Synthesis of MDI and PCL-diol-based polyurethanes containing [2] and [3]rotaxanes and their properties

We have successfully synthesized novel polyurethanes where PU1 contains a [3]rotaxane that consists of N-3,5-di-tert-butylbenzyl-N-3-hydroxypropylammonium hexafluorophosphate (AOH1) and N,N′-Dimethyl-N,N′-bis(dibenzo-24-crown-8)-terephthalamide (BisC) as well as PU2 contains a [2]rotaxane that consists of AOH1 and dibenzo-24-crown-8 ether. Diphenylmethanediisocyanate (MDI), 1,4-butanediol (BD) and poly(ε-caprolactone)diol (PCL) were used as an isocyanate, chain expander, and soft segment, respectively. A polyurethane without any rotaxane structures (PU0) were also prepared as a reference polymer. The existence of the rotaxanes in the polyurethanes was confirmed by 1H NMR spectroscopy and TGA measurement. ATR-FT-IR spectral measurement revealed that the rotaxanes disturb the formation of hydrogen bonding between the polyurethane chains. From the DSC result, the rotaxanes retard the recrystallization of the PCL unit whereas no influence on the glass transition temperatures of the polyurethanes was observed. The retarding effect appeared remarkably with PU1. These thermal behaviors of the polyurethanes were also supported by viscoelastic measurement. In tensile test, the tensile strength and break of strain of PU1 were larger than those of PU2

Petrological and Geochemical Study of Sundoro Volcano, Central Java, Indonesia: Temporal Variations in Differentiation and Source Processes during the Growth of an Individual Volcano

Volcanic rocks of the Java sector of Sunda arc have a wide range of isotopic compositions that indicate significant addition of subjected sediment. What processes control these geochemical characteristics is a topic of long-standing debate. Here we report Sr-Nd-Pb radiogenic isotope ratios and geochemical data from stratigraphically well-constrained rocks of Sundoro volcano in central Java that represent the volcano's activity since 34 ka. The rocks range from basalt (51 wt SiO2) to andesite (63 wt SiO2) and are dominated by basaltic andesite. We divide them into magma types A, B and C, having low, medium and high 87Sr/86Sr and Pb isotopic ratios, respectively. According to various differentiation indices, the three magma types have separate, parallel 87Sr/86Sr, Ba/Zr and La/Yb trends and disparate Pb isotopic trends. The dominant process of intracrustal differentiation appears to be magma mixing, in which each of the three magma types represents the mixing of a distinct mafic end-member and a distinct felsic end-member. The distinct geochemical profiles of these magma types indicate that the three mafic end-members are genetically unrelated and that their differences may represent characteristics of their magma sources. On the basis of trace element ratios (Ba/Yb and La/Yb) and Sr-Nd-Pb isotopic compositions, we estimate that magma types A, B and C represent mantle wedge materials fluxed by ~1, ~1.5 and ~2 slab-derived materials containing 50, 55 and 65 sediment component, respectively, reflecting increasing proportions of sediments and increasing slab flux. Geochemical data from Merapi volcano, interpreted using the same approach, reveal a similar increase in the slab-derived flux to the magma source, raising the possibility that such short-lived variations in magma genesis, perhaps related to the subduction of bathymetric relief features, characterize the unusual magmatism beneath the volcanic front of the central Java sector of the Sunda arc. © 2022 The Author(s). Published by Oxford University Press. All rights reserved

Effect of the volcanic front migration on helium, nitrogen, argon, and carbon geochemistry of hydrothermal/magmatic fluids from Hokkaido volcanoes, Japan

International audienc

Total mass estimate of the January 23, 2018, phreatic eruption of Kusatsu-Shirane Volcano, central Japan

Abstract On January 23, 2018, a small phreatic eruption (VEI = 1) occurred at the Motoshirane Pyroclastic Cone Group in the southern part of Kusatsu-Shirane Volcano in central Japan. The eruption ejected ash, lapillus, and volcanic blocks from three newly opened craters: the main crater (MC), west crater (WC), and south crater (SC). Volcanic blocks were deposited up to 0.5 km from each crater. In contrast, the ash released during this eruption fell up to 25 km ENE of the volcano. The total mass of the fall deposit generated by the eruption was estimated using two methods, yielding total masses of 3.4 × 104 t (segment integration method) and 2.4 × 104 t (Weibull fitting method). The calculations indicate that approximately 70% of the fall deposit was located within 0.5 km of the craters, which was mainly attributed to the low height of the eruption plume