12,853 research outputs found
Near threshold rotational excitation of molecular ions by electron-impact
New cross sections for the rotational excitation of H by electrons are
calculated {\it ab initio} at low impact energies. The validity of the
adiabatic-nuclei-rotation (ANR) approximation, combined with -matrix
wavefunctions, is assessed by comparison with rovibrational quantum defect
theory calculations based on the treatment of Kokoouline and Greene ({\it Phys.
Rev. A} {\bf 68} 012703 2003). Pure ANR excitation cross sections are shown to
be accurate down to threshold, except in the presence of large oscillating
Rydberg resonances. These resonances occur for transitions with
and are caused by closed channel effects. A simple analytic formula is derived
for averaging the rotational probabilities over such resonances in a 3-channel
problem. In accord with the Wigner law for an attractive Coulomb field,
rotational excitation cross sections are shown to be large and finite at
threshold, with a significant but moderate contribution from closed channels.Comment: 3 figures, a5 page
Electron-impact rotational excitation of symetric-top molecular ions
We present electron-impact rotational excitation calculations for polyatomic molecular ions. The theory developed in this paper is an extension of the work of Rabadán et al (Rabadán I, Sarpal B K and Tennyson J 1998 J. Phys. B: At. Mol. Opt. Phys. 31 2077) on linear molecular ions to the case of symmetric-top species. The H3+ and H3O+ ions, as well as their deuterated forms D3+ and D3O+, are used as test cases and cross sections are obtained at various levels of approximation for impact energies up to 5 eV. As in the linear case, the widely used Coulomb–Born (CB) approximation is found to be unreliable in two major aspects: transitions with ΔJ > 1 are entirely dominated by short-range interactions and threshold effects are important at very low energies. Electron collisional selection rules are found to be consistent with the CB theory. In particular, dominant transitions are those for which ΔJ ≤ 2 and ΔK = 0
Collisional excitation of HC3N by para- and ortho-H2
New calculations for rotational excitation of cyanoacetylene by collisions
with hydrogen molecules are performed to include the lowest 38 rotational
levels of HC3N and kinetic temperatures to 300 K. Calculations are based on the
interaction potential of Wernli et al. A&A, 464, 1147 (2007) whose accuracy is
checked against spectroscopic measurements of the HC3N-H2 complex. The quantum
coupled-channel approach is employed and complemented by quasi-classical
trajectory calculations. Rate coefficients for ortho-H2 are provided for the
first time. Hyperfine resolved rate coefficients are also deduced. Collisional
propensity rules are discussed and comparisons between quantum and classical
rate coefficients are presented. This collisional data should prove useful in
interpreting HC3N observations in the cold and warm ISM, as well as in
protoplanetary disks.Comment: 8 pages, 2 tables, 4 figures, accepted for publication in MNRA
Low-energy electron collisions with water: elastic and rotationally inelastic scattering
Differential, integral and momentum transfer cross sections for the vibrationally elastic and rotationally inelastic scattering of electrons from water at low collision energies (E < 7 eV) are reported. The R-matrix method is used to compute the body-fixed T-matrices while the scattering calculations are performed within the fixed-nuclei approximation corrected with the standard Born-closure formula. Our calculations are compared with the very recent experimental results of Cho et al (2003 Radiat. Phys. Chem. 68 115). The differential and momentum transfer cross sections are in good agreement with the experimental results. The relative contribution of the rotationally inelastic processes is investigated in some detail. In particular, the importance of the pure elastic process at very low energy is emphasized
Experiments with a fully instrumented split Stirling cryocooler
A practical model that can be used to accurately size and optimally split stirling cryocoolers is discussed. A practical model that could be used to extrapolate existing designs to meet different specifications was developed. However, to do this detailed knowledge of the dynamic operating parameters of this type of cryocooler is required. The first stage is to fully instrument a refrigerator so that various dynamic parameters can be measured. The second stage involves the application of these measurements to the design and optimization of a range of coolers
Many parameter Hoelder perturbation of unbounded operators
If is a -mapping, for , having
as values unbounded self-adjoint operators with compact resolvents and common
domain of definition, parametrized by in an (even infinite dimensional)
space, then any continuous (in ) arrangement of the eigenvalues of is
indeed in .Comment: LaTeX, 4 pages; The result is generalized from Lipschitz to Hoelder.
Title change
Quasi-classical rate coefficient calculations for the rotational (de)excitation of H2O by H2
The interpretation of water line emission from existing observations and
future HIFI/Herschel data requires a detailed knowledge of collisional rate
coefficients. Among all relevant collisional mechanisms, the rotational
(de)excitation of H2O by H2 molecules is the process of most interest in
interstellar space. To determine rate coefficients for rotational de-excitation
among the lowest 45 para and 45 ortho rotational levels of H2O colliding with
both para and ortho-H2 in the temperature range 20-2000 K. Rate coefficients
are calculated on a recent high-accuracy H2O-H2 potential energy surface using
quasi-classical trajectory calculations. Trajectories are sampled by a
canonical Monte-Carlo procedure. H2 molecules are assumed to be rotationally
thermalized at the kinetic temperature. By comparison with quantum calculations
available for low lying levels, classical rates are found to be accurate within
a factor of 1-3 for the dominant transitions, that is those with rates larger
than a few 10^{-12}cm^{3}s^{-1}. Large velocity gradient modelling shows that
the new rates have a significant impact on emission line fluxes and that they
should be adopted in any detailed population model of water in warm and hot
environments.Comment: 8 pages, 2 figures, 1 table (the online material (4 tables) can be
obtained upon request to [email protected]
Niaogho versus beghedo : un conflit foncier à la veille de la révolution burkinabé
Le conflit foncier qui a opposé les habitants des deux bourgs de Niaogho et Beghedo dans la région bissa du Burkina Faso est plus qu'une bagarre entre deux villages. C'est l'illustration des enjeux politiques et économiques dont la terre est porteuse dans le Burkina d'aujourd'hui. Cette crise s'est déroulée en même temps que la course pour le pouvoir au niveau national, qui a abouti à la mise en place de la Révolution démocratique et populaire en 1983. La description des causes du conflit montre qu'il était urgent de clarifier les droits fonciers des exploitants. Le programme de "gestion des terroirs" permet aujourd'hui d'appliquer de façon plus réaliste la réorganisation agraire et foncière. (Résumé d'auteur
Plasma wake inhibition at the collision of two laser pulses in an underdense plasma
An electron injector concept for laser-plasma accelerator was developed in
ref [1] and [2] ; it relies on the use of counter-propagating ultrashort laser
pulses. In [2], the scheme is as follows: the pump laser pulse generates a
large amplitude laser wakefield (plasma wave). The counter-propagating
injection pulse interferes with the pump laser pulse to generate a beatwave
pattern. The ponderomotive force of the beatwave is able to inject plasma
electrons into the wakefield. We have studied this injection scheme using 1D
Particle in Cell (PIC) simulations. The simulations reveal phenomena and
important physical processes that were not taken into account in previous
models. In particular, at the collision of the laser pulses, most plasma
electrons are trapped in the beatwave pattern and cannot contribute to the
collective oscillation supporting the plasma wave. At this point, the fluid
approximation fails and the plasma wake is strongly inhibited. Consequently,
the injected charge is reduced by one order of magnitude compared to the
predictions from previous models.Comment: 4 pages, 4 figure
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