New Molecular Collisional Interaction Effect in Low-Energy Sputtering

Y. Yao, Z. Hargitai, M. Albert, R. G. Albridge, A. V. Barnes, J. M. Gilligan, B. Pratt Ferguson, G. Lüpke, V. D. Gordon (currently with UT Austin), and N. H. Tolk are with the Department of Physics and Astronomy, Vanderbilt University, Nashville, Tennessee 37235 -- J. C. Tully is with the Department of Physics and Department of Chemistry, Yale University, New Haven, Connecticut 06520 -- G. Betz and W. Husinsky are with the Institut für Allgemeine Physik, Technische Universität Wien, A-1040 Vienna, AustriaAn unexpected pronounced enhancement is observed in sputtering yields per atom for N2+ compared to N+ from a polycrystalline gold target. This effect is seen when the kinetic energy per projectile atom is below 500 eV and increases as projectile energy decreases to near-threshold energies. Enhancements for O2+ over O+ begin at even lower kinetic energies below 100 eV per atom. This new molecular interaction effect may be explained qualitatively by invoking a simple energy transfer model which involves the vibrational frequency of the molecule and the collisional interaction time. [S0031-9007(98)06668-X]Chemistr

Ultrafast x-ray-induced nuclear dynamics in diatomic molecules using femtosecond x-ray-pump-x-ray-probe spectroscopy

Citation: Lehmann, C. S., Picon, A., Bostedt, C., Rudenko, A., Marinelli, A., Moonshiram, D., . . . Southworth, S. H. (2016). Ultrafast x-ray-induced nuclear dynamics in diatomic molecules using femtosecond x-ray-pump-x-ray-probe spectroscopy. Physical Review A, 94(1), 7. doi:10.1103/PhysRevA.94.013426The capability of generating two intense, femtosecond x-ray pulses with a controlled time delay opens the possibility of performing time-resolved experiments for x-ray-induced phenomena. We have applied this capability to study the photoinduced dynamics in diatomic molecules. In molecules composed of low-Z elements, K-shell ionization creates a core-hole state in which the main decay mode is an Auger process involving two electrons in the valence shell. After Auger decay, the nuclear wave packets of the transient two-valence-hole states continue evolving on the femtosecond time scale, leading either to separated atomic ions or long-lived quasibound states. By using an x-ray pump and an x-ray probe pulse tuned above the K-shell ionization threshold of the nitrogen molecule, we are able to observe ion dissociation in progress by measuring the time-dependent kinetic energy releases of different breakup channels. We simulated the measurements on N-2 with a molecular dynamics model that accounts for K-shell ionization, Auger decay, and the time evolution of the nuclear wave packets. In addition to explaining the time-dependent feature in the measured kinetic energy release distributions from the dissociative states, the simulation also reveals the contributions of quasibound states

Hetero-site-specific X-ray pump-probe spectroscopy for femtosecond intramolecular dynamics

Citation: Picon, A., Lehmann, C. S., Bostedt, C., Rudenko, A., Marinelli, A., Osipov, T., . . . Southworth, S. H. (2016). Hetero-site-specific X-ray pump-probe spectroscopy for femtosecond intramolecular dynamics. Nature Communications, 7, 6. doi:10.1038/ncomms11652New capabilities at X-ray free-electron laser facilities allow the generation of two-colour femtosecond X-ray pulses, opening the possibility of performing ultrafast studies of X-ray-induced phenomena. Particularly, the experimental realization of hetero-site-specific X-ray-pump/X-ray-probe spectroscopy is of special interest, in which an X-ray pump pulse is absorbed at one site within a molecule and an X-ray probe pulse follows the X-ray-induced dynamics at another site within the same molecule. Here we show experimental evidence of a hetero-site pump-probe signal. By using two-colour 10-fs X-ray pulses, we are able to observe the femtosecond time dependence for the formation of F ions during the fragmentation of XeF2 molecules following X-ray absorption at the Xe site

Validity of the disabilities of the Arm, Shoulder and Hand patient-reported outcome measure (DASH) and the Quickdash when used in Dupuytren’s disease

This study investigated aspects of the validity and reliability of the 30-item Disabilities of the Arm, Shoulder and Hand patient-reported outcome measure (DASH) and its relationship with the shorter 11-item QuickDASH in patients with Dupuytren’s disease. Seven hundred and fifty-nine DASH questionnaires were studied, covering pre- and postoperative patients undergoing different treatments for Dupuytren’s disease. Items related to pain rose early after treatment before returning to baseline, suggesting that studying pain is relevant during postoperative recovery. Across all 759 sets of responses, the QuickDASH agreed closely with the DASH. In exploratory factor analysis, the DASH was not unidimensional, questioning the validity of the DASH summary score in Dupuytren’s disease. Further validation of existing PROMs for use in Dupuytren’s disease is needed. These data suggest that pain is a relevant symptom to study during postoperative recovery following treatment for Dupuytren’s disease

