Unexpected Architectures. Restorations in Romagna Between the Two World Wars

The research here presented is a critical appraisal of some restoration works carried out between the two World Wars in a particular geographic context, which is the Romagna district, in the Northeast of Italy. Starting from two case studies (the Casa del Fascio in Forl\uec and the Malatesta Library in Cesena) and thanks to the analysis of bibliographical sources, archival documents, and drawings, this research aims at understanding how broader and major theories about architectural restoration are articulated in peripheral background. What emerges are unexpected results: Late and deeply contextualized operations, strongly linked with the national panorama but at the same time chasing for the revival of their own history

Bicolor Electroluminescent Pixels from Single Active Molecular Material

We report on the fabrication of the first bicolor micropixelated OLED from a single molecular material using a single-step bottom up procedure, The implementation of a deposition technique, based on a spatial-switch and con formational-sensitive STD surface-tension-driven lithography, has allowed us to exploit the spontaneous supramolecular properties and the conformational flexibility of a conjugated thiophene-based material, 6-bis-(50-hexyl-[2, 20]bithiophen-5-yl)-3, 5-dimethyl-dithieno[3, 2-b: 20, 30-d]-thiophene (DTT7Me). The existence of two regularly alternating emitting regions on a micrometer scale allows obtaining electroluminescent emission at two different wavelengths from a single material

Amplified spontaneous emission and efficient tunable laser emission from a substituted thiophene-based oligomer

We investigated gain and lasing in spin-coated films of a soluble substituted oligothiophene. With increasing excitation power, the photoluminescence spectra show a clear line narrowing due to amplified spontaneous emission. We measure a low threshold (20 μJ cm−2) for line narrowing and a large gain cross section (6×10−16 cm2), indicating that this molecule is a promising active material for organic solid-state lasers. As a demonstrator, we realize a transverse electromagnetic (TEM00) single-mode laser with tunable emission from the yellow to the red (a range of 37 nm), with a pump threshold as low as 18 μJ cm−2 and efficiency of 1.9%. These results are among the best so far reported for organic lasers

Efficient second harmonic generation from thin films of V-shaped benzo[b]thiophene based molecules

We have designed an original approach for efficient Second Harmonic Generation of tailored V-shape benzo[b]thiophene molecular systems enabling versatile and flexible one-step, dry and technologically friendly thin film processing. The designed moieties show χ(2) values at least as high as the reference LiNbO3 single crystal, without poling processing and matching the constrains of integrated optical configuration for nonlinear optical devices. This may open the way to a new class of organic materials exploitable for photonic applications

DISCOVERING AND COMMUNICATING THE RATIONALIST ARCHITECTURE OF FORLÌ. AN INTEGRATED PROCESS

A partnership between the Department of Architecture of the University of Bologna and ATRIUM aimed at enhancing the knowledge and communication of the rationalist architecture, built in the city of Forlì during the Fascist regime. The importance of finding an interpretative key for this dissonant heritage, bearers of an “uncomfortable” memory but at the same time able to strongly characterize the architectural quality of cities, was a primary goal.The cooperation started with the development of a pilot project regarding three architectures considered iconic for this context but also able to foster more complex urban policies. The first deliverable of the programme was the search, record, and management of the archival materials related to the whole history of these buildings. The enormous amount of data acquired revealed the importance of working on a dual track, aimed at both the stakeholders involved in the management process of this heritage and those who experience it.For what concerns the “technical level” which is related to the knowledge field, the first challenge was to understand how to manage information boosting interoperability, guaranteeing easy access and above all making the research implementable. According to the “touristic level” instead, a further objective of the project was related to the communication of this heritage to a varied audience of visitors.</p

New light-emitting functionalized oligothiophenes

We present a new class of highly photo and electroluminescent oligomers based on the presence of one inner thienyl-S,S-dioxide unit as the luminophore. The light emission frequency of the new compounds, which are characterized by greater electron affinities than the corresponding oligomers bearing an unmodified thienyl ring, was tuned over the entire visible range by changing the nature of the alkyl or aryl groups attached in the α- and/or in the β-positions of the thienyl-S,S-dioxide moiety. A few aspects of the solid state supramolecular organization of the new compounds are reported

Visible-Light Assisted Covalent Surface Functionalization of Reduced Graphene Oxide Nanosheets with Arylazo Sulfones

We present an environmentally benign methodology for the covalent functionalization (arylation) of reduced graphene oxide (rGO) nanosheets with arylazo sulfones. A variety of tagged aryl units were conveniently accommodated at the rGO surface via visible-light irradiation of suspensions of carbon nanostructured materials in aqueous media. Mild reaction conditions, absence of photosensitizers, functional group tolerance and high atomic fractions (XPS analysis) represent some of the salient features characterizing the present methodology. Control experiments for the mechanistic elucidation (Raman analysis) and chemical nanomanipulation of the tagged rGO surfaces are also reported

Sistemi automatici di registrazione: nuove metodologie bioacustiche applicate a indagini ornitologiche in alcuni siti della Rete Natura 2000 del Veneto. Risultati e prospettive.

Il lavoro illustra i risultati di un progetto di monitoraggio acustico delle specie ornitologiche presenti in alcuni siti della Rete Natura 2000 del Veneto. Si descrive la metodologia impiegata, basata su registratori automatici programmabili e sull'analisi spettrografica delle registrazioni risultanti. Il progetto e' stato realizzato in collaborazione con il Corpo Forestale dello Stato

Bicolor Pixels from a Single Active Molecular Material by Surface-Tension-Driven Deposition†

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Solid-state supramolecular organization, established directly from powder diffraction data, and photoluminescence efficiency of rigid-core oligothiophene-S,S-dioxides.

The "rigid-core" material 3,5-dimethyl-2,3'-bis(3-methylthiophene)-dithieno[3,2-b:',3'−d]thiophene-4,4-dioxide (DTTOMe4) has the highest photoluminescence ever reported for thiophene-based molecule..