51 research outputs found
Minimal auxiliary basis set for time-dependent density functional theory and comparison with tight-binding approximations: Application to silver nanoparticles
The modeling of optical spectra of plasmonic nanoparticles via first-principles approaches is computationally expensive; thus, methods with high accuracy/computational cost ratio are required. Here, we show that the Time-Dependent Density Functional Theory (TDDFT) approach can be strongly simplified if only one s-type function per atom is employed in the auxiliary basis set, with a properly optimized exponent. This approach (named TDDFT-as, for auxiliary s-type) predicts excitation energies for silver nanoparticles with different sizes and shapes with an average error of only 12 meV compared to reference TDDFT calculations. The TDDFT-as approach resembles tight-binding approximation schemes for the linear-response treatment, but for the atomic transition charges, which are here computed exactly (i.e., without approximation from population analysis). We found that the exact computation of the atomic transition charges strongly improves the absorption spectra in a wide energy range
Atomistic investigation of hybrid plasmonic systems
By using time-dependent density functional theory, we investigate in a fully quantum mechanical framework the interactions, in an ultra-near-field regime, between a localized surface plasmon excitable in a silver tetrahedral cluster and a molecular exciton with excitation energy in the same range. We show that, for metal–molecule distances below 5 Å, the optical response of the system results characterized by the appearance of a double peak structure. We analyze the transition densities for the resonant energies and propose a plasmon–exciton electromagnetic interaction model to explain the emerging of a lower energy resonance in the spectra of such kind of hybrid systems of interest for molecular plasmonics
Fisheye Photogrammetry to Survey Narrow Spaces in Architecture and a Hypogea Environment
Nowadays, the increasing computation power of commercial grade processors has actively led to a vast spreading of image-based reconstruction software as well as its application in different disciplines. As a result, new frontiers regarding the use of photogrammetry in a vast range of investigation activities are being explored. This paper investigates the implementation of
fisheye lenses in non-classical survey activities along with the related problematics. Fisheye lenses are outstanding because of their large field of view.
This characteristic alone can be a game changer in reducing the amount of data required, thus speeding up the photogrammetric process when needed. Although they come at a cost, field of view (FOV), speed and manoeuvrability are key to the success of those optics as shown by two of the presented case studies: the survey of a very narrow spiral staircase located in the Duomo di Milano and the survey of a very narrow hypogea structure in Rome. A third case study, which deals with low-cost sensors, shows the metric evaluation of a commercial spherical camera equipped with fisheye lenses
an application of cosmo sky med to coastal erosion studies
AbstractStarted in 2009, the COSMOCoast project aims to the investigation of the potential of Remote Sensing in support to the management of coastal areas. Particular attention is paid to the contribution of data acquired from the COSMO-SkyMed constellation, in view of their frequency of acquisitions and ground resolution; in particular this paper aims at assessing the potential of COSMO-SkyMed data for coastline delineation. The results are conceived to be of particular interest for public administration bodies in charge of coastal defense. Keywords: Remote Sensing, Coastal Zones Management, COSMO-SkyMed
Hyperspectral Imaging in Major Hepatectomies: Preliminary Results from the Ex-Machyna Trial.
Ischemia-reperfusion injury during major hepatic resections is associated with high rates of post-operative complications and liver failure. Real-time intra-operative detection of liver dysfunction could provide great insight into clinical outcomes. In the present study, we demonstrate the intra-operative application of a novel optical technology, hyperspectral imaging (HSI), to predict short-term post-operative outcomes after major hepatectomy. We considered fifteen consecutive patients undergoing major hepatic resection for malignant liver lesions from January 2020 to June 2021. HSI measures included tissue water index (TWI), organ hemoglobin index (OHI), tissue oxygenation (StO2%), and near infrared (NIR). Pre-operative, intra-operative, and post-operative serum and clinical outcomes were collected. NIR values were higher in unhealthy liver tissue (p = 0.003). StO2% negatively correlated with post-operative serum ALT values (r = -0.602), while ΔStO2% positively correlated with ALP (r = 0.594). TWI significantly correlated with post-operative reintervention and OHI with post-operative sepsis and liver failure. In conclusion, the HSI imaging system is accurate and precise in translating from pre-clinical to human studies in this first clinical trial. HSI indices are related to serum and outcome metrics. Further experimental and clinical studies are necessary to determine clinical value of this technology
Tumor microenvironment‐derived serum markers as a new frontier of diagnostic and prognostic assessment in biliary tract cancers
No abstract availabl
Augmented Reality and Image-Guided Robotic Liver Surgery
PMC8699460Artificial intelligence makes surgical resection easier and safer, and, at the same time, can improve oncological results. The robotic system fits perfectly with these more or less diffused technologies, and it seems that this benefit is mutual. In liver surgery, robotic systems help surgeons to localize tumors and improve surgical results with well-defined preoperative planning or increased intraoperative detection. Furthermore, they can balance the absence of tactile feedback and help recognize intrahepatic biliary or vascular structures during parenchymal transection. Some of these systems are well known and are already widely diffused in open and laparoscopic hepatectomies, such as indocyanine green fluorescence or ultrasound-guided resections, whereas other tools, such as Augmented Reality, are far from being standardized because of the high complexity and elevated costs. In this paper, we review all the experiences in the literature on the use of artificial intelligence systems in robotic liver resections, describing all their practical applications and their weaknesses
The counterclock-clockwise approach for central hepatectomy: A useful strategy for a safe vascular control.
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Chatting to Personalize and Plan Cultural Itineraries
Abstract. In this paper, we present a system for the generation of cultural itineraries that exploits conversational agents to implicitly build formal user profiles. The key idea is that the preferences for user profiling are not obtained in a direct way, but acquired during a natural language conversation of the tourists with the system. When the user profile is ready, it becomes the input for the generation of the customized cultural itinerary. The proposed system, called DiEM System 3, is designed for dialogues in the domain of cultural heritage, but its flexible architecture allows to customize the dialogues in different application domains (cinema, finance, medicine, etc.).
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