Measurement of an Elongation of the Pion Source in Z Decays

We measure Bose-Einstein correlations between like-sign charged pion pairs in hadronic Z decays with the L3 detector at LEP. The analysis is performed in three dimensions in the longitudinal center-of-mass system. The pion source is found to be elongated along the thrust axis with a ratio of transverse to longitudinal radius of $0.81\pm 0.02 ^{+0.03}_{-0.19}$

High Effectiveness of Broad Access Direct-Acting Antiviral Therapy for Hepatitis C in an Australian Real-World Cohort: The REACH-C Study

Australia was one of the first countries with unrestricted access to government subsidized direct-acting antiviral (DAA) therapy for adults with chronic hepatitis C virus. This study assessed real-world DAA treatment outcomes across a diverse range of Australian clinical services and evaluated factors associated with successful treatment and loss to follow-up. Real-world Effectiveness of Antiviral therapy in Chronic Hepatitis C (REACH-C) consisted a national observational cohort of 96 clinical services including specialist clinics and less traditional settings such as general practice. Data were obtained on consecutive individuals who commenced DAAs from March 2016 to June 2019. Effectiveness was assessed by sustained virological response ≥12 weeks following treatment (SVR) using intention-to-treat (ITT) and per-protocol (PP) analyses. Within REACH-C, 10,843 individuals initiated DAAs (male 69%; ≥50 years 52%; cirrhosis 22%). SVR data were available in 85% (9,174 of 10,843). SVR was 81% (8,750 of 10,843) by ITT and 95% (8,750 of 9,174) by PP. High SVR (≥92%) was observed across all service types and participant characteristics. Male gender (adjusted odds ratio [aOR] 0.56, 95% confidence interval [CI] 0.43-0.72), cirrhosis (aOR 0.52, 95% CI 0.41-0.64), recent injecting drug use (IDU; aOR 0.64, 95% CI 0.46-0.91) and previous DAA treatment (aOR 0.50, 95% CI 0.28-0.90) decreased the likelihood of achieving SVR. Multiple factors modified the likelihood of loss to follow-up including IDU ± opioid agonist therapy (OAT; IDU only: aOR 1.75, 95% CI 1.44-2.11; IDU + OAT: aOR 1.39, 95% CI 1.11-1.74; OAT only, aOR 1.36; 95% CI 1.13-1.68) and age (aOR 0.97, 95% CI 0.97-0.98). Conclusion: Treatment response was high in a diverse population and through a broad range of services following universal access to DAA therapy. Loss to follow-up presents a real-world challenge. Younger people who inject drugs were more likely to disengage from care, requiring innovative strategies to retain them in follow-up

Assessment of the physical characteristics and stormwater effluent quality of permeable pavement systems containing recycled materials

This paper evaluates the physical characteristics of two recycled materials and the pollutant removal efficiencies of four 0.2 m2 tanked permeable pavement rigs in the laboratory, that contained either natural aggregates or these recycled materials in the sub-base. The selected recycled materials were Crushed Concrete Aggregates (CCA) and Cement-bounded Expanded Polystyrene beads (C-EPS) whilst the natural aggregates were basalt and quartzite. Natural stormwater runoff was used as influent. Effluent was collected for analysis after 7–10 mins of discharge. Influent and effluent were analysed for pH, Chemical Oxygen Demand (COD), Dissolved Oxygen (DO), Electroconductivity (EC), turbidity, Total Suspended Solids (TSS), Total Dissolved Solids (TDS), Nitrate-Nitrogen (NO3-N), reactive phosphorous (PO43-) and sulphates (SO42-). Both CCA and C-EPS had suitable physical properties for use as sub-base materials in PPS. However, C-EPS is recommended for use in pavements with light to no traffic because of its relatively low compressive strength. In terms of pollutant removal efficiencies, significant differences (p 0.05) were found with respect to TSS, turbidity, COD and NO3-N. Effluent from rigs containing CCA and C-EPS saw significant increases in pH, EC and TDS measurements whilst improvements in DO, TSS, turbidity, COD, PO43- and SO42- were observed. All mean values except pH were, however, within the Maximum Permissible Levels (MPLs) of water pollutants discharged into the environment according to the Trinidad and Tobago Environmental Management Authority (EMA) or the United States Environmental Protection Agency (US EPA). In this regard, the CCA and C-EPS performed satisfactorily as sub-base materials in the permeable pavement rigs. It is noted, however, that further analysis is recommended through leaching tests on the recycled materials