innovation Program under Grant 823717-ESTEEM3, and Ana B. Hungría thanks the financial support from Junta de Andalucía Project P20_00968. Silvia Nuti thanks FCT/MCTEC (Portugal) for her doctoral grant associated with the chemistry Ph.D. program (SFRH/BD/144618/2019). Javier Fernández-Lodeiro thanks FCT for the research contract through the Program DL 57/2016-Norma Transitória. The work was carried out partially through the INL User Facilities (Braga, Portugal) and the Electron Microscope Division (DME) of the Servicios Centrales de Investigación Científica y Tecnológica (SC-ICYT) at Cadiz University (Cadiz, Spain). The authors thank Dr. Jamila Djafari for the assistance with the design of the graphical abstract. Funding Information: This work received financial support from Portugal national funds [Fundação para a Ciência e Tecnologia and Ministério da Ciência, Tecnologia e Ensino Superior (FCT/MCTES)] through the Projects UIDB/50006/2020 and UIDP/50006/2020. Silvia Nuti, Carlos Lodeiro, José-Luis Capelo-Martinez, Adrián Fernández-Lodeiro, and Javier Fernández-Lodeiro thank the financial support from national funds (FCT/MCTES) through Project Met4Cat (EXPL/QUI-COL/0263/2021). The authors thank the financial support by the PROTEOMASS Scientific Society (Portugal) (General Funding Grant 2023). The authors acknowledge funding from the European Union’s Horizon 2020 Research and Innovation Program under Grant 823717-ESTEEM3, and Ana B. Hungría thanks the financial support from Junta de Andalucía Project P20_00968. Silvia Nuti thanks FCT/MCTEC (Portugal) for her doctoral grant associated with the chemistry Ph.D. program (SFRH/BD/144618/2019). Javier Fernández-Lodeiro thanks FCT for the research contract through the Program DL 57/2016–Norma Transitória. The work was carried out partially through the INL User Facilities (Braga, Portugal) and the Electron Microscope Division (DME) of the Servicios Centrales de Investigación Científica y Tecnológica (SC-ICYT) at Cadiz University (Cadiz, Spain). The authors thank Dr. Jamila Djafari for the assistance with the design of the graphical abstract. Publisher Copyright: © 2023 The Authors. Published by American Chemical Society.Bimetallic nanostructures composed of gold (Au) and palladium (Pd) have garnered increased interest for their applications in heterogeneous catalysis. This study reports a simple strategy for manufacturing Au@Pd bimetallic branched nanoparticles (NPs), which offer a tunable optical response, using polyallylamine-stabilized branched AuNPs as template cores for Pd overgrowth. The palladium content can be altered by manipulating the concentration of PdCl42- and ascorbic acid (AA) that are injected, which permit an overgrowth of the Pd shell up to ca. 2 nm thick. The homogeneous distribution of Pd at the surfaces of Au NPs can be carried out regardless of their size or branching degree, which allows for an adjustment of the plasmon response in the near-infrared (NIR) spectral range. As a proof of concept, the nanoenzymatic activity of pure gold and gold-palladium NPs was compared, exploring their peroxidase-like activity in the oxidation of 3,3′,5,5′-tetramethylbenzidine (TMB). The bimetallic AuPd NPs demonstrate an increase in the catalytic properties attributed to the presence of palladium at the surface of gold.publishersversionpublishe

Erratum: Virial coefficients and demixing in the Asakura-Oosawa model (vol 142, 014902, 2015)

© 2015 AIP Publishing LLCDepto. de Estructura de la Materia, Física Térmica y ElectrónicaFac. de Ciencias FísicasTRUEpu

Dysautonomia Differentially Influences the Effect of Affective Pain Perception on Quality of Life in Parkinson’s Disease Patients

[EN] Background. Our aim was to evaluate the real effect of dysautonomic symptoms on the influence of affective pain perception on quality of life in PD patients. Methods. An observational cross-sectional study was carried out using 105 Parkinson's disease (PD) patients of the Movement Disorders Unit, Hospital de Cruces (Bilbao, Spain) [men 59 (56.2%), women 46 (43.85%)]. Statistical analysis was made in order to evaluate the possible association of pain with life quality. Results. Quality of life measured by PDQ-39 (Parkinson's Disease Questionnaire for quality of life) was statistically associated with affective dimension of pain (PRIA, affective pain rating index). However, the influence of this dimension on PDQ-39 was different in the specific case of PD patients that experimented a high score (>12) in SCOPA-AUT (Scale for Outcomes in PD-Autonomic scale). Conclusions. These results confirm the effect of affective perception of pain in life quality of PD patients, indicating the critical role of autonomic symptoms in the modulation of the influence of pain on quality of life and showing the possible utility of dysautonomia as clinical prognostic indicator of quality of life in PD patients affected by painS

Nanostructured Sensors for Determination of 3-(3,4-Dichlorophenyl)-1,1-Dimethylurea Based in Molecularly Imprinted Polymers (MIPs) Deposited in Screen Printed Carbon Nanotubes

A sensor based on molecularly imprinted polymers (MIP) was developed for determination of 3-(3,4-Dichlorophenyl)-1,1- dimethylurea (diuron). The MIP were synthesized by free radical polymerization in wich diuron acted as template, methacrylic acid (MAA) acted as functional monomer and ethylene glycol dimethacrylate (EGDMA) acted as crosslinker. For construction of the sensor, glassy carbon electrode was modified with Nafion® and MIP/NIP (non imprinted polymer) to see the contribution of MIP, as a film, in the diuron recognition. Differential Pulse Voltammetry was used to the quantification of diuron in a range of response 0.4 - 1.2 V in a PBS (pH=8). All parameters affecting the sensor were optimized. The sensor showed a linear response from 1.00x10-5 to 9.616x10-5 M in PBS 0.1 M (pH=8). The limit of detection was 0.58x10-5 mol L-1. The nanostructured sensor was prepared using carbon nanotubes and showed a 4 times greater response than the glassy carbon, showing promising